The effect of the powder average on the peak shapes and positions in neutron
pair distribution functions of polycrystalline materials is examined. It is
shown that for highly anisotropic crystals, the powder average leads to shifts
in peak positions and to non-Gaussian peak shapes. The peak shifts can be as
large as several percent of the lattice spacing
We report new accurate mesasurements of the mobility of excess electrons in
high density Helium gas in extended ranges of temperature [(26≤T≤77)K] and density [(0.05≤N≤12.0)atoms⋅nm−3] to ascertain
the effect of temperature on the formation and dynamics of localized electron
states. The main result of the experiment is that the formation of localized
states essentially depends on the relative balance of fluid dilation energy,
repulsive electron-atom interaction energy, and thermal energy. As a
consequence, the onset of localization depends on the medium disorder through
gas temperature and density. It appears that the transition from delocalized to
localized states shifts to larger densities as the temperature is increased.
This behavior can be understood in terms of a simple model of electron
self-trapping in a spherically symmetric square well.Comment: 23 pages, 13 figure
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