Mechanistic Links Between the Sedimentary Redox Cycle and Marine Acid-Base Chemistry

The redox state of Earth's surface is controlled on geological timescales by the flow of electrons through the sedimentary rock cycle, mediated largely by the weathering and burial of C‐S‐Fe phases. These processes buffer atmospheric pO₂. At the same time, CO₂ influxes and carbonate burial control seawater acid‐base chemistry and climate over long timescales via the carbonate‐silicate cycle. However, these two systems are mechanistically linked and impact each other via charge balance in the hydrosphere. Here, we use a low‐order Earth system model to interrogate a subset of these connections, with a focus on changes that occur during perturbations to electron flow through the sedimentary rock cycle. We show that the net oxidation or reduction of the Earth's surface can play an important role in controlling acid‐base processes in the oceans and thus climate, and suggest that these links should be more fully integrated into interpretive frameworks aimed at understanding Earth system evolution throughout Precambrian and Phanerozoic time

Lipschitz-continuity of the integrated density of states for Gaussian random potentials

The integrated density of states of a Schroedinger operator with random potential given by a homogeneous Gaussian field whose covariance function is continuous, compactly supported and has positive mean, is locally uniformly Lipschitz-continuous. This is proven using a Wegner estimate

Red blood cells and other non-spherical capsules in shear flow: oscillatory dynamics and the tank-treading-to-tumbling transition

We consider the motion of red blood cells and other non-spherical microcapsules dilutely suspended in a simple shear flow. Our analysis indicates that depending on the viscosity, membrane elasticity, geometry and shear rate, the particle exhibits either tumbling, tank-treading of the membrane about the viscous interior with periodic oscillations of the orientation angle, or intermittent behavior in which the two modes occur alternately. For red blood cells, we compute the complete phase diagram and identify a novel tank-treading-to-tumbling transition at low shear rates. Observations of such motions coupled with our theoretical framework may provide a sensitive means of assessing capsule properties.Comment: 11 pages, 4 figure

Compact solid-state laser source for 1S-2S spectroscopy in atomic hydrogen

We demonstrate a novel compact solid-state laser source for high-resolution two-photon spectroscopy of the $1S-2S$ transition in atomic hydrogen. The source emits up to 20 mW at 243 nm and consists of a 972 nm diode laser, a tapered amplifier, and two doubling stages. The diode laser is actively stabilized to a high-finesse cavity. We compare the new source to the stable 486 nm dye laser used in previous experiments and record 1S-2S spectra using both systems. With the solid-state laser system we demonstrate a resolution of the hydrogen spectrometer of 6 \times 10^{11} which is promising for a number of high-precision measurements in hydrogen-like systems

Radiant heat exchange in a space environment Scientific technical report, 1 Feb. - 31 Jul. 1970

Spectral and directional surface property effects on radiant heat transfer in space environmen

Current-eddy interaction in the Agulhas Return Current region from the seismic oceanography perspective

Interleaving in the Agulhas Return Current (ARC) frontal region is commonly manifested in the form of thermohaline intrusions, as sub-tropical and sub-polar water masses of similar density meet. In Jan/Feb 2012, the Naval Research Laboratory and collaborators carried out a field experiment in which seismic and traditional hydrographic observations were acquired to examine frontal zone mixing processes. The high lateral resolution (10 m) of the seismic observations allowed fine-scale lateral tracking of thermal intrusions, which were corroborated with simultaneous XBT casts. Between seismic deployments both salinity and temperature data were acquired via CTD, Underway-CTD and microstructure profiles. This study focuses on analyzing seismic reflection data in a particular E-W transect where the northward flowing ARC interacted with the southward flowing portion of a large anticyclonic eddy. Strong reflectors were most prominent at the edge of a hyperbolic zone formed between the eddy and ARC, where sub-polar waters interacted with waters of sub-tropical origin on either side. Reflectors were shallow within the hyperbolic zone and extended to 1200 m below the ARC. The nature of the observed reflectors will be determined from comparison of seismic reflection and derived ∂T/∂z fields, and XBT and TS profiles from the available hydrographic data

Radiant heat exchange in a space environment Scientific technical report, 1 Aug. 1969 - 31 Jan. 1970

Spectral surface property effects on radiant heat transfer in aerospace environmen

Preliminary results of aerial infrared surveys at Pisgah Crater, California

In-flight tests of airborne infrared scanners, and comparison with field reflectance dat