A supramolecular peptide nanofiber templated Pd nanocatalyst for efficient Suzuki coupling reactions under aqueous conditions

Cataloged from PDF version of article.A bioinspired peptide amphiphile nanofiber template for formation of one-dimensional Pd nanostructures is demonstrated. The Pd and peptide nanocatalyst system enabled efficient catalytic activity in Suzuki coupling reactions in water at room temperature. The nanocatalyst system can be easily separated and reused in successive reactions without significant loss in activity and structural integrity. This journal is © 2012 The Royal Society of Chemistry

Theory of superconducting and magnetic proximity effect in S∣\midF structures with inhomogeneous magnetization textures and spin-active interfaces

We present a study of the proximity effect and the inverse proximity effect in a superconductor$\mid$ferromagnet bilayer, taking into account several important factors which mostly have been ignored in the literature so far. These include spin-dependent interfacial phase shifts (spin-DIPS) and inhomogeneous textures of the magnetization in the ferromagnetic layer, both of which are expected to be present in real experimental samples. Our approach is numerical, allowing us to access the full proximity effect regime. In Part I of this work, we study the superconducting proximity effect and the resulting local density of states in an inhomogeneous ferromagnet with a non-trivial magnetic texture. Our two main results in Part I are a study of how Bloch and N\'eel domain walls affect the proximity-induced superconducting correlations and a study of the superconducting proximity effect in a conical ferromagnet. The latter topic should be relevant for the ferromagnet Ho, which was recently used in an experiment to demonstrate the possibility to generate and sustain long-range triplet superconducting correlations. In Part II of this work, we investigate the inverse proximity effect with emphasis on the induced magnetization in the superconducting region as a result of the "leakage" from the ferromagnetic region. It is shown that the presence of spin-DIPS modify conclusions obtained previously in the literature with regard to the induced magnetization in the superconducting region. In particular, we find that the spin-DIPS can trigger an anti-screening effect of the magnetization, leading to an induced magnetization in the superconducting region with \textit{the same sign} as in the proximity ferromagnet.Comment: 16 pages, 18 figures. Accepted for publication in Phys. Rev.

Amyloid-like peptide nanofiber templated titania nanostructures as dye sensitized solar cell anodic materials

Cataloged from PDF version of article.One-dimensional titania nanostructures can serve as a support for light absorbing molecules and result in an improvement in the short circuit current (Jsc) and open circuit voltage (Voc) as a nanostructured and high-surface-area material in dye-sensitized solar cells. Here, self-assembled amyloid-like peptide nanofibers were exploited as an organic template for the growth of one-dimensional titania nanostructures. Nanostructured titania layers were utilized as anodic materials in dye sensitized solar cells (DSSCs). The photovoltaic performance of the DSSC devices was assessed and an enhancement in the overall cell performance compared to unstructured titania was observed. © 2013 The Royal Society of Chemistry

Spin screening of magnetic moments in superconductors

We consider ferromagnetic particles embedded into a superconductor and study the screening of their magnetic moments by the spins of the Cooper pairs in the superconductor. It is shown that a magnetic moment opposite to the one of the ferromagnetic particle is induced in the superconductor. In the case of a small itinerant ferromagnet grain and low temperatures the full screening of the magnetic moment takes place, \textit{% i.e} the absolute value of the total magnetic moment induced in the superconductor is equal to the one of the ferromagnetic particle. In type II superconductors the proposed screening by spins of the conduction electrons can be much stronger than the conventional screening by Meissner currents.Comment: 7 pages; 2 figure

Spin Screening and Antiscreening in a Ferromagnet/Superconductor Heterojunction

We present a theoretical study of spin screening effects in a ferromagnet/superconductor (F/S) heterojunction. It is shown that the magnetic moment of the ferromagnet is screened or antiscreened, depending on the polarization of the electrons at the Fermi level. If the polarization is determined by the electrons of the majority (minority) spin band then the magnetic moment of the ferromagnet is screened (antiscreened) by the electrons in the superconductor. We propose experiments that may confirm our theory: for ferromagnetic alloys with certain concentration of Fe or Ni ions there will be screening or antiscreening respectively. Different configurations for the density of states are also discussed.Comment: 5 pages; 4 figures. to be published in Phys. Rev,

