Integrated Geomechanical and Digital Photogrammetric Survey in the Study of Slope Instability Processes of a Flysch Sea Cliff (Debeli Rtič Promontory, Slovenia)

This work presents an integrated study approach that combines the results of a geomechanical survey with data obtained using digital photogrammetry (DP), to assess slope instability processes affecting a sea cliff at the Debeli Rtič promontory (Slovenia). The investigated cliff is 4–18 m-high and is made up of an alternation of sandstones and marlstones belonging to the Flysch Formation of Trieste, which is Eocene in age. The studied cliff was subjected to localized slope failures that occurred in the past and is currently subject to frequent rock collapses, thus resulting in its partial and episodic retreat. Field evidence acquired through a traditional survey was integrated with outputs of the DP technique based on 1399 images that were collected using both a commercial unmanned aerial vehicle (UAV) and a mobile phone (MP). UAV-derived images were useful for performing rock mass structure analysis in the upper part of the investigated cliff, where the traditional survey was not possible due to hazardous operating conditions. In addition, the use of a MP was observed to be a useful tool for the rapid collection of images at the toe of unsafe marine cliff environments. This study highlights that UAV-DP and MP-DP techniques can only be effective if the outcomes obtained from the 3D model reconstruction are validated by direct measurements acquired by means of the traditional field survey, thus avoiding improper or even erroneous results while enlarging the amount of data and the area of investigation. The study approach presented herein allowed for the assessment of slope instabilities affecting the Flysch Sea cliff, whose retreat is caused by the combined action of marine erosion and slope gravitational processes

Possible Recycling of End-of-Life Dolomite Refractories by the Production of Geopolymer-Based Composites: Experimental Investigation

Production and characterization of geopolymers prepared by mixing metakaolin, end-of-life dolomite refractories, sodium silicate solution, and sodium hydroxide solution have been performed. The as-received refractory was crumbled in order to obtain products having, respectively, 250\ua0\u3bcm, 1 mm, and 2.5\ua0mm maximum particles size. Each batch of powder was added in different proportions to a blank geopolymeric matrix. It has been observed that the addition of waste refractory reduces workability of the reference refractory-free slurry. After hardening, only the set of samples prepared with powders with maximum size of 250\ua0\u3bcm maintain integrity while the others resulted affected by the presence of fractures caused by volumetric instabilities; samples with composition R100 showed the highest compressive strength, whereas higher refractory addition lowers strength. Specific surface area appears independent by materials composition; conversely pore volume slightly increases with the addition of dolomite refractory powder. During the thermodilatometric tests all compositions display a shrinkage of about 0.1% between 170 and 400\ua0\ub0C; however, sintering starts at higher temperature (above 600\ua0\ub0C) and samples melt in the range between 650 and 750\ua0\ub0C as a function of their composition, thus showing that the resulting materials loose refractoriness with respect to both the reference geopolymer and the dolomite refractory. Graphical Abstract: [Figure not available: see fulltext.

Integrated Geomechanical and Digital Photogrammetric Survey in the Study of Slope Instability Processes of a Flysch Sea Cliff (Debeli Rtic Promontory, Slovenia)

This work presents an integrated study approach that combines the results of a geomechanical survey with data obtained using digital photogrammetry (DP), to assess slope instability processes affecting a sea cliff at the Debeli Rtic promontory (Slovenia). The investigated cliff is 4-18 m-high and is made up of an alternation of sandstones and marlstones belonging to the Flysch Formation of Trieste, which is Eocene in age. The studied cliff was subjected to localized slope failures that occurred in the past and is currently subject to frequent rock collapses, thus resulting in its partial and episodic retreat. Field evidence acquired through a traditional survey was integrated with outputs of the DP technique based on 1399 images that were collected using both a commercial unmanned aerial vehicle (UAV) and a mobile phone (MP). UAV-derived images were useful for performing rock mass structure analysis in the upper part of the investigated cliff, where the traditional survey was not possible due to hazardous operating conditions. In addition, the use of a MP was observed to be a useful tool for the rapid collection of images at the toe of unsafe marine cliff environments. This study highlights that UAV-DP and MP-DP techniques can only be effective if the outcomes obtained from the 3D model reconstruction are validated by direct measurements acquired by means of the traditional field survey, thus avoiding improper or even erroneous results while enlarging the amount of data and the area of investigation. The study approach presented herein allowed for the assessment of slope instabilities affecting the Flysch Sea cliff, whose retreat is caused by the combined action of marine erosion and slope gravitational processes

Synthesis, crystallographic characterization, and mechanical behavior of alumina chromia alloys

Powder mixtures of Alumina and Chromia, blended in different proportions (1, 3, 5 and 10%wt) by attrition milling, were fired either by pressureless sintering in air and hot pressing under vacuum. The resulting materials, characterized by X-ray diffraction, Raman spectroscopy, SEM, hardness and fracture toughness showed that all the compositions form complete solid solution which maintain the same crystal structures of corundum; chromia addition retards materials' densification of pressureless fired samples but not that of hot-pressed samples. Data from Raman spectroscopy and SEM/EDXS showed the appearance of Ti- and Mn-based impurities near the indentation print, in particular on fractured grains. The addition of chromia improves hardness, but does not affect toughness which is, on the other hand, greatly influenced by materials\u2019 residual porosity