2 research outputs found
catena-Poly[[(2,2′-dimethyl-4,4′-bi-1,3-thiaÂzole-κ2 N,N′)cadmium]-di-μ-bromido]
In the title coordination polymer, [CdBr2(C8H8N2S2)]n, the CdII atom is six-coordinated in a distorted octaÂhedral geometry by two N atoms from a 2,2′-dimethyl-4,4′-bi-1,3-thiaÂzole ligand and four bridging Br atoms. The bridging function of the Br atoms leads to a chain structure along [100]. InterÂchain C—H⋯Br hydrogen bonds and π–π contacts between the thiaÂzole rings [centroid–centroid distances = 3.810 (5) and 3.679 (5) Å] are observed