Iron Oxide Nanoparticles Employed as Seeds for the Induction of Microcrystalline Diamond Synthesis

Iron nanoparticles were employed to induce the synthesis of diamond on molybdenum, silicon, and quartz substrates. Diamond films were grown using conventional conditions for diamond synthesis by hot filament chemical vapor deposition, except that dispersed iron oxide nanoparticles replaced the seeding. X-ray diffraction, visible, and ultraviolet Raman Spectroscopy, energy-filtered transmission electron microscopy , electron energy-loss spectroscopy, and X-ray photoelectron spectroscopy (XPS) were employed to study the carbon bonding nature of the films and to analyze the carbon clustering around the seed nanoparticles leading to diamond synthesis. The results indicate that iron oxide nanoparticles lose the O atoms, becoming thus active C traps that induce the formation of a dense region of trigonally and tetrahedrally bonded carbon around them with the ensuing precipitation of diamond-type bonds that develop into microcrystalline diamond films under chemical vapor deposition conditions. This approach to diamond induction can be combined with dip pen nanolithography for the selective deposition of diamond and diamond patterning while avoiding surface damage associated to diamond-seeding methods

Superhard Phases of Simple Substances and Binary Compounds of the B-C-N-O System: from Diamond to the Latest Results (a Review)

The basic known and hypothetic one- and two-element phases of the B-C-N-O system (both superhard phases having diamond and boron structures and precursors to synthesize them) are described. The attention has been given to the structure, basic mechanical properties, and methods to identify and characterize the materials. For some phases that have been recently described in the literature the synthesis conditions at high pressures and temperatures are indicated.Comment: Review on superhard B-C-N-O phase

Complex heterogeneous precipitation in titanium-niobium microalloyed Al-killed HSLA steels-II. Non-titanium based particles

An analytical electron microscopical investigation of three Ti-Nb Al deoxidized steels with different N:Ti ratios has been undertaken. In each steel, a large number of small (<10 nm) particles were observed. Parallel electron energy loss spectroscopy (PEELS) showed that their compositions in the three steels were consistent with those reported for the caps on the TiN cores in the equivalent steels in Part I, i.e. NbC0.7N0.3, NbC and (Nb0.7Ti0.3)C, respectively. The Nb incorporated in these caps added to that dissolved in the TiN cores results in a significant reduction in the number of small particles which give effective dispersion hardening. The size of this reduction depends on a number of competing factors. AlN precipitation also occurred in the as-rolled steel with highest N content and in the normalized steels with the two higher N contents. AlN is usually expected to control the austenite grain growth. NbC-based material grew on the AlN. A dendritic complex based on the iso-structural compounds MnSiN2 and AlN was observed in the high N steel

Complex heterogeneous precipitation in titanium-niobium microalloyed Al-killed HSLA steels-I. (Ti,Nb)(C,N) particles

Precipitation in Ti-Nb Al-killed microalloyed HSLA steels (Ti/N weight ratio from 4.4 to 1) was investigated in both the as-rolled and the normalised conditions using analytical electron microscopy including parallel electron energy loss spectroscopy (PEELS). An extensive formation of heterogeneously nucleated complex (Ti,Nb)(C,N) particles down to 10 nm in size was observed. The core of such a complex particle is based on TiN and has a spherical, cubic or cruciform shape. The N/(Ti+Nb) atomic ratio in the core is similar to the average value in the steel whereas the Nb/Ti ratio is much smaller than the average value and not proportional to it. Many of the cores have caps in the form of epitaxial overgrowths based on NbC. Their composition changes from Nb(C,N) to (Nb,Ti)C as the N/Ti ratio decreases. The formation of these complex particles and their detailed morphology are controlled by the processing conditions as well as the overall composition

Roughness and Angularity of Fragments from Meteorite Disruption Experiments

In this study, we set out to explore the relationship between fracture roughness and sample strength. We analyze 45 fragments of Aba Panu, Allende, and Tamdakht, three meteorites that have been strength-tested to disruption, to determine whether their shape or texture is correlated with measured compressive strength. A primary goal is to understand whether these exterior properties correlate with more challenging strength-related measurements. We first scan the samples and construct high-fidelity 3D models. The gradient-based angularity index AIg and the rms slope roughness metric θ rms are applied to all nine samples, and their validity and any correlation between them are analyzed. We find that different sample subsets show significant variation in both correlation strength and direction. We also find AIg to be of questionable validity in its application to highly angular samples. Based on our methodology and results, we do not find sufficient separation between the roughness values of samples to allow distinct identification of the three meteorites based on roughness alone. Additionally, neither metric shows a strong correlation with the strength of individual fragments. We do find, however, that the spread of the fragment strength distribution within a given meteorite has some correlation with its average roughness metric. Increased fragment roughness may imply greater structural heterogeneity and therefore potentially weaker behavior at larger sizes. We only have significant data sets for two meteorites, however, which are insufficient to correlate meteorite fracture roughness to meteorite strength in any simple way. © 2023. The Author(s). Published by the American Astronomical Society.Open access journalThis item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]

