Mesoporous NH4NiPO4·H2O for High-Performance Flexible All-Solid-State Asymmetric Supercapacitors

Nowadays, wearable energy storage devices have been growing rapidly, but flexible systems with both excellent cycling stability and decent flexibility are still challenging. In this work, a flexible all-solid-state NH4NiPO4·H2O//graphene supercapacitor with remarkable performance was successfully assembled. When cycled at a current density of 5 mA cm−2, the device delivered 121 mF cm−2, and showed good cycling stability after 3,000 cycles. Moreover, the all-solid-state NH4NiPO4·H2O//graphene supercapacitor also exhibit high mechanical flexibility with well-maintained specific capacitance, even under bending to arbitrary angles (up to 180°) and different weights (up to 50 g)

Nitrogen-Doped Carbon Coated WS2 Nanosheets as Anode for High-Performance Sodium-Ion Batteries

Due to the cost-effectiveness of sodium source, sodium-ion batteries (SIBs) have attracted considerable attention. However, SIBs still have some challenges in competing with lithium-ion batteries for practical applications. Particularly, the high rate capability and cycling stability are posing big problems for SIBs. Here, nitrogen-doped carbon-coated WS2 nanosheets (WS2/NC) were successfully synthesized by a high-temperature solution method, followed by carbonization of polypyrrole. When used as anode electrodes for SIBs, WS2/NC composite exhibited high-rate capacity at 386 and 238.1 mAh g−1 at 50 and 2,000 mA g−1, respectively. Furthermore, even after 400 cycle, the composite electrode could still deliver a capacity of ~180.1 mAh g−1 at 1,000 mA g−1, corresponding to a capacity loss of 0.09% per cycle. The excellent electrochemical performance could be attributed to the synergistic effect of the highly conductive nature of the nitrogen-doped carbon-coating and WS2 nanosheets. Results showed that the WS2/NC nanosheets are promising electrode materials for SIBs application

Simulation analysis of minimum bending radius for lead frame copper alloys

Copper alloy has a lot of excellent properties, so it becomes an important alloy for lead frame materials for the integrated circuit. The minimum bending radius of three different copper alloys (Cu-Fe-P, Cu-Ni-Si, Cu-Cr-Sn-Zn) for lead frame materials was analyzed by using finite element. Tensile tests for the three kinds of materials were done to obtain yield stress, ultimate strength and other parameters. The strain-hardening exponent n and normal anisotropy index r of the materials were obtained according to the tensile tests. The minimum bending radius of corresponding materials was available with the simulation analysis, and consequently, the bending properties of the different materials were compared. The results show that the bending property of Cu-Cr-Sn-Zn alloy is the best, and Cu-Ni-Si alloy the worst

Simulation analysis of minimum bending radius for lead frame copper alloys

Copper alloy has a lot of excellent properties, so it becomes an important alloy for lead frame materials for the integrated circuit. The minimum bending radius of three different copper alloys (Cu-Fe-P, Cu-Ni-Si, Cu-Cr-Sn-Zn) for lead frame materials was analyzed by using finite element. Tensile tests for the three kinds of materials were done to obtain yield stress, ultimate strength and other parameters. The strain-hardening exponent n and normal anisotropy index r of the materials were obtained according to the tensile tests. The minimum bending radius of corresponding materials was available with the simulation analysis, and consequently, the bending properties of the different materials were compared. The results show that the bending property of Cu-Cr-Sn-Zn alloy is the best, and Cu-Ni-Si alloy the worst

Effects of Microstructure, Mechanical and Physical Properties on Machinability of Graphite Cast Irons

Flake (FGI) and spheroidal (SGI) graphite cast irons are often used to produce workpieces, which often need to be machined. Machinability differences under various machining methods are the basis for choosing machining equipment and technology. In this work, FGI and SGI were used to produce tractor front brackets, and the machinability of both materials under turning and drilling processes was compared. The machinability (turning and drilling ability) has been evaluated in terms of machining load, chips shape, surface roughness, and tool temperature. The influence of materials microstructure and thermal conductivity on the machinability was analyzed. In the turning process, the cutting force and its standard deviation of the FGI were larger than the SGI due to the higher volume fraction of pearlite. The surface roughness was similar in both materials. In the drilling process, the even action of the friction and cutting force on the bit turned into similar drilling loads for both materials. Higher friction and lower thermal conductivity caused a higher bit temperature in SGI drilling compared to FGI. The chip breaking was worse in SGI drilling, where the longer chips scratched the internal surface of the holes, resulting in the higher surface roughness

