Curing kinetics and effects of fibre surface treatment and curing parameters on the interfacial and tensile properties of hemp/epoxy composites

The curing kinetics of neat epoxy (NE) and hemp fibre/epoxy composites was studied and assessed using two dynamic models (the Kissinger and Flynn-Wall-Ozawa Models) and an isothermal model (the Autocatalytic Model) which was generally supported by the experimental data obtained from dynamic and isothermal differential scanning calorimetry (DSC) scans. The activation energies for the curing of composites exhibited lower values compared to curing of NE which is believed to be due to higher nucleophilic activity of the amine groups of the curing agent in the presence of fibres. The highest tensile strength, σ was obtained with composites produced with an epoxy to curing agent ratio of 1:1 and the highest Young's modulus, E was obtained with an epoxy to curing agent ratio of 1:1.2. Alkali treated hemp fibre/epoxy (ATFE) composites were found to have higher σ and E values compared to those for untreated hemp fibre/epoxy (UTFE) composites which was consistent with the trend for interfacial shear strength (IFSS) values. Composites σ and E were found to be higher for a processing temperature of 70°C than for 25°C for both UTFE and ATFE composites, but were found to decrease as the curing temperature was increased further to 120°C

Influence of accelerated ageing on the physico-mechanical properties of alkali-treated industrial hemp fibre reinforced poly(lactic acid) (PLA) composites

30 wt% aligned untreated long hemp fibre/PLA (AUL) and aligned alkali treated long hemp fibre/PLA (AAL) composites were produced by film stacking and subjected to accelerated ageing. Accelerated ageing was carried out using UV irradiation and water spray at 50 °C for four different time intervals (250, 500, 750 and 1000 h). After accelerated ageing, tensile strength (TS), flexural strength, Young's modulus (YM), flexural modulus and mode I fracture toughness (KIc) were found to decrease and impact strength (IS) was found to increase for both AUL and AAL composites. AUL composites had greatest overall reduction in mechanical properties than that for AAL composites upon exposure to accelerated ageing environment. FTIR analysis and crystallinity contents of the accelerated aged composites support the results of the deterioration of mechanical properties upon exposure to accelerated ageing environment

Optimising industrial hemp fibre for composites

The optimisation of New Zealand grown hemp fibre for inclusion in composites has been investigated. The optimum growing period was found to be 114 days, producing fibres with an average tensile strength of 857 MPa and a Young’s modulus of 58 GPa. An alkali treatment with 10wt% NaOH solution at a maximum processing temperature of 160o C with a hold time of 45 minutes was found to produce strong fibres with a low lignin content and good fibre separation. Although a good fit with the Weibull distribution function was obtained for single fibre strength, this did not allow for accurate scaling to strengths at different lengths. Alkali treated fibres, polypropylene and a maleated polypropylene (MAPP) coupling agent were compounded in a twin-screw extruder, and injection moulded into composite tensile test specimens. The strongest composite consisted of polypropylene with 40wt% fibre and 3wt% MAPP, and had a tensile strength of 47.2 MPa, and a Young’s modulus of 4.88 GPa

Influence of hygrothermal ageing on the physico-mechanical properties of alkali treated industrial hemp fibre reinforced polylactic acid composites

30 wt% aligned untreated long hemp fibre/polylactic acid (AUL) and aligned alkali treated long hemp fibre/polylactic acid (AAL) composites were produced by film stacking and subjected to hygrothermal ageing environment along with neat polylactic acid (PLA). Hygrothermal ageing was carried out by immersing samples in distilled water at 25 and 50 ºC over a period of 3 months. It was found that both neat PLA and composites followed Fickian diffusion. Higher temperature generally increased the Diffusion coefficient, D of neat PLA and composites, as well as shortening the saturation time. Neat PLA had the lowest D value followed by AAL composites and then AUL composites. After hygrothermal ageing, tensile and flexural strength, Young’s and flexural modulus and KIc were found to decrease and impact strength was found to increase for both AUL and AAL composites. AUL composites had greater overall reduction in mechanical properties than that for AAL composites after hygrothermal ageing. Crystallinity contents of the hygrothermal aged composites support the results of the deterioration of mechanical properties upon exposure to hygrothermal ageing environment