48 research outputs found
The effect of oxygen stoichiometry on electrical transport and magnetic properties of La0.9Te0.1MnOy
The effect of the variation of oxygen content on structural, magnetic and
transport properties in the electron-doped manganites La0.9Te0.1MnOy has been
investigated. All samples show a rhombohedral structure with the space group .
The Curie temperature decreases and the paramagnetic-ferromagnetic (PM-FM)
transition becomes broader with the reduction of oxygen content. The
resistivity of the annealed samples increases slightly with a small reduction
of oxygen content. Further reduction in the oxygen content, the resistivity
maximum increases by six orders of magnitude compared with that of the
as-prepared sample, and the r(T) curves of samples with y = 2.86 and y = 2.83
display the semiconducting behavior () in both high-temperature PM phase and
low-temperature FM phase, which is considered to be related to the appearance
of superexchange ferromagnetism (SFM) and the localization of carriers. The
results are discussed in terms of the combined effects of the increase in the
Mn2+/(Mn2++Mn3+) ratio, the partial destruction of double exchange (DE)
interaction, and the localization of carriers due to the introduction of oxygen
vacancies in the Mn-O-Mn network.Comment: 20 pages, 8 figure