119 research outputs found
On the theory of the ceramic densification process an of recrystallization in colloidal solutions
In a short survey the analogy between the theories on diffusion in solids and in solutions is shown. As a result, analogous theories are developed for the ceramic sintering process and the recrystallization in colloidal solutions. By a thermodynamic method a description is given of the available free energy, the diffusion flux and the driving force
The influence of foreign ions on the crystal lattice of barium titanate
From investigations of phase diagrams of ternary oxides the lattice sites of foreign ions and compensating vacancies are established. Large trivalent ions occupy barium sites and are completely compensated by titanium vacancies. Small pentavalent ions occupy titanium sites and are mainly compensated by titanium vacancies. During these investigations a new compound was found, Ba La4 Ti4 O15 isomorphous with Ba5 Nb4 O15
Phase diagrams of in Double Exchange Model with added antiferromagnetic and Jahn-Teller interaction
The phase diagram of the multivalent manganites , in
space of temperature and doping , is a challenge for the theoretical
physics. It is an important test for the model used to study these compounds
and the method of calculation. To obtain theoretically this diagram for
, we consider the two-band Double Exchange Model for manganites with
added Jahn-Teller coupling and antiferromagnetic Heisenberg term. In order to
calculate Curie and N\'{e}el temperatures we derive an effective Heisenberg
model for a vector which describes the local orientation of the total
magnetization of the system. The exchange constants of this model are different
for different space directions and depend on the density of electrons,
antiferromagnetic constants and the Jahn-Teller energy. To reproduce the well
known phase transitions from A-type antiferromagnetism to ferromagnetism at low
and C-type antiferromagnetism to G-type antiferromagnetism at large , we
argue that the antiferromagnetic exchange constants should depend on the
lattice direction. We show that ferromagnetic to A-type antiferromagnetic
transition results from the Jahn-Teller distortion. Accounting adequately for
the magnon-magnon interaction, Curie and N\'{e}el temperatures are calculated.
The results are in very good agreement with the experiment and provide values
for the model parameters, which best describe the behavior of the critical
temperature for .Comment: 13 pages, 5 figure
Colossal magnetooptical conductivity in doped manganites
We show that the current carrier density collapse in doped manganites, which
results from bipolaron formation in the paramagnetic phase, leads to a colossal
change of the optical conductivity in an external magnetic field at
temperatures close to the ferromagnetic transition. As with the colossal
magnetoresistance (CMR) itself, the corresponding magnetooptical effect is
explained by the dissociation of localized bipolarons into mobile polarons
owing to the exchange interaction with the localized Mn spins in the
ferromagnetic phase. The effect is positive at low frequencies and negative in
the high-frequency region. The present results agree with available
experimental observations.Comment: 4 pages, REVTeX 3.0, two eps-figures included in the tex
Evidence for a Low-Spin to Intermediate-Spin State Transition in LaCoO3
We present measurements of the magnetic susceptibility and of the thermal
expansion of a LaCoO single crystal. Both quantities show a strongly
anomalous temperature dependence. Our data are consistently described in terms
of a spin-state transition of the Co ions with increasing temperature
from a low-spin ground state to an intermediate-spin state without (100K -
500K) and with (>500K) orbital degeneracy. We attribute the lack of orbital
degeneracy up to 500K to (probably local) Jahn-Teller distortions of the
CoO octahedra. A strong reduction or disappearance of the Jahn-Teller
distortions seems to arise from the insulator-to-metal transition around 500 K.Comment: an error in the scaling factor of Eq.(4) and consequently 2 values of
table I have been corrected. The conclusions of the paper remain unchanged.
See also: C. Zobel et al. Phys. Rev. B 71, 019902 (2005) and J. Baier et al.
Phys. Rev. B 71, 014443 (2005
Interplay of superexchange and orbital degeneracy in Cr-doped LaMnO3
We report on structural, magnetic and Electron Spin Resonance (ESR)
investigations in the manganite system LaMn_{1-x}Cr_{x}O_{3} (x<=0.5). Upon
Cr-doping we observe a reduction of the Jahn-Teller distortion yielding less
distorted orthorhombic structures. A transition from the Jahn-Teller distorted
O' to the pseudocubic O phase occurs between 0.3<x<0.4. A clear connection
between this transition and the doping dependence of the magnetic and ESR
properties has been observed. The effective moments determined by ESR seem
reduced with respect to the spin-only value of both Mn^{3+} and Cr^{3+} ions
Ultrasonic evidence of an uncorrelated cluster formation temperature in manganites with first-order magnetic transition at T_C
Ultrasonic attenuation and phase velocity measurements have been carried out
in the ferromagnetic perovskites La_{2/3}Ca_{1/3}MnO_3 and
La_{2/3}Sr_{1/3}MnO_3. Data show that the transition at the Curie temperature,
T_C, changes from first- to second-order as Sr replaces Ca in the perovskite.
The compound with first-order transition shows also another transition at a
temperature T* > T_C. We interpret the temperature window T_C < T < T* as a
region of coexistence of a phase separated regime of metallic and insulating
regions, in the line of recent theoretical proposals.Comment: 4 pages, 2 figure
Ordering and Fluctuation of Orbital and Lattice Distortion in Perovskite Manganese Oxides
Roles of orbital and lattice degrees of freedom in strongly correlated
systems are investigated to understand electronic properties of perovskite Mn
oxides such as La_{1-x}Sr_{x}MnO_{3}. An extended double-exchange model
containing Coulomb interaction, doubly degenerate orbitals and Jahn-Teller
coupling is derived under full polarization of spins with two-dimensional
anisotropy. Quantum fluctuation effects of Coulomb interaction and orbital
degrees of freedom are investigated by using the quantum Monte Carlo method. In
undoped states, it is crucial to consider both the Coulomb interaction and the
Jahn-Teller coupling in reproducing characteristic hierarchy of energy scales
among charge, orbital-lattice and spin degrees of freedom in experiments. Our
numerical results quantitatively reproduce the charge gap amplitude as well as
the stabilization energy and the amplitude of the cooperative Jahn-Teller
distortion in undoped compounds. Upon doping of carriers, in the absence of the
Jahn-Teller distortion, critical enhancement of both charge compressibility and
orbital correlation length is found with decreasing doping concentration. These
are discussed as origins of strong incoherence in charge dynamics. With the
Jahn-Teller coupling in the doped region, collapse of the Jahn-Teller
distortion and instability to phase separation are obtained and favorably
compared with experiments. These provide a possible way to understand the
complicated properties of lightly doped manganites.Comment: 22 pages RevTeX including 25 PS figures, submitted to Phys.Rev.B,
replaced version; two figures are replaced by Fig.17 with minor changes in
the tex
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