472 research outputs found
Magnetic ordering, electronic structure and magnetic anisotropy energy in the high-spin Mn single molecule magnet
We report the electronic structure and magnetic ordering of the single
molecule magnet [MnO(2,2'-biphenoxide)Br]
based on first-principles all-electron density-functional calculations. We find
that two of the ten core Mn atoms are coupled antiferromagnetically to the
remaining eight, resulting in a ferrimagnetic ground state with total spin
S=13. The calculated magnetic anisotropy barrier is found to be 9 K in good
agreement with experiment. The presence of the Br anions impact the electronic
structure and therefore the magnetic properties of the 10 Mn atoms. However,
the electric field due to the negative charges has no significant effect on the
magnetic anisotropy.Comment: 4 pages, submitted to PR
Properties of low-lying states in some high-nuclearity Mn, Fe and V clusters: Exact studies of Heisenberg models
Using an efficient numerical scheme that exploits spatial symmetries and spin
parity, we have obtained the exact low-lying eigenstates of exchange
Hamiltonians for the high nuclearity spin clusters, Mn_{12}, Fe_8 and V_{15}.
The largest calculation involves the Mn_{12} cluster which spans a Fock space
of a hundred million. Our results show that the earlier estimates of the
exchange constants need to be revised for the Mn_{12} cluster to explain the
level ordering of low-lying eigenstates. In the case of the Fe_8 cluster,
correct level ordering can be obtained which is consistent with the exchange
constants for the already known clusters with butterfly structure. In the
V_{15} cluster, we obtain an effective Hamiltonian that reproduces exactly, the
eight low-lying eigenvalues of the full Hamiltonian.Comment: Revtex, 12 pages, 16 eps figures; this is the final published versio
Characterization of the S = 9 excited state in Fe8Br8 by Electron Paramagnetic Resonance
High Frequency electron paramagnetic resonance has been used to observe the
magnetic dipole, M = 1, transitions in the excited
state of the single molecule magnet FeBr. A Boltzmann analysis of the
measured intensities locates it at 24 2 K above the ground
state, while the line positions yield its magnetic parameters D = -0.27 K, E =
0.05 K, and B = -1.3 10 K. D is thus smaller by 8%
and E larger by 7% than for . The anisotropy barrier for is
estimated as 22 K,which is 25% smaller than that for (29 K). These
data also help assign the spin exchange constants(J's) and thus provide a basis
for improved electronic structure calculations of FeBr.Comment: 7 pages, Figs included in text, submitted to PR
The Geometry and Moduli of K3 Surfaces
These notes will give an introduction to the theory of K3 surfaces. We begin
with some general results on K3 surfaces, including the construction of their
moduli space and some of its properties. We then move on to focus on the theory
of polarized K3 surfaces, studying their moduli, degenerations and the
compactification problem. This theory is then further enhanced to a discussion
of lattice polarized K3 surfaces, which provide a rich source of explicit
examples, including a large class of lattice polarizations coming from elliptic
fibrations. Finally, we conclude by discussing the ample and Kahler cones of K3
surfaces, and give some of their applications.Comment: 34 pages, 2 figures. (R. Laza, M. Schutt and N. Yui, eds.
