Bis(μ-3-nitro­phthalato-κ2 O 1:O 2)bis­[(thio­urea-κS)zinc] dihydrate

In the title complex, [Zn2(C8H3NO6)2(CH4N2S)4]·2H2O, the carboxyl­ate groups of the 3-nitro­phthalate ligands coordinate in a bis-monodentate mode to the ZnII cations. This results in the formation of a centrosymmetric dimer containing two ZnII cations with distorted tetra­hedral geometries provided by the O atoms of two different 3-nitro­phthalate dianions and the S atoms of two non-equivalent coordinated thio­urea mol­ecules. The crystal structure exhibits N—H⋯O and O—H⋯O hydrogen bonds which link the dimers into a three-dimensional network

The Analysis of the Properties of Bus Network Topology in Beijing Basing on Complex Networks

The transport network structure plays a crucial role in transport dynamics. To better understand the property of the bus network in big city and reasonably configure the bus lines and transfers, this paper seeks to take the bus network of Beijing as an example and mainly use space L and space P to analyze the network topology properties. The approach is applied to all the bus lines in Beijing which includes 722 lines and 5421 bus station. In the first phase of the approach, space L is used. The results show that the bus network of Beijing is a scale-free network and the degree of more than 99 percent of nodes is lower than 10. The results also show that the network is an assortative network with 46 communities. In a second phase, space P is used to analyze the property of transfer. The results show that the average transfer time of Beijing bus network which is 1.88 and 99.8 percent of arbitrary two pair nodes is reachable within 4 transfers

Ionic polarization-induced current-voltage hysteresis in ch3nh3pbx3 perovskite solar cells

CH3NH3PbX3 (MAPbX3) perovskites have attracted considerable attention as absorber materials for solar light harvesting, reaching solar to power conversion efficiencies above 20%. In spite of the rapid evolution of the efficiencies, the understanding of basic properties of these semiconductors is still ongoing. One phenomenon with so far unclear origin is the so-called hysteresis in the current–voltage characteristics of these solar cells. Here we investigate the origin of this phenomenon with a combined experimental and computational approach. Experimentally the activation energy for the hysteretic process is determined and compared with the computational results. First-principles simulations show that the timescale for MAþ rotation excludes a MA-related ferroelectric effect as possible origin for the observed hysteresis. On the other hand, the computationally determined activation energies for halide ion (vacancy) migration are in excellent agreement with the experimentally determined values, suggesting that the migration of this species causes the observed hysteretic behaviour of these solar cells

Research on Public Transit Network Hierarchy Based on Residential Transit Trip Distance

To the problem of being lack of transit network hierarchy theory, a research on public transit network hierarchy optimization based on residential transit trip distance is conducted. Firstly, the hierarchy standard of transit network is given, in addition, both simulating electron cloud model and Rayleigh distribution model are used to fit the residential transit trip distance. Secondly, from the view of balance between supply and demand, the hierarchy step of transit network based on residential transit trip distance is proposed. Then, models of transit’s supply turnover and demand turnover are developed. Finally, the method and models are applied into transit network optimization of Baoding, Hebei, China