Large transverse field tunnel splittings in the Fe_8 spin Hamiltonian

The spin Hamiltonian that describes the molecular magnet Fe$_8$ has biaxial symmetry with mutually perpendicular easy, medium, and hard magnetic axes. Previous calculations of the ground state tunnel splittings in the presence of a magnetic field along the hard axis are extended, and the meaning of the previously discovered oscillation of this splitting is further clarified

Diabolical points in the magnetic spectrum of Fe_8 molecules

The magnetic molecule Fe_8 has been predicted and observed to have a rich pattern of degeneracies in its spectrum as an external magnetic field is varied. These degeneracies have now been recognized to be diabolical points. This paper analyzes the diabolicity and all essential properties of this system using elementary perturbation theory. A variety of arguments is gievn to suggest that an earlier semiclassical result for a subset of these points may be exactly true for arbitrary spinComment: uses europhys.sty package; 3 embedded ps figure

Oscillatory Tunnel Splittings in Spin Systems: A Discrete Wentzel-Kramers-Brillouin Approach

Certain spin Hamiltonians that give rise to tunnel splittings that are viewed in terms of interfering instanton trajectories, are restudied using a discrete WKB method, that is more elementary, and also yields wavefunctions and preexponential factors for the splittings. A novel turning point inside the classically forbidden region is analysed, and a general formula is obtained for the splittings. The result is appled to the \Fe8 system. A previous result for the oscillation of the ground state splitting with external magnetic field is extended to higher levels.Comment: RevTex, one ps figur

Quenched Spin Tunneling and Diabolical Points in Magnetic Molecules: II. Asymmetric Configurations

The perfect quenching of spin tunneling first predicted for a model with biaxial symmetry, and recently observed in the magnetic molecule Fe_8, is further studied using the discrete phase integral (or Wentzel-Kramers-Brillouin) method. The analysis of the previous paper is extended to the case where the magnetic field has both hard and easy components, so that the Hamiltonian has no obvious symmetry. Herring's formula is now inapplicable, so the problem is solved by finding the wavefunction and using connection formulas at every turning point. A general formula for the energy surface in the vicinity of the diabolo is obtained in this way. This formula gives the tunneling apmplitude between two wells unrelated by symmetry in terms of a small number of action integrals, and appears to be generally valid, even for problems where the recursion contains more than five terms. Explicit results are obtained for the diabolical points in the model for Fe_8. These results exactly parallel the experimental observations. It is found that the leading semiclassical results for the diabolical points appear to be exact, and the points themselves lie on a perfect centered rectangular lattice in the magnetic field space. A variety of evidence in favor of this perfect lattice hypothesis is presented.Comment: Revtex; 4 ps figures; follow up to cond-mat/000311

Spin Tunneling in Magnetic Molecules: Quasisingular Perturbations and Discontinuous SU(2) Instantons

Spin coherent state path integrals with discontinuous semiclassical paths are investigated with special reference to a realistic model for the magnetic degrees of freedom in the Fe8 molecular solid. It is shown that such paths are essential to a proper understanding of the phenomenon of quenched spin tunneling in these molecules. In the Fe8 problem, such paths are shown to arise as soon as a fourth order anisotropy term in the energy is turned on, making this term a singular perturbation from the semiclassical point of view. The instanton approximation is shown to quantitatively explain the magnetic field dependence of the tunnel splitting, as well as agree with general rules for the number of quenching points allowed for a given value of spin. An accurate approximate formula for the spacing between quenching points is derived

Spin Tunneling, Berry phases and Doped Antiferromagnets

Interference effects between Berry phase factors in spin tunneling systems have been discussed in recent Letters by Loss, DiVincenzo and Grinstein and von Delft and Henley. This Comment points out that Berry phases in spin tunneling are important in another interesting case: the two dimensional doped antiferromagnet. I show that the dispersion of a single hole in the t-J model changes sign as $e^{2\pi s}$ where $s$ is the size of the spins. This provides an interpretation of the numerical results for the s=\half model, and a prediction for other spin sizes.Comment: 5 pages, LaTe

European household waste management schemes: Their effectiveness and applicability in England.

This paper reviews European household waste management schemes and provides an insight into their effectiveness in reducing or diverting household waste. The paper also considers the feasibility of replicating such schemes in England. Selected case studies include those implemented using variable charging schemes, direct regulation and household incentivisation (reduced disposal charges). A total of 15 case studies were selected from developed countries in the EU where some schemes have operated for more than a decade. Criteria for assessing the effectiveness and replicability of schemes were developed using scheme progress towards targets, response time, compatibility with government policy, ease of administration and operation, and public acceptance as attributes. The study demonstrates the capability of these schemes to significantly reduce household waste and suggests changes to allow their possible adoption in England. One of the main barriers to their adoption is the Environmental Protection Act, 1990 that prevents English local authorities (LAs) from implementing the variable charging method for household waste management. This barrier could be removed through a change in legislation. The need to derive consistent data and standardise the method of measuring the effectiveness of schemes is also highlighted

Spin tunnelling in mesoscopic systems

We study spin tunnelling in molecular magnets as an instance of a mesoscopic phenomenon, with special emphasis on the molecule Fe8. We show that the tunnel splitting between various pairs of Zeeman levels in this molecule oscillates as a function of applied magnetic field, vanishing completely at special points in the space of magnetic fields, known as diabolical points. This phenomena is explained in terms of two approaches, one based on spin-coherent-state path integrals, and the other on a generalization of the phase integral (or WKB) method to difference equations. Explicit formulas for the diabolical points are obtained for a model Hamiltonian.Comment: 13 pages, 5 figures, uses Pramana style files; conference proceedings articl

Macroscopic Quantum Coherence in a Magnetic Nanoparticle Above the Surface of a Superconductor

We study macroscopic quantum tunneling of the magnetic moment in a single-domain particle placed above the surface of a superconductor. Such a setup allows one to manipulate the height of the energy barrier, preserving the degeneracy of the ground state. The tunneling amplitude and the effect of the dissipation in the superconductor are computed.Comment: RevTeX, 4 pages, 1 figure. Submitted to Phys. Rev. Let