On the parametrization of optical particle counter response including instrument-induced broadening of size spectra and a self-consistent evaluation of calibration measurements

Optical particle counters (OPCs) are common tools for the in situ measurement of aerosol particle number size distributions. As the actual quantity measured by OPCs is the intensity of light scattered by individual particles, it is necessary to translate the distribution of detected scattering signals into the desired information, i.e., the distribution of particle sizes. A crucial part in this challenge is the modeling of OPC response and the calibration of the instrument – in other words, establishing the relation between instrument-specific particle scattering cross-section and measured signal amplitude. To date, existing methods lack a comprehensive parametrization of OPC response, particularly regarding the instrument-induced broadening of signal amplitude distributions. This deficiency can lead to significant size distribution biases. We introduce an advanced OPC response model including a simple parametrization of the broadening effect and a self-consistent way to evaluate calibration measurements using a Markov chain Monte Carlo (MCMC) method. We further outline how to consistently derive particle number size distributions with realistic uncertainty estimates within this new framework. Based on measurements of particle standards for two OPCs, the Grimm model 1.129 (SkyOPC) and the DMT Passive Cavity Aerosol Spectrometer Probe (PCASP), we demonstrate that residuals between measured and modeled response can be substantially reduced when using the new approach instead of existing methods. More importantly, for the investigated set of measurements only the new approach yields results that conform with the true size distributions within the range of model uncertainty. The presented innovations will help improving the accuracy of OPC-derived size distributions and the assessment of their precision.© Author(s) 201

Evaluation of ECMWF-IFS (version 41R1) operational model forecasts of aerosol transport by using ceilometer network measurements

In this paper, we present a comparison of model simulations of aerosol profiles with measurements of the ceilometer network operated by the German Weather Service (DWD) over 1 year from September 2015 to August 2016. The aerosol forecasts are produced by the Copernicus Atmosphere Monitoring Service (CAMS) using the aerosol module developed within the Global and regional Earth-system Monitoring using Satellite and in-situ data (GEMS) and Monitoring Atmospheric Composition and Climate (MACC) projects and coupled into the European Centre for Medium-Range Weather Forecasts Integrated Forecasting System (ECMWF-IFS). As the model output provides mass mixing ratios of different types of aerosol, whereas the ceilometers do not, it is necessary to determine a common physical quantity for the comparison. We have chosen the attenuated backscatter β∗ for this purpose. The β∗ profiles are calculated from the mass mixing ratios of the model output assuming the inherent aerosol microphysical properties. Comparison of the attenuated backscatter averaged between an altitude of 0.2 km (typical overlap range of ceilometers) and 1 km in general shows similar annual average values. However, the standard deviation of the difference between model and observation is larger than the average in 8 out of 12 sites. To investigate possible reasons for the differences, we have examined the role of the hygroscopic growth of particles and the particle shape. Our results show that using a more recent particle growth model would result in a ∼22 % reduction of particle backscatter for sea salt aerosols, corresponding to a 10 % reduction of the total backscatter signal on average. Accounting for nonspherical dust particles in the model would reduce attenuated backscatter of dust particles by ∼30 %. As the concentration of dust aerosol is in general very low in Germany, a significant effect on the total backscatter signal is restricted to dust episodes. In summary, consideration of both effects tends to improve the agreement between model and observations but without leading to a perfect consistency. In addition, a strong Saharan dust event was investigated to study the agreement of the spatiotemporal distribution of particles. It was found that the arrival time of the dust layer and its vertical extent very well agree between model and ceilometer measurements for several stations. This underlines the potential of a network of ceilometers to validate the dispersion of aerosol layers.© Author(s) 201

Triple-wavelength depolarization-ratio profiling of Saharan dust over Barbados during SALTRACE in 2013 and 2014

Triple-wavelength polarization lidar measurements in Saharan dust layers were performed at Barbados (13.1°N, 59.6°W), 5000–8000km west of the Saharan dust sources, in the framework of the Saharan Aerosol Long-range Transport and Aerosol-Cloud-Interaction Experiment (SALTRACE-1, June–July 2013, SALTRACE-3, June–July 2014). Three case studies are discussed. High quality was achieved by comparing the dust linear depolarization ratio profiles measured at 355, 532, and 1064nm with respective dual-wavelength (355, 532nm) depolarization ratio profiles measured with a reference lidar. A unique case of long-range transported dust over more than 12000km is presented. Saharan dust plumes crossing Barbados were measured with an airborne triple-wavelength polarization lidar over Missouri in the midwestern United States 7 days later. Similar dust optical properties and depolarization features were observed over both sites indicating almost unchanged dust properties within this 1 week of travel from the Caribbean to the United States. The main results of the triple-wavelength polarization lidar observations in the Caribbean in the summer seasons of 2013 and 2014 are summarized. On average, the particle linear depolarization ratios for aged Saharan dust were found to be 0.252±0.030 at 355nm, 0.280±0.020 at 532nm, and 0.225±0.022 at 1064nm after approximately 1 week of transport over the tropical Atlantic. Based on published simulation studies we present an attempt to explain the spectral features of the depolarization ratio of irregularly shaped mineral dust particles, and conclude that most of the irregularly shaped coarse-mode dust particles (particles with diameters > 1µm) have sizes around 1.5–2µm. The SALTRACE results are also set into the context of the SAMUM-1 (Morocco, 2006) and SAMUM-2 (Cabo Verde, 2008) depolarization ratio studies. Again, only minor changes in the dust depolarization characteristics were observed on the way from the Saharan dust sources towards the Caribbean.© Author(s) 201