Development of wood composites from recycled fibres bonded with magnesium lignosulfonate

The potential of producing ecofriendly composites from industrial waste fibres, bonded with magnesium lignosulfonate, a lignin-based formaldehyde-free adhesive, was investigated in this work. Composites were produced in the laboratory using the following parameters: a hot press temperature of 210 °C, a pressing time of 16 min, and a 15% gluing content of magnesium lignosulfonate (on the dry fibres). The physical and mechanical properties of the produced composites were evaluated and compared with the European Standard (EN) required properties (EN 312, EN 622-5) of common wood-based panels, such as particleboards for internal use in dry conditions (type P2), load-bearing particleboards for use in humid conditions (type P5), heavy-duty load-bearing particleboards for use in humid conditions (type P7), and medium-density fibreboards (MDF) for use in dry conditions. In general, the new produced composites exhibited satisfactory mechanical properties: a bending strength (MOR) (18.5 N•mm-2) that was 42% higher than that required for type P2 particleboards (13 Nmm-2) and 16% higher than that required for type P5 particleboards (16 N•mm-2). Additionally, the modulus of elasticity (MOE) of composites (2225 N•mm-2) was 24% higher than that required for type P2 particleboards (1800 N•mm-2) and equivalent to the required MOE of MDF panels for use in dry conditions (2200 N•mm-2). However, these ecofriendly composites showed deteriorated moisture properties, i.e., 24 h swelling and 24 h water absorption, which were a distinct disadvantage. This should be further investigated, as modifications in the lignosulfonate formula used and/or production parameters are necessary. © 2020 by the authors

Durability of accoya wood in ground stake testing after 10 years of exposure in Greece

In this research, acetylated wood (Accoya) was tested in ground contact in central Greece. After ten years of exposure during a ground stake test, acetylated pine wood (Pinus radiata) stakes, with a 20% acetyl weight gain, were completely intact and showed no visual decay (decay rating: 0). However, the key mechanical properties of Accoya wood, that is, modulus of elasticity (MOE) and modulus of rupture (MOR) after 10 years of ground contact, were significantly reduced by 32.8% and 29.6%, respectively, despite an excellent visual result since no evidence of fungal attack was identified. This contradiction could possibly indicate that the hallmarks of decay, i.e., brownrot decay of acetylated wood can be the significant loss of mechanical properties before decay is actually visible. © 2020 by the authors. Licensee MDPI, Basel, Switzerland

Medium-density fibreboards bonded with phenol-formaldehyde resin and calcium lignosulfonate as an eco-friendly additive

The potential of addition of calcium lignosulfonate as an eco-friendly additive with a phenol-formaldehyde (PF) resin, at different ratios, to produce medium-density fibreboards (MDF) with acceptable properties, was investigated in this work. The fibreboards were fabricated in the laboratory with low PF resin percentage (3%, 4%, 5%), while the addition levels of calcium lignosulfonate varied from 5% to 15% (on the dry fibres). The physical and mechanical properties of the fibreboards were evaluated, and further statistically analysed in order to determine the optimal values of PF resin content and lignosulfonate addition for fulfilling the European standards. It was shown that at the low PF resin content (3%), addition of lignosulfonate should not exceed 10% to avoid deterioration in the mechanical properties. It was concluded that PF resin content of 3.5% can be recommended for the production of lignosulfonate-PF bonded MDF panels to comply with the EN standard requirements. © 2020 Informa UK Limited, trading as Taylor & Francis Group

Improving fire retardancy of medium density fiberboard by nano-wollastonite

The improving effects of addition of nano-wollastonite on some fire properties of medium-density fiberboard (MDF) were studied in this work. Nano-wollastonite was added at four levels (2%, 4%, 6%, and 8%). The size range of at least 70% of nano-wollastonite particles were 30 to 110 nm. The results showed statistically significant improving effect of nano-wollastonite on time to onset of ignition. The improving effect was primarily attributed to an increase in thermal conductivity of board containing nano-wollastonite. This increase in turn resulted in better curing of resin, and a higher integrity of fibers thereof. Moreover, nano-particles provided a surface with reduced combustibility and therefore, penetration of fire to the inner layers of boards was delayed, thus improving fire properties. High and significant correlations were found between thermal conductivity coefficients of boards with different fire properties. It was concluded that for applications where fire properties are of prime importance, nano-wollastonite content of 8% can be recommended. Moreover, further studies are needed to compare and standardize the results obtained from the apparatus used here with those obtained from internationally recognized apparatuses like cone calorimeter. © 2020 John Wiley & Sons Lt

