Tannin Gels and Their Carbon Derivatives: A Review

International audienceTannins are one of the most natural, non-toxic, and highly reactive aromatic biomolecules classified as polyphenols. The reactive phenolic compounds present in their chemical structure can be an alternative precursor for the preparation of several polymeric materials for applications in distinct industries: adhesives and coatings, leather tanning, wood protection, wine manufacture, animal feed industries, and recently also in the production of new porous materials (i.e., foams and gels). Among these new polymeric materials synthesized with tannins, organic and carbon gels have shown remarkable textural and physicochemical properties. Thus, this review presents and discusses the available studies on organic and carbon gels produced from tannin feedstock and how their properties are related to the different operating conditions, hence causing their cross-linking reaction mechanisms. Moreover, the steps during tannin gels preparation, such as the gelation and curing processes (under normal or hydrothermal conditions), solvent extraction, and gel drying approaches (i.e., supercritical, subcritical, and freeze-drying) as well as the methods available for their carbonization (i.e., pyrolysis and activation) are presented and discussed. Findings from organic and carbon tannin gels features demonstrate that their physicochemical and textural properties can vary greatly depending on the synthesis parameters, drying conditions, and carbonization methods. Research is still ongoing on the improvement of tannin gels synthesis and properties, but the review evaluates the application of these highly porous materials in multidisciplinary areas of science and engineering, including thermal insulation, contaminant sorption in drinking water and wastewater, and electrochemistry. Finally, the substitution of phenolic materials (i.e., phenol and resorcinol) by tannin in the production of gels could be beneficial to both the bioeconomy and the environment due to its low-cost, bio-based, non-toxic, and non-carcinogenic characteristics

Investigation of sustainable porous carbon as radar absorbing material

Radar Absorbing Materials (RAMs) are composite materials able to attenuate an incident electromagnetic wave. Usually, RAMs are made of a polymeric matrix and an electromagnetic absorbent filler, such as silicon carbide or carbon black. Several materials have been investigated as potential fillers, aiming to improve the Reflection Loss (RL) and absorption bandwidth broadening. In this paper, a composite made with silicone rubber and biochar was investigated as a sustainable porous carbon made with biomass waste. Five different composites were characterized, composed of 1 - 5 wt.% of biochar in the silicone rubber. Although the RL of pure biochar composites is not significant, it was demonstrated here how a biochar composite can improve the RL of a RAM material when it is applied as a double-layer structure. While the RL of a ferrite-based RAM with 2.0 mm thickness reaches -28 dB, a combination of this RAM with biochar composite reaches ~ -60 dB with the same thickness. The double-layer structure with 2.3 mm thickness can have an absorption bandwidth of 2.95 GHz over the X-band frequency range, and a structure with 2.6 mm thickness can reach a RL of ~-76 dB. This demonstrates a sustainable, cheaper, and lighter material application (i.e., biochar), which is successfully used in the development of high-efficient electromagnetic shield or sensors.Keywords: Biochar, permittivity, RAM, sustainability, reflectivity.

Caracterização eletromagnética do compósito de carbeto de silício e negro de fumo em matriz polimérica

Este trabalho apresenta as propriedades eletromagnéticas de um Material Absorvedor de Radiação Eletromagnética (MARE) feito a partir de Carbeto de Silício (SiC) e Negro de Fumo (NF) como aditivos. O compósito SiC/NF foi produzido utilizando 70 %(m/m) de matriz de silicone, e variando as concentrações do aditivo em 3 %(m/m), 2 %(m/m) e 1 %(m/m) de NF com 27 %(m/m), 28 %(m/m) e 29 %(m/m) de SiC, respectivamente. A estrutura química e a morfologia das partículas de SiC e NF foram analisadas através de espectroscopia Raman e Microscopia Eletrônica de Varredura (MEV). As propriedades dielétricas dos MAREs foram obtidas por meio do analisador de rede vetorial na faixa de frequência de 12,4 a 18,0 GHz. Os resultados de refletividade mostraram que o compósito SiC/NF com 1 %(m/m) de NF apresentou a melhor absorção de radiação eletromagnética, chegando a -47,9 dB em 16,8 GHz com uma amostra de aproximadamente 5,5 mm de espessura.Palavras-chave: MARE, banda Ku, refletividade, permissividade, material dielétrico.