10 research outputs found

    Electronic Switch in the Carbon-Centered [Re<sub>12</sub>CS<sub>17</sub>(CN)<sub>6</sub>]<sup> <it>n</it>&#8722;</sup>Nanocluster

    No full text
    Abstract An abrupt change in internuclear Re&#8211;Re distances between {Re6} subunits in the carbon-centered [Re12&#956;6-CS17(CN)6] n&#8722;complexes caused by the change of the oxidation state (n = 6, 8) is first theoretically shown to be possibly controlled by an external electric field.13C NMR signal is shown to change over ~400 ppm (~37G) for &#956;6-C atom together withn. Thereby, the metal cluster [Re12&#956;6-CS17(CN)6] n&#8722;can be considered as a perspective model of a molecular switch.</p

    Nuclear Magnetic Resonance and Relaxation of Molecules Adsorbed on Solids

    No full text
    corecore