Photochromism in single nitrogen-vacancy defect in diamond

Photochromism in single nitrogen-vacancy optical centers in diamond is demonstrated. Time-resolved optical spectroscopy shows that intense irradiation at 514 nm switches the nitrogen-vacancy defects to the negative form. This defect state relaxes back to the neutral form under dark conditions. Temporal anticorrelation of photons emitted by the different charge states of the optical center unambiguously indicates that the nitrogen-vacancy defect accounts for both 575 nm and 638 nm emission bands. Possible mechanism of photochromism involving nitrogen donors is discussed.Comment: 11 pages, 3 figures, submitted to Applied Physics B: Lasers and Optic

Experimental open air quantum key distribution with a single photon source

We present a full implementation of a quantum key distribution (QKD) system with a single photon source, operating at night in open air. The single photon source at the heart of the functional and reliable setup relies on the pulsed excitation of a single nitrogen-vacancy color center in diamond nanocrystal. We tested the effect of attenuation on the polarized encoded photons for inferring longer distance performance of our system. For strong attenuation, the use of pure single photon states gives measurable advantage over systems relying on weak attenuated laser pulses. The results are in good agreement with theoretical models developed to assess QKD security