The generalized representation of particle localization in quantum mechanics

It has been shown earlier that while strict localization of the free Dirac particle is not describable within the usual mathematical formalism, it is possible to describe sequences of positive-energy states whose spread Δ = 〈(x-x)〉 about any given point x approaches zero, where x is Dirac's position operator. The concept of a generalized function is extended here to allow for the succinct description of localized states in terms of "Asymptotic Localizing Functions." Localization of both the nonrelativistic particle and the Dirac particle can be adequately represented in this new formalism

Probability backflow and a new dimensionless quantum number

Pure states of a free particle in non-relativistic quantum mechanics are described, in which the probability of finding the particle to have a negative x-coordinate increases over an arbitrarily long, but finite, time interval, even though the x-component of the particle's velocity is certainly positive throughout that time interval. It is shown that, for any state of this type, the greatest amount of probability which can flow back from positive to negative x-values in this counter-intuitive way, over any given time interval, is equal to the largest eigenvalue of a certain Hermitian operator, and it is estimated numerically to have a value near 0.04. This value is not only independent of the length of the time interval and the mass of the particle, but is also independent of the value of Planck's constant. It reflects the structure of Schrodinger's equation, rather than the values of the parameters appearing there. Backflow of positive probability is related to the non-positivity of Wigner's density function, and can be regarded as arising from a flow of negative probability in the same direction as the velocity. Generalizations are indicated, to the relativistic free electron, and to non-relativistic cases in which probability backflow occurs even in opposition to an arbitrarily strong constant force