Designing sustainable medical devices

Stakeholders in the medical device manufacturing industry are becoming more concerned about the environmental impact of their products and processes. The consumers are also becoming more aware of the negative impact that manufacturers can have on the environment. Government initiatives continue to increase environmental awareness through the development of new policy and legislation, encouraging industry to become more accountable for the environmental impact of their products and operations. The ISO 14001 standard, Environmental Management Systems-Requirements with Guidance for Use, sets guidelines to enable businesses to recognize the environmental effects of their products and processes. Departments can use the tool to set targets to lower the environmental impact and identify areas of high environmental concern when designing, purchasing, and marketing products. Research in these areas will be used to develop the environmental scoring tool to aid in the design of future sustainable medical devices

X-ray Properties of Radio-Selected Dual Active Galactic Nuclei

Merger simulations predict that tidally induced gas inflows can trigger kpc-scale dual active galactic nuclei (dAGN) in heavily obscured environments. Previously with the Very Large Array, we have confirmed four dAGN with redshifts between $0.04 < z < 0.22$ and projected separations between 4.3 and 9.2 kpc in the SDSS Stripe 82 field. Here, we present $Chandra$ X-ray observations that spatially resolve these dAGN and compare their multi-wavelength properties to those of single AGN from the literature. We detect X-ray emission from six of the individual merger components and obtain upper limits for the remaining two. Combined with previous radio and optical observations, we find that our dAGN have properties similar to nearby low-luminosity AGN, and they agree well with the black hole fundamental plane relation. There are three AGN-dominated X-ray sources, whose X-ray hardness-ratio derived column densities show that two are unobscured and one is obscured. The low obscured fraction suggests these dAGN are no more obscured than single AGN, in contrast to the predictions from simulations. These three sources show an apparent X-ray deficit compared to their mid-infrared continuum and optical [OIII] line luminosities, suggesting higher levels of obscuration, in tension with the hardness-ratio derived column densities. Enhanced mid-infrared and [OIII] luminosities from star formation may explain this deficit. There is ambiguity in the level of obscuration for the remaining five components since their hardness ratios may be affected by non-nuclear X-ray emissions, or are undetected altogether. They require further observations to be fully characterized.Comment: 11 pages, 5 figures, Accepted for publication in the Astrophysical Journa

Digital modulation of the nickel valence state in a cuprate-nickelate heterostructure

Layer-by-layer oxide molecular beam epitaxy has been used to synthesize cuprate-nickelate multilayer structures of composition (La$_2$CuO$_4$)$_m$/LaO/(LaNiO$_3$)$_n$. In a combined experimental and theoretical study, we show that these structures allow a clean separation of dopant and doped layers. Specifically, the LaO layer separating cuprate and nickelate blocks provides an additional charge that, according to density functional theory calculations, is predominantly accommodated in the interfacial nickelate layers. This is reflected in an elongation of bond distances and changes in valence state, as observed by scanning transmission electron microscopy and x-ray absorption spectroscopy. Moreover, the predicted charge disproportionation in the nickelate interface layers leads to a thickness-dependent metal-to-insulator transition for $n=2$, as observed in electrical transport measurements. The results exemplify the perspectives of charge transfer in metal-oxide multilayers to induce doping without introducing chemical and structural disorder