Optimization of CCUS supply chains in the UK: A strategic role for emissions reduction

The UK is the second largest emitter of carbon dioxide in Europe. It aims to take urgent actions to achieve the 2030 target for CO_{2} emissions reduction imposed by EU environmental policies. Three different carbon capture utilization and storage (CCUS) supply chains are developed giving economic indicators for CO_{2} utilization routes not implying carbon dioxide hydrogenation (i.e. with high TRL). The study presents an innovative proposal to reduce CO_{2} impact in the UK, a country rich in coal, which requires reduction of carbon dioxide emissions from flue gases as the easiest and best performing solution. Bunter Sandstone, Scottish offshore and Ormskirk Sandstone are the storage sites considered, while several attractive potential utilization options are considered. Through minimization of total costs, the CCUS supply chain with Bunter Sandstone as storage site results in the most economically profitable solution due to the highest value of net present value (€ 0.554 trillion) and lowest value of pay back period (2.85 years). Only carbon tax is considered. The total cost is € 1.04 billion/year. Across the supply chain, 6.4 Mton/year of carbon dioxide emissions are avoided, to be either stored or used for calcium carbonate production. Future work should consider uncertainty, dynamics of market demand and social aspects

The development of a musically logical procedure for solving the problems of transcription for guitar performance of J.S. Bach's Suite in E Minor (BWV 996)

The procedure that was developed involves the interrelationship of factors such as Baroque performance practice, Bach's keyboard orientation, Bach's compositional techniques, analysis of musical structure at various hierarchical levels, the delineation of structural units through performance variables, ornamentation, phrasing, articulation, fingering, expressive effect, and necessary compromises of the musical fabric to accommodate instrumental/technical limitations. A foundational premise of the procedure is that the guitarist should develop an idealized conception of the music and determine the manner in which to realize, or to most closely approximate, that conception on the instrument. This approach involves analysis, investigation of the interrelated factors, and extensive experimentation with the instrument to test alternative solutions. The study presents detailed discussions of both the process and results of such analysis, investigation, and experimentation.An integral part of the professional training of the college level guitar performance major is the study and performance of the music of J.S. Bach. Because Bach did not compose any works for the guitar, the guitarist must perform transcriptions. Because of the insufficiency of published transcriptions of Bach's music that are adequate for use in the education of the college level guitar performance major, the study was designed to provide (1) a musically logical procedure for solving the problems of transcription for guitar performance, (2) a transcription of the Suiye in E minor that would be pedagogically adequate, and (3) a thorough basic introduction to ornamentation in Bach's music

A simulation tool for analysis and design of reverse electrodialysis using concentrated brines

Reverse Electrodialysis (SGP-RE or RED) represents a viable technology for the conversion of the Salinity Gradient Power into electric power. A comprehensive model is proposed for the RED process using sea or brackish water and concentrated brine as feed solutions. The goals were (i) reliably describing the physical phenomena involved in the process and (ii) providing information for optimal equipment design. For such purposes, the model has been developed at two different scales of description: a lower scale for the repeating unit of the system (cell pair), and a higher scale for the entire equipment (stack). The model was implemented in a process simulator, validated against original experimental information and then used to investigate the influence of the main operating factors and on power output. Feed solutions of different salinities were also tested. A good matching was found between predictions and experiments for a wide range of inlet concentrations, flow rates and feed temperatures. Optimal feed conditions, for the adopted system geometry and membranes, have been found employing brackish water (0.08-0.1 M NaCl) as dilute and brine (4.5-5 M NaCl) as concentrate to generate the highest power density at 40\ub0C temperature. The model can be used to explore the full potential of the RED technology, especially for any investigation regarding the future scale-up of the process

Water desalination by capacitive electrodialysis: Experiments and modelling

Electrodialysis-related technologies keep spreading in multiple fields, among which water desalination still plays a major role. A new technology that has not yet been thoroughly investigated is capacitive electrodialysis (CED), which couples the standard ED with capacitive electrodes. CED has a number of advantages such as removal of toxic products and system simplification. Little mention is made of this technology in the literature and, to the best of our knowledge, no modelling works have ever been presented. In this work, the CED process has been studied through experiments and modelling. A CED model is presented for the first time. With a simple calibration based on macroscopic membrane properties and the characterisation of electrode behaviour, the model is able to simulate the dynamics of simple as well as more complex layouts. An original experimental characterisation of electrodes is presented, showing how the collected data can be implemented into the model. After a successful validation with experimental data, dynamic simulations of a single pass CED unit have been performed with the aim of assessing the effect of different capacitive electrode properties on process performance. Results show how the impact of these properties is different depending on the number of cell pairs

