Alternative factor analysis of the investment intensity of the gross regional product of the Baikal region

Each effective indicator depends on numerous and various factors. The more detailed is the study of the influence of factors on the magnitude of the effective indicator, the more accurate are the results of the analysis and the evaluation of the quality of the subject of the research work. Hence, in the analysis of economic activity, an important methodological issue is the study and measurement of the influence of factors on the magnitude of the economic indicators studied. The article deals with the analysis of the investment intensity of the gross regional product of the Baikal region of the Russian Federation. The author has introduced into scientific circulation the following indicators: the investment intensity of the gross regional product, the science intensity of the gross regional product and the science return of the invested capital. The paper reveals the influence of the factors affecting the investment intensity of the gross regional product in the Baikal region of the Russian Federation and provides methodological approaches to its calculation. Also, the article presents the author’s analytical and systematized statistical material for the analysis of the key indicators revealing the impact on the investment intensity of the gross regional product in the Baikal region of the Russian Federation. The paper is produced in the framework of the scientific project of the Siberian Branch of the Russian Academy of Sciences No. XI.174.1.4 “Activation of the internal development potential of regions of the resource specialization (on the example of the Baikal region)”

Alternative factor analysis of the science intensity of the invested capital in the Baikal region

Factor analysis is the basic tool when conducting a comprehensive analysis of economic activity. In the factor analysis, the major attention is given to the research of internal reasons that form the specificity of the phenomenon under study and identification of generalized factors standing behind relevant specific indicators. The article deals with the analysis of the science intensity of the invested capital in the Baikal region of the Russian Federation. Science intensity is an important parameter for determining the efficiency of the economic activity. The author introduced into scientific circulation the following indicators: the science intensity of the invested capital, the science intensity of the gross regional product and the investment return of the gross regional product. The paper reveals the influence of factors affecting the change in the science intensity of the invested capital in the Baikal region of the Russian Federation, and provides methodological approaches to its calculation. The article presents the author’s analytical and systematized statistical material for the analysis of the key indicators revealing the impact of the invested capital in the Baikal region of the Russian Federation on the change of the science intensity. The research has been carried out in the framework of the scientific project of the Irkutsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences No. XI.174.1.4 “Activation of the internal development potential of regions of the resource specialization (on the example of the Baikal region)”

Synthesis, Crystal Structure and Thermal Stability of 1D Linear Silver(I) Coordination Polymers with 1,1,2,2-Tetra(pyrazol-1-yl)ethane

Two new linear silver(I) nitrate coordination polymers with bitopic ligand 1,1,2,2-tetra(pyrazol-1-yl)ethane were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction and thermal analysis. Silver coordination polymers demonstrated a yellow emission near 500 nm upon excitation at 360 nm. Crystal structures of coordination polymers were determined and structural peculiarities are discussed. In both of the structures, silver ions are connected via bridging ligand molecules to form polymeric chains with a five-atomic environment. The coordination environment of the central atom corresponds to a distorted trigonal bipyramid with two N atoms of different ligands in apical positions. The Ag–N bond distances vary in a wide range of 2.31–2.62 Å, giving strongly distorted metallacycles. Thermolysis of coordination polymers in reductive atmosphere (H2/He) leads to the formation of silver nanoparticles with a narrow size distribution

Synthesis, Crystal Structure and Luminescent Properties of 2D Zinc Coordination Polymers Based on Bis(1,2,4-triazol-1-yl)methane and 1,3-Bis(1,2,4-triazol-1-yl)propane

Two new two-dimensional zinc(II) coordination polymers containing 2,5-thiophenedicarboxylate and bitopic ligands bis(1,2,4-triazol-1-yl)methane (btrm) or 1,3-bis(1,2,4-triazol-1-yl)propane (btrp) were synthesized. Synthesized compounds were characterized by IR spectroscopy, elemental analysis, powder X-ray diffraction, and thermal analysis. Crystal structures of coordination polymers were determined and their structural peculiarities are discussed. The differences in structural features, thermal behavior, and luminescent properties are discussed

Synthesis, Crystal Structure, Thermal Analysis, and DFT Calculations of Molecular Copper(II) Chloride Complexes with Bitopic Ligand 1,1,2,2-tetrakis(pyrazol-1-yl)ethane

