53 research outputs found
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Biogeochemical Mechanisms Controlling Reduced Radionuclide Particle Properties and Stability
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Reduction of U(VI) Complexes by Anthraquinone Disulfonate: Experiment and Molecular Modeling
Past studies demonstrate that complexation will limit abiotic and biotic U(VI) reduction rates and the overall extent of reduction. However, the underlying basis for this behavior is not understood and presently unpredictable across species and ligand structure. The central tenets of these investigations are: (1) reduction of U(VI) follows the electron-transfer (ET) mechanism developed by Marcus; (2) the ET rate is the rate-limiting step in U(VI) reduction and is the step that is most affected by complexation; and (3) Marcus theory can be used to unify the apparently disparate U(VI) reduction rate data and as a computational tool to construct a predictive relationship
Phase diagram of an Ising model with long-range frustrating interactions: a theoretical analysis
We present a theoretical study of the phase diagram of a frustrated Ising
model with nearest-neighbor ferromagnetic interactions and long-range
(Coulombic) antiferromagnetic interactions. For nonzero frustration, long-range
ferromagnetic order is forbidden, and the ground-state of the system consists
of phases characterized by periodically modulated structures. At finite
temperatures, the phase diagram is calculated within the mean-field
approximation. Below the transition line that separates the disordered and the
ordered phases, the frustration-temperature phase diagram displays an infinite
number of ``flowers'', each flower being made by an infinite number of
modulated phases generated by structure combination branching processes. The
specificities introduced by the long-range nature of the frustrating
interaction and the limitation of the mean-field approach are finally
discussed.Comment: 32 pages, 7 figure
Origin of Life
The evolution of life has been a big enigma despite rapid advancements in the
fields of biochemistry, astrobiology, and astrophysics in recent years. The
answer to this puzzle has been as mind-boggling as the riddle relating to
evolution of Universe itself. Despite the fact that panspermia has gained
considerable support as a viable explanation for origin of life on the Earth
and elsewhere in the Universe, the issue remains far from a tangible solution.
This paper examines the various prevailing hypotheses regarding origin of life
like abiogenesis, RNA World, Iron-sulphur World, and panspermia; and concludes
that delivery of life-bearing organic molecules by the comets in the early
epoch of the Earth alone possibly was not responsible for kick-starting the
process of evolution of life on our planet.Comment: 32 pages, 8 figures,invited review article, minor additio
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