Bonding in alpha-quartz (SiO2): A view of the unoccupied states

High-resolution core-loss and low-loss spectra of alpha-quartz were acquired by electron energyloss spectroscopy (EELS) with a transmission electron microscope (TEM). Spectra contain the Si L-1, L-2,L-3, K, and O K core-loss edges, and the surface and bulk low-loss spectra. The core-loss edges represent the atom- projected partial densities of states of the excited atoms and provide information on the unoccupied s, p, and d states as a function of energy above the edge onset. The band structure and total density of states were calculated for alpha-quartz using a self-consistent pseudopotential method. Projected local densities of Si and O s, p, and d states (LDOS) were calculated and compared with the EELS core-loss edges. These LDOS successfully reproduce the dominant Si and O core-loss edge shapes up to ca. 15 eV above the conduction-band onset. In addition, the calculations provide evidence for considerable charge transfer From Si to O and suggest a marked ionicity of the Si-O bond. The experimental and calculated data indicate that O 2p-Si d pi-type bonding is minimal. The low-loss spectra exhibit four peaks that are assigned to transitions from maxima in the valence-band density of states to the conduction band. A band gap of 9.65 eV is measured from the low-loss spectrum. The structures of the surface low-loss spectrum are reproduced by the joint density of states derived from the band-structure calculation. This study provides a detailed description of the unoccupied DOS of alpha-quartz by comparing the core-loss edges and low-loss spectrum, on a relative energy scale and relating the spectral features to the atom- and angular-momentum- resolved components of a pseudopotential band-structure calculation

Hypervelocity Impact Experiments in Iron‐Nickel Ingots and Iron Meteorites: Implications for the NASA Psyche Mission

The National Aeronautics and Space Administration (NASA) Psyche mission will visit the 226-km diameter main belt asteroid (16) Psyche, our first opportunity to visit a metal-rich object at close range. The unique and poorly understood nature of Psyche offers a challenge to the mission as we have little understanding of the surface morphology and composition. It is commonly accepted that the main evolutionary process for asteroid surfaces is impact cratering. While a considerable body of literature is available on collisions on rocky/icy objects, less work is available for metallic targets with compositions relevant to Psyche. Here we present a suite of impact experiments performed at the NASA Ames Vertical Gun Range facility on several types of iron meteorites and foundry-cast ingots that have similar Fe-Ni compositions as the iron meteorites. Our experiments were designed to better understand crater formation (e.g., size, depth), over a range of impact conditions, including target temperature and composition. We find that the target strength, as inferred from crater sizes, ranges from 700 to 1,300 MPa. Target temperature has measurable effects on strength, with cooled targets typically 10-20% stronger. Crater morphologies are characterized by sharp, raised rims and deep cavities. Further, we derive broad implications for Psyche's collisional evolution, in light of available low resolution shape models. We find that the number of large craters (>50 km) is particularly diagnostic for the overall bulk strength of Psyche. If confirmed, the number of putative large craters may indicate that Psyche's bulk strength is significantly reduced compared to that of intact iron meteorites. Plain Language Summary Many iron meteorites are thought to be remnants of the cores of melted asteroids. Some cores may have been exposed by collisions during the earliest days of Solar System history, with a few survivors possibly found today in the main asteroid belt. National Aeronautics and Space Administration (NASA) Psyche mission will be the first spacecraft to visit asteroid (16) Psyche, an object thought to be representative of these metallic asteroids. Impacts onto (16) Psyche in the past may therefore be able to tell us about the history and nature of this body. To this end, we performed high-speed impact experiments into metallic targets in order to understand how crater formation differs from rocky bodies. These experiments revealed that impact craters into metal targets are deeper and have sharper rims than on their rocky counterparts. These results will be crucial for interpreting both the bulk properties of Psyche's interior and the modification of Psyche's surface when the Psyche mission reaches its target.6 month embargo; first published online 24 October 2019This item from the UA Faculty Publications collection is made available by the University of Arizona with support from the University of Arizona Libraries. If you have questions, please contact us at [email protected]