Electromagnetic mass of an electron in one-dimensional photonic crystal

© Published under licence by IOP Publishing Ltd. Electromagnetic mass of an electron in one-dimensional photonic crystal is investigated. The exact expression describing the dependence of this mass on the angular coordinate of the electron's momentum is derived

Oscillations of Induced Magnetization in Superconductor-Ferromagnet Heterostructures

We study a change in the spin magnetization of a superconductor-ferromagnet (SF) heterostructure, when temperature is lowered below the superconducting transition temperature. It is assumed that the SF interface is smooth on the atomic scale and the mean free path is not too short. Solving the Eilenberger equation we show that the spin magnetic moment induced in the superconductor is an oscillating sign-changing function of the product $hd$ of the exchange field $h$ and the thickness $d$ of the ferromagnet. Therefore the total spin magnetic moment of the system in the superconducting state can be not only smaller (screening) but also greater (anti-screening) than that in the normal state, in contrast with the case of highly disordered (diffusive) systems, where only screening is possible. This surprising effect is due to peculiar periodic properties of localized Andreev states in the system. It is most pronounced in systems with ideal ballistic transport (no bulk disorder in the samples, smooth ideally transparent interface), however these ideal conditions are not crucial for the very existence of the effect. We show that oscillations exist (although suppressed) even for arbitrary low interface transparency and in the presence of bulk disorder, provided that $h \tau \gg 1$ ($\tau$ -- mean free path). At low interface transparency we solve the problem for arbitrary strength of disorder and obtain oscillating magnetization in ballistic regime ($h \tau \gg 1$) and nonoscillating magnetization in diffusive one ($h \tau \ll 1$) as limiting cases of one formula.Comment: 10 pages, 2 figures, accepted for publication in Phys. Rev.

One-Dimensional Peptide Nanostructure Templated Growth of Iron Phosphate Nanostructures for Lithium-Ion Battery Cathodes

© 2016 American Chemical Society.Template-directed synthesis of nanomaterials can provide benefits such as small crystalline size, high surface area, large surface-to-volume ratio, and structural stability. These properties are important for shorter distance in ion/electron movement and better electrode surface/electrolyte contact for energy storage applications. Here nanostructured FePO4 cathode materials were synthesized by using peptide nanostructures as a template inspired by biomineralization process. The amorphous, high surface area FePO4 nanostructures were utilized as a cathode for lithium-ion batteries. Discharge capacity of 155 mAh/g was achieved at C/20 current rate. The superior properties of biotemplated and nanostructured amorphous FePO4 are shown compared to template-free crystalline FePO4

One-Dimensional Peptide Nanostructure Templated Growth of Iron Phosphate Nanostructures for Lithium-Ion Battery Cathodes

© 2016 American Chemical Society.Template-directed synthesis of nanomaterials can provide benefits such as small crystalline size, high surface area, large surface-to-volume ratio, and structural stability. These properties are important for shorter distance in ion/electron movement and better electrode surface/electrolyte contact for energy storage applications. Here nanostructured FePO4 cathode materials were synthesized by using peptide nanostructures as a template inspired by biomineralization process. The amorphous, high surface area FePO4 nanostructures were utilized as a cathode for lithium-ion batteries. Discharge capacity of 155 mAh/g was achieved at C/20 current rate. The superior properties of biotemplated and nanostructured amorphous FePO4 are shown compared to template-free crystalline FePO4

Size-controlled conformal nanofabrication of biotemplated three-dimensional TiO2 and ZnO nanonetworks

Cataloged from PDF version of article.A solvent-free fabrication of TiO2 and ZnO nanonetworks is demonstrated by using supramolecular nanotemplates with high coating conformity, uniformity, and atomic scale size control. Deposition of TiO2 and ZnO on three-dimensional nanofibrous network template is accomplished. Ultrafine control over nanotube diameter allows robust and systematic evaluation of the electrochemical properties of TiO2 and ZnO nanonetworks in terms of size-function relationship. We observe hypsochromic shift in UV absorbance maxima correlated with decrease in wall thickness of the nanotubes. Photocatalytic activities of anatase TiO2 and hexagonal wurtzite ZnO nanonetworks are found to be dependent on both the wall thickness and total surface area per unit of mass. Wall thickness has effect on photoexcitation properties of both TiO2 and ZnO due to band gap energies and total surface area per unit of mass. The present work is a successful example that concentrates on nanofabrication of intact three-dimensional semiconductor nanonetworks with controlled band gap energies