Magnetic Field Effects on the Far-Infrared Absorption in Mn_12-acetate
We report the far-infrared spectra of the molecular nanomagnet Mn_12-acetate
(Mn_12) as a function of temperature (5-300 K) and magnetic field (0-17 T). The
large number of observed vibrational modes is related to the low symmetry of
the molecule, and they are grouped together in clusters. Analysis of the mode
character based on molecular dynamics simulations and model compound studies
shows that all vibrations are complex; motion from a majority of atoms in the
molecule contribute to most modes. Three features involving intramolecular
vibrations of the Mn_12 molecule centered at 284, 306 and 409 cm-1 show changes
with applied magnetic field. The structure near 284 cm displays the
largest deviation with field and is mainly intensity related. A comparison
between the temperature dependent absorption difference spectra, the gradual
low-temperature cluster framework distortion as assessed by neutron diffraction
data, and field dependent absorption difference spectra suggests that this mode
may involve Mn motion in the crown.Comment: 5 pages, 4 figures, PRB accepte
Superradiation from Crystals of High-Spin Molecular Nanomagnets
Phenomenological theory of superradiation from crystals of high-spin
molecules is suggested. We show that radiation friction can cause a
superradiation pulse and investigate the role of magnetic anisotropy, external
magnetic field and dipole-dipole interactions. Depending on the contribution of
all these factors at low temperature, several regimes of magnetization of
crystal sample are described. Very fast switch of magnetization's direction for
some sets of parameters is predicted.Comment: 10 pages, 3 figure
High frequency resonant experiments in Fe molecular clusters
Precise resonant experiments on Fe magnetic clusters have been
conducted down to 1.2 K at various tranverse magnetic fields, using a
cylindrical resonator cavity with 40 different frequencies between 37 GHz and
110 GHz. All the observed resonances for both single crystal and oriented
powder, have been fitted by the eigenstates of the hamiltonian . We have identified the
resonances corresponding to the coherent quantum oscillations for different
orientations of spin S = 10.Comment: to appear in Phys.Rev. B (August 2000
Populism and health policy: three international case studies of right-wing populist policy frames
Over the past decade, some of the world's most stable parliamentary democracies have witnessed a revival in right‐wing populist political parties, movements and leaders. Although there is a growing body of theoretical and empirical literature documenting the rise of populism, there has been very little exploration of the implications for health policy of this important political development. In this article, we draw from three illustrative international cases, originating from the USA, the UK and Italy, to explore the ways in which right‐wing populism influences health policy: the election of President Trump in the United States (and subsequent healthcare reforms), the United Kingdom's vote to withdraw from the European Union (Brexit), and how this has played out in the context of the UK National Health Service, and the rise of a politically aligned anti‐vaccination movement in Italy. Drawing on the work of the influential socio‐political theorist Ernesto Laclau, we interpret populism as a performative political act, predicated on drawing logics of equivalence (and difference) between different actors. We use this theoretical framing to explore the ways in which the recent upsurge in right‐wing populism creates a specific set of barriers and challenges for access to healthcare and the health of populations
Studies of transverse and longitudinal relaxations of Mn in molecular cluster magnet MnAc
The transverse and longitudinal relaxation rates 1/ and 1/ of
Mn in molecular cluster magnet MnAc have been measured al low
temperatures down to 200mK and in the fields upto 9T. Both of 1/ and
1/ exhibit remarkable decreases with decreasing temperature and with
increasing field, with the relative relation . In the
analysis, we adopt a simple model that the thermal fluctuation of the cluster
spin =10 associated with the spin-phonon interactionis, is only due to the
excitation to the first excited state from the ground state with the average
life-times and (). We show that
1/ is interpreted in terms of the strong collision regime as given by
1/, and that 1/ is understood by the high-frequency limit based
on standard perturbation treatment for the step-wise fluctuating field, thus
being proportional to 1/.Comment: 12 pages, 11 fugures, revtex
Asymmetric Lineshape due to Inhomogeneous Broadening of the Crystal-Field Transitions in Mn12ac Single Crystals
The lineshape of crystal-field transitions in single crystals of Mn12ac
molecular magnets is determined by the magnetic history. The absorption lines
are symmetric and Gaussian for the non-magnetized state obtained by zero-field
cooling (zfc). In the magnetized state which is reached when the sample is
cooled in a magnetic field (fc), however, they are asymmetric even in the
absence of an external magnetic field. These observations are quantitatively
explained by inhomogeneous symmetrical (Gaussian) broadening of the
crystal-field transitions combined with a contribution of off-diagonal
components of the magnetic susceptibility to the effective magnetic
permeability.Comment: 4 pages, 3 figure
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