Technological properties and fire performance of medium density fibreboard (MDF) treated with selected polyphosphate-based fire retardants

The objective of the work was to evaluate the efficacy of two new polyphosphate-based fire retardants (FRs) and one commercial product named Siriono® on the fire performance and physical–mechanical properties of medium density fibreboard (MDF) fabricated in the laboratory from Scots pine (Pinus sylvestris L.) wood. The fibres were treated with aqueous solutions of fire retardants, at 12% loading (dry salt on dry wood), and bonded with a melamine urea formaldehyde (MUF) adhesive. The physical and mechanical properties of panels were assessed using the European standards, whereas their fire performance was evaluated using an in-house method and the Cone calorimeter. In overall, the chemicals added enhanced the fire and smoke properties of the panels to varying degrees. Critical FR parameters such as peak heat release rate (peak HRR), total heat release (THR) and total smoke production (TSP) were significantly improved in the FR-treated panels, as exhibited in cone calorimeter tests. However, the internal bond strength of treated panels largely decreased by the addition of fire retardants, while thickness swell and water absorption negatively affected to a significant extent. In contrast, the formaldehyde release of the panels was considerably decreased at the E1 class level, with the incorporation of the polyphosphate-based additives. © 2019 Informa UK Limited, trading as Taylor & Francis Group

Fire performance and leach resistance of pine wood impregnated with guanyl-urea phosphate/boric acid and a melamine-formaldehyde resin

Scots pine (Pinus sylvestris L.) wood impregnated with guanyl-urea phosphate/boric acid and a melamine-formaldehyde resin exhibited considerably increased resistance to leaching, while sustaining superior fire retardancy as tested by the limiting oxygen index (LOI) method. It was found that guanyl-urea phosphate has been well trapped in the wood structure by the cured resin network as evidenced by FTIR spectroscopy. Markedly, weight percentage gain (WPG) losses of fire retardant as low as 7.4% were achieved after excessive leaching of treated wood (EN 84). This was attributed to the effect of melamine-formaldehyde resin. Overall, this type of treatment could be a reliable method for producing fire-resistant pine wood for exterior uses. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature

Furfurylation of tropical wood species with and without silver nanoparticles: Part I: Analysis with confocal laser scanning microscopy and FTIR spectroscopy

This work focused on the upgrading of non-durable tropical wood species originating from fast-growing plantations of Costa Rica. Modification of such tropical woods with furfuryl alcohol, although has not been broadly studied up to date, offers a potential way to increase their low durability. The purpose of this research was to investigate the modification effects on cell wall, vessels wall, radial and axial parenchyma using confocal laser scanning microscopy (CLSM) as well as the changes in the bands of chemical composition using Fourier-transform infrared spectroscopy (FTIR). In fact, nine tropical wood species such as Cedrela odorata, Cordia alliodora, Enterolobium cyclocarpum, Gmelina arborea, Hieronyma alchorneoides, Samanea saman, Tectona grandis, Vochysia ferruginea and Vochysia guatemalensis were treated with plain furfuryl alcohol (FA), and furfuryl alcohol combined with silver nanoparticles (FA-NPsAg). Furfurylation effects were also assessed by the weight percentage gain (WPG) of wood. Results showed that WPG varied from 14.4% to 44.3% with the FA treatment, and from 12.9% to 44.5% with the FA-NPsAg treatment. In the species which exhibited a WPG over 25% with the FA treatment, fluorescence at 600 nm band occurred mostly in the cell walls of fibres, while the furfurylation degree in radial and axial parenchyma was limited. Moreover, furfurylation occurred in lesser extent in wood species with high abundance of axial parenchyma as revealed by fluorescence. Wood species such as Vochysia ferruginea, Vochysia guatemalensis, Cedrela odorata, Samanea saman, Enterolobium cyclocarpum, which showed WPGs>25%, evidenced considerable changes in the lignin structure as observed in the FTIR spectra. In particular, with the FA treatment, the changes were observed in the bands of 1711, 1652, 1561, 889, 796 and 733 cm–1, whereas, with the FA-NPsAg treatment, the changes occurred in the bands of 1711, 1505, 1426, 1370, 1224 and 1016 cm–1. Overall, no significant difference was found in FTIR spectra and anatomical fluorescence between the FA and FA-NPsAg treatment, probably because the NPsAg concentration was insufficient for a change to occur in the bonds. © 2021 Informa UK Limited, trading as Taylor & Francis Group