Investigating the Trade-Off between Design and Operational Flexibility in Continuous Manufacturing of Pharmaceutical Tablets: A Case Study of the Fluid Bed Dryer

Market globalisation, shortened patent lifetimes and the ongoing shift towards personalised medicines exert unprecedented pressure on the pharmaceutical industry. In the push for continuous pharmaceutical manufacturing, processes need to be shown to be agile and robust enough to handle variations with respect to product demands and operating conditions. In this paper we examine the use of operational envelopes to study the trade-off between the design and operational flexibility of the fluid bed dryer at the heart of a tablet manufacturing process. The operating flexibility of this unit is key to the flexibility of the full process and its supply chain. The methodology shows that for the fluid bed dryer case study there is significant effect on flexibility of the process at different drying times with the optimal obtained at 700 s. The flexibility is not affected by the change in volumetric flowrate, but only by the change in temperature. Here the method used a black box model to show how it could be done without access to the full model equation set, as this often needs to be the case in commercial settings

Economic Benefits of Waste Pickling Solution Valorization

An integrated hybrid membrane process, composed of a diffusion dialysis (DD), a membrane distillation (MD) and a reactive precipitation unit (CSTR), is proposed as a promising solution for the valorization and onsite recycling of pickling waste streams. An economic analysis was performed aiming to demonstrate the feasibility of the developed process with a NPV of about EUR 40,000 and a DPBP of 4 years. The investment and operating costs, as well as the avoided costs and the benefits for the company operating the plant, were analyzed with an extensive cost tracking exercise and through face-to-face contact with manufacturers and sector leaders. A mathematical model was implemented using the gPROMS modelling platform. It is able to simulate steady state operations and run optimization analysis of the process performance. The impact of key operating and design parameters, such as the set-point bath concentration and the DD and MD membrane areas, respectively, was investigated and the optimal arrangement was identified. Finally, operating variables and design parameters were optimized simultaneously in a nonlinear framework as a tradeoff between profitability and environmental impact. We show how the integration of new technologies into the traditional pickling industry could provide a significant benefit for the issues of process sustainability, which are currently pressing

Effects of citric acid and fibronectin and laminin application in treating periodontitis

. To determine the effect on new connective tissue attachment of citric acid conditioning and fibronectin-laminin application in treating naturally occurring periodontitis, all 4 quadrants in each of 2 Beagle dogs were used. Each quadrant included: P 2 , P 3 , P 4 , and M 1 teeth. 2 treatment modalities were employed and comparatively analyzed for differences in histological healing respponses at 120 days after surgery. The treatments were: (1) surgery (mucoperiosteal flaps) plus citric acid; (2) surgery plus citric acid followed by fibronectin-laminin application. After scaling and root planing, coronal and root surface reference notches were placed for histometric measurements. Following each of the randomly assigned treatments, flaps were sutured. After sacrifice, tissue blocks of treated areas were decalcified and serially cut, obtaining bucco-lingual and mesiodistal sections. Using a Filar micrometer. 5 distances were masured on the buccal aspect: (1) from root surface notch to alveolar bone crest; (2) from root surface notch to coronal extent of the cementum; (3) from root surface notch to apical extent of the junctional epithelium; 84) from free gingival margin to apical extent of junctional epithelium; (5) from the coronal notch to the alveolar bone crest. Results showed no differences among the 5 measurements between the 2 treatments tested. On mesiodistal sections, surface area determinations were made in the furcations, evaluating the space occupied by new connective tissue, with or without bone, or by epithelium. For this, images were digitized using a Zeiss IBAS Image analysis system with a 4mB of array processor memory coupled to a Newvicon TV camera and a microcomputer. Significant differences were found, with increased values for both regenerative connective tissue and bone when surgery plus citric acid was followed by fibronectin-laminin application. Often, these tissues filled completely furcation areas above root surface reference notches.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/73686/1/j.1600-051X.1987.tb01543.x.pd