Epoxy-based paints from glycolysis products of postconsumer PET bottles: synthesis, wet paint properties and film properties

Glycolysis of waste polyethylene terephthalate (PET) flakes obtained from grinding postconsumer bottles was carried out at 180-190A degrees C, and molar ratios of PET/EG were taken as 1/6. Reaction product was extracted by hot water, and water soluble crystallizable fraction and water insoluble fraction were obtained. These fractions were characterized by hydroxyl value determination. Water soluble crystallizable fraction obtained from glycolysis product was used for synthesis of PET-based epoxy resin. Two epoxy-based paints were prepared using different amounts of PET-based epoxy resin. Wet paint properties, and chemical and physical film properties of paints containing waste PET were determined. Increasing the rate of PET-based epoxy resin in paint formulation did not have a negative effect on the wet paint properties and dry film properties of epoxy-based paints containing waste PET

Effects of Remote Ischemic Conditioning Methods on Ischemia-Reperfusion Injury in Muscle Flaps: An Experimental Study in Rats

Background The aim of this study was to investigate the effects of remote ischemic conditioning on ischemia-reperfusion injury in rat muscle flaps histopathologically and biochemically. Methods Thirty albino rats were divided into 5 groups. No procedure was performed in the rats in group 1, and only blood samples were taken. A gracilis muscle flap was elevated in all the other groups. Microclamps were applied to the vascular pedicle for 4 hours in order to achieve tissue ischemia. In group 2, no additional procedure was performed. In groups 3, 4, and 5, the right hind limb was used and 3 cycles of ischemia-reperfusion for 5 minutes each (total, 30 minutes) was applied with a latex tourniquet (remote ischemic conditioning). In group 3, this procedure was performed before flap elevation (remote ischemic preconditoning). In group 4, the procedure was performed 4 hours after flap ischemia (remote ischemic postconditioning). In group 5, the procedure was performed after the flap was elevated, during the muscle flap ischemia episode (remote ischemic perconditioning). Results The histopathological damage score in all remote conditioning ischemia groups was lower than in the ischemic-reperfusion group. The lowest histopathological damage score was observed in group 5 (remote ischemic perconditioning). Conclusions The nitric oxide levels were higher in the blood samples obtained from the remote ischemic perconditioning group. This study showed the effectiveness of remote ischemic conditioning procedures and compared their usefulness for preventing ischemia-reperfusion injury in muscle flaps

Fairness and feasibility in deep mitigation pathways with novel carbon dioxide removal considering institutional capacity to mitigate

Questions around the technical and political feasibility of deep mitigation scenarios assessed by the Intergovernmental Panel on Climate Change have increasingly been raised as have calls for more directly analyzing and incorporating aspects of justice and fairness. Simultaneously, models are increasing the technical representation of novel carbon-dioxide removal (CDR) approaches to provide policy-relevant analyses of mitigation portfolios in the context of the rising number of net-zero CO _2 and GHG targets made by parties to the Paris Agreement. Still, in most cost-effective mitigation scenarios developed by integrated assessment models, a significant portion of mitigation is assumed to take place in developing regions. We address these intersecting questions through analyzing scenarios that include direct air capture of CO _2 with storage (DACCS), a novel CDR technology that is not dependent on land potential and can be deployed widely, as well as regional variations in institutional capacity for mitigation based on country-level governance indicators. We find that including novel CDR and representations of institutional capacity can enhance both the feasibility and fairness of 2 °C and 1.5 °C high-overshoot scenarios, especially in the near term, with institutional capacity playing a stronger role than the presence of additional carbon removal methods. However, our results indicate that new CDR methods being studied by models are not likely to change regional mitigation outcomes of scenarios which achieve the 1.5 °C goal of the Paris Agreement. Thus, while engineered carbon removals like DACCS may play a significant role by midcentury, gross emissions reductions in mitigation pathways arriving at net-zero CO _2 emissions in line with 1.5 °C do not substantially change. Our results highlight that further investment and development of novel CDR is critical for post-net-zero CO _2 mitigation, but that equitable achievement of this milestone will need to arrive through technical and financial transfers, rather than by substantial carbon removals in developed countries before mid-century

Global roll-out of comprehensive policy measures may aid in bridging emissions gap

Closing the emissions gap between Nationally Determined Contributions (NDCs) and the global emissions levels needed to achieve the Paris Agreement's climate goals will require a comprehensive package of policy measures. National and sectoral policies can help fill the gap, but success stories in one country cannot be automatically replicated in other countries. They need to be adapted to the local context. Here, we develop a new Bridge scenario based on nationally relevant, short-term measures informed by interactions with country experts. These good practice policies are rolled out globally between now and 2030 and combined with carbon pricing thereafter. We implement this scenario with an ensemble of global integrated assessment models. We show that the Bridge scenario closes two-thirds of the emissions gap between NDC and 2 °C scenarios by 2030 and enables a pathway in line with the 2 °C goal when combined with the necessary long-term changes, i.e. more comprehensive pricing measures after 2030. The Bridge scenario leads to a scale-up of renewable energy (reaching 52%-88% of global electricity supply by 2050), electrification of end-uses, efficiency improvements in energy demand sectors, and enhanced afforestation and reforestation. Our analysis suggests that early action via good-practice policies is less costly than a delay in global climate cooperation

Global roll-out of comprehensive policy measures may aid in bridging emissions gap

Closing the emissions gap between Nationally Determined Contributions (NDCs) and the global emissions levels needed to achieve the Paris Agreement’s climate goals will require a comprehensive package of policy measures. National and sectoral policies can help fill the gap, but success stories in one country cannot be automatically replicated in other countries. They need to be adapted to the local context. Here, we develop a new Bridge scenario based on nationally relevant, short-term measures informed by interactions with country experts. These good practice policies are rolled out globally between now and 2030 and combined with carbon pricing thereafter. We implement this scenario with an ensemble of global integrated assessment models. We show that the Bridge scenario closes two-thirds of the emissions gap between NDC and 2 °C scenarios by 2030 and enables a pathway in line with the 2 °C goal when combined with the necessary long-term changes, i.e. more comprehensive pricing measures after 2030. The Bridge scenario leads to a scale-up of renewable energy (reaching 52%–88% of global electricity supply by 2050), electrification of end-uses, efficiency improvements in energy demand sectors, and enhanced afforestation and reforestation. Our analysis suggests that early action via good-practice policies is less costly than a delay in global climate cooperation