9 research outputs found
The Influence of Plasma-Based Nitriding and Oxidizing Treatments on the Mechanical and Corrosion Properties of CoCrMo Biomedical Alloy
International audiencePlasma-based nitriding and/or oxidizing treatments were applied to CoCrMo alloy to improve its surface mechanical properties and corrosion resistance for biomedical applications. Three treatments were performed. A set of CoCrMo samples has been subjected to nitriding at moderate temperatures (~ 400 °C). A second set of CoCrMo samples was oxidized at 395 °C in pure O2. The last set of CoCrMo samples was nitrided and subsequently oxidized under the experimental conditions of previous sets (double treatment). The microstructure and morphology of the layers formed on the CoCrMo alloy were investigated by X-ray diffraction, Atomic Force Microscopy, and Scanning Electron Microscopy. In addition, nitrogen and oxygen profiles were determined by Glow Discharge Optical Emission Spectroscopy, Rutherford Backscattering Spectroscopy, Energy-Dispersive X-ray, and Nuclear Reaction Analysis. Significant improvement of the Vickers hardness of the CoCrMo samples after plasma nitriding was observed due to the supersaturated nitrogen solution and the formation of an expanded FCC γN phase and CrN precipitates. In the case of the oxidized samples, Vickers hardness improvement was minimal. The corrosion behavior of the samples was investigated in simulated body fluid (0.9 pct NaCl solution at 37 °C) using electrochemical techniques (potentiodynamic polarization and cyclic voltammetry). The concentration of metal ions released from the CoCrMo surfaces was determined by Instrumental Neutron Activation Analysis. The experimental results clearly indicate that the CoCrMo surface subjected to the double surface treatment consisting in plasma nitriding and plasma oxidizing exhibited lower deterioration and better resistance to corrosion compared to the nitrided, oxidized, and untreated samples. This enhancement is believed to be due to the formation of a thicker and more stable layer
Chromium (VI) removal from aqueous solutions using a polyethylenimine - epichlorohydrin resin
Sorption of Th(IV) onto ZnO nanoparticles and diatomite-supported ZnO nanocomposite: kinetics, mechanism and activation parameters
WOS: 000384108400003In this study, for the first time ZnO nanoparticles and diatomite-supported ZnO nanocomposite have been utilized as adsorbent for the removal of Th(IV) ions from aqueous solutions under different experimental conditions. The Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (D-R) isotherms were used to analyze the equilibrium data. The sorption equilibrium data were fitted well to the Langmuir isotherm with maximum sorption capacities values was found to be 1.105 mmol/g and 0.320mmol/gfor ZnO nanoparticles and diatomite-supported ZnO nanocomposite, respectively. Pseudo-first and pseudo-second order equations, Intraparticle diffusion and Bangham's models were considered to evaluate the rate parameters and sorption mechanism. Sorption kinetics were better reproduced by the pseudo-second order model (R-2 > 0.999), with an activation energy (E-a) of +99.74kJ/mol and +62.95kJ/mol for ZnO nanoparticles and diatomite-supported ZnOnanocomposite, respectively. In order to specify the type of sorption reaction, thermodynamic parameters were also determined. The evaluated Delta G* and Delta H* indicate the non-spontaneous and endothermic nature of the reactions. The results of this work suggest that both of the used materials are fast and effective adsorbents for removing Th(IV) from aqueous solutions and chemical sorption plays a role in controlling the sorption rate.Ege UniversityEge University [2012 NBE 015]This project was supported by Ege University Scientific Research Project Unit Project No. 2012 NBE 015. The research for this paper was carried out at the Institute of Nuclear Sciences, Ege University, Bornova-Izmir, within the frame of ERASMUS Program
Chromium (VI) removal from aqueous solutions using a polyethylenimine - epichlorohydrin resin
The ability of a synthesized polyethylenimine - epichlorohydrin resin to
remove Cr(VI) from aqueous solutions was investigated in absence (initial pH
2 to 7) and presence of background electrolytes (NaNO3 and Na2SO4 solutions
of initial pH 3 and 6). The determined Cr-uptake was significantly higher
than the one reported for the majority of other sorbents. The
photo-metrically determined uptake data were modeled by the Langmuir,
Redlich-Peterson, Langmuir-Freundlich, and Toth equations. The modeling
results did not point out any preference to one specific model in terms of
the goodness-of-fit and the prediction of maximum sorption capacity. The
Cr-sorption kinetics was investigated at 15, 25, 35 and 45 oC using
51Cr-labeled solutions and γ-ray spectroscopy. The Cr-sorption was very fast
at all studied temperatures and well reproduced by the pseudo-second order
kinetics equation. Rate constant and activation energy values were
calculated using the experimental data. The Cr-loaded resin was also
examined by XRD, XPS, XAFS and SEM/EDS. The XPS and XAFS investigations
indicated a partial reduction of Cr(VI) to Cr(III). The environmental
compatibility of the Cr-loaded resin was examined using the EPA-TCLP method.
The Cr-binding by the resin was very stable and regeneration attempts by HCl
solutions of pH 3 were rather unsuccessful