Power generation characteristics of pulse jet rechargeable direct carbon fuel cells at different isooctane fuel supply frequency

INTRODUCTION Our research group previously proposed a new type of a direct carbon fuel cell (DCFC) called a rechargeable direct carbon fuel cell (RDCFC), which uses as fuel the solid-state carbon deposited on the electrode [1~6]. In a typical RDCFC, lower hydrocarbons such as propane are the supplied fuel, and deposition of the solid-state carbon (charging) into the anode is done by pyrolysis. In an RDCFC, this charging method causes several problems, such as low carbon extraction efficiency and batch-type rather than continuous operation. Our research group thus developed a pulse jet RDCFC because a constant power density can be maintained by supplying small amounts of high energy density liquid fuel by a pulse jet while generating electricity and continuous power generation by repeating the charging and power generation at short intervals. In addition, in a pulse jet RDCFC, deterioration of anodes due to carbon is minimized by frequent carbon removal and high energy conversion efficiency by utilizing hydrogen, methane, and other hydrocarbons as well as the solid-state carbon generated by the pyrolysis of liquid fuel. In a pulse jet RDCFC, the frequency at which isooctane fuel is supplied influences the power generation characteristics. When this supply frequency is increased, the power generation characteristics of a pulse jet RDCFC are thought to change to those of a flow-type SOFC. In this study, the effect of a supply frequency of isooctane on power generation characteristics of a pulse jet RDCFC was investigated