Two binuclear coordination compounds of Cu(II) chloride with the bitopic ligand 1,1,2,2-tetrakis(pyrazol-1-yl)ethane (Pz4) of the composition [Cu2(µ2-Pz4)(DMSO)2Cl4]·4H2O and [Cu2(µ2-Pz4)(DMSO)2Cl4]∙2DMSO were prepared and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis, single-crystal X-ray diffraction, and powder diffraction analysis. It was shown that in contrast to silver(I) and copper(II) nitrates, copper(II) chloride forms discrete complexes instead of coordination polymers. The supramolecular structure of the complex [Cu2(µ2-Pz4)(DMSO)2Cl4]·4H2O with lattice water molecules is formed by OH···Cl and OH···O hydrogen bonds. Density functional theory (DFT) calculations of vibrational frequencies of the ligand and its copper(II) complex allowed for assigning IR bands to specific vibrations

Unligated Diruthenium(II,II) Tetra(trifluoroacetate): The First X-ray Structural Study, Thermal Compressibility, Lewis Acidity, and Magnetism

The title compound, [Ru2(O2CCF3)4] (1), has been obtained without any exogenous ligands and crystallized by deposition from the gas phase at 170 C. Its crystal structure has been determined for the first time to confirm an infinite chain motif built on axial Ru···O interactions of the diruthenium(II,II) units. The X-ray diffraction studies at variable temperatures showed no phase transitions in the range of 295-100 K but revealed a significant decrease in the volume per atom from 14.2 to 13.3 Å3. This noticeable thermal compressibility effect is discussed in connection with the solid-state packing of the [Ru2(O2CCF3)4] chains. The highly electrophilic character of the diruthenium(II,II) units has been shown by the gas-phase deposition reaction of [Ru2(O2CCF3)4] with an aromatic donor substrate, namely [2.2]paracyclophane (C16H16). As a result of the above reaction, a new arene adduct [Ru2(O2CCF3)4·C16H16] (2) has been isolated in crystalline form. It has an extended one-dimensional (1D) chain structure comprised of alternating building units and based on the rare bridging mode of [2.2]paracyclophane, [Ru2(O2CCF3)4·(2-2:2-C16H16)]. The magnetic susceptibility of 1 and 2 has been measured and compared in the range of 1.8-300 K. In addition, in the course of synthesis of 1 by the carboxylate exchange reactions, a new mixed-carboxylate diruthenium(II,II) core complex [Ru2(O2CCF3)3(O2CC2H5)] (3), bearing no exogenous ligands, has also been isolated and structurally characterized. It exhibits an interesting polymeric structure in which the ruthenium(II) centers selectively form axial interdimer contacts with the O-atoms of the propionate groups only.The title compound, [Ru2(O2CCF3)4] (1), has been obtained without any exogenous ligands and crystallized by deposition from the gas phase at 170 C. Its crystal structure has been determined for the first time to confirm an infinite chain motif built on axial Ru···O interactions of the diruthenium(II,II) units. The X-ray diffraction studies at variable temperatures showed no phase transitions in the range of 295-100 K but revealed a significant decrease in the volume per atom from 14.2 to 13.3 Å3. This noticeable thermal compressibility effect is discussed in connection with the solid-state packing of the [Ru2(O2CCF3)4] chains. The highly electrophilic character of the diruthenium(II,II) units has been shown by the gas-phase deposition reaction of [Ru2(O2CCF3)4] with an aromatic donor substrate, namely [2.2]paracyclophane (C16H16). As a result of the above reaction, a new arene adduct [Ru2(O2CCF3)4·C16H16] (2) has been isolated in crystalline form. It has an extended one-dimensional (1D) chain structure comprised of alternating building units and based on the rare bridging mode of [2.2]paracyclophane, [Ru2(O2CCF3)4·(2-2:2-C16H16)]. The magnetic susceptibility of 1 and 2 has been measured and compared in the range of 1.8-300 K. In addition, in the course of synthesis of 1 by the carboxylate exchange reactions, a new mixed-carboxylate diruthenium(II,II) core complex [Ru2(O2CCF3)3(O2CC2H5)] (3), bearing no exogenous ligands, has also been isolated and structurally characterized. It exhibits an interesting polymeric structure in which the ruthenium(II) centers selectively form axial interdimer contacts with the O-atoms of the propionate groups only