Cu-Doped ZnO Electronic Structure and Optical Properties Studied by First-Principles Calculations and Experiments

The band structure, the density of states and optical absorption properties of Cu-doped ZnO were studied by the first-principles generalized gradient approximation plane-wave pseudopotential method based on density functional theory. For the Zn1-xCuxO (x = 0, x = 0.0278, x = 0.0417) original structure, geometric optimization and energy calculations were performed and compared with experimental results. With increasing Cu concentration, the band gap of the Zn1-xCuxO decreased due to the shift of the conduction band. Since the impurity level was introduced after Cu doping, the conduction band was moved downwards. Additionally, it was shown that the insertion of a Cu atom leads to a red shift of the optical absorption edge, which was consistent with the experimental results

Melamine Foam-Derived Carbon Scaffold for Dendrite-Free and Stable Zinc Metal Anode

Aqueous Zn-ion batteries (AZIBs) are one of the most promising large-scale energy storage devices due to the excellent characteristics of zinc metal anode, including high theoretical capacity, high safety and low cost. Nevertheless, the large-scale applications of AZIBs are mainly limited by uncontrollable Zn deposition and notorious Zn dendritic growth, resulting in low plating/stripping coulombic efficiency and unsatisfactory cyclic stability. To address these issues, herein, a carbon foam (CF) was fabricated via melamine-foam carbonization as a scaffold for a dendrite-free and stable Zn anode. Results showed that the abundant zincophilicity functional groups and conductive three-dimensional network of this carbon foam could effectively regulate Zn deposition and alleviate the Zn anode’s volume expansion during cycling. Consequently, the symmetric cell with CF@Zn electrode exhibited lower voltage hysteresis (32.4 mV) and longer cycling performance (750 h) than the pure Zn symmetric cell at 1 mA cm−2 and 1 mAh cm−2. Furthermore, the full battery coupling CF@Zn anode with MnO2 cathode can exhibit a higher initial capacity and better cyclic performance than the one with the bare Zn anode. This work brings a new idea for the design of three-dimensional (3D) current collectors for stable zinc metal anode toward high-performance AZIBs

Facile Synthesis of Two-Dimensional Porous MgCo2O4 Nanosheets as Anode for Lithium-Ion Batteries

Lithium-ion batteries (LIBs) have drawn considerable attention due to their high energy density and good cycling stability. As a transition-metal oxide, MgCo2O4 (MCO) is a promising candidate for energy storage applications because of its low-cost and environmental characteristics. Here, MCO porous nanosheets have been successfully synthesized by a microwave-assisted liquid phase method followed by an annealing procedure. As a result, MCO annealed at 600 °C exhibited optimal rate and cycling performances for Lithium storage application. Specifically, when tested as anode materials for Lithium ion batteries, MCO porous nanosheets delivered a high specific capacity of 1173.8 mAh g−1 at 200 mA g−1, and the specific capacity reached 1130.1 mAh g−1 after 100 cycles at 200 mA g−1, achieving 96.3% for the retention rate. The excellent electrochemical performances are mainly attributed to the monolayer porous nanosheet, which provides short transport paths for Li ions and electrons. Results demonstrated that the MCO porous nanosheets are promising electrode materials for Lithium ion batteries applications

An Enhanced Second-Order Cone Programming-Based Evaluation Method on Maximum Hosting Capacity of Solar Energy in Distribution Systems with Integrated Energy

In order to adjust to the change of the large-scale deployment of photovoltaic (PV) power generation and fully exploit the potentialities of an integrated energy distribution system (IEDS) in solar energy accommodation, an evaluation method on maximum hosting capacity of solar energy in IEDS based on convex relaxation optimization algorithm is proposed in this paper. Firstly, an evaluation model of maximum hosting capacity of solar energy for IEDS considering the electrical-thermal comprehensive utilization of solar energy is proposed, in which the maximization of PV capacity and solar collector (SC) capacity are fully considered. Secondly, IEDS’s potential in electricity, heat, and gas energy coordinated optimization is fully exploited to enhance the hosting capacity of solar energy in which the electric distribution network, heating network, and natural gas network constraints are fully modeled. Then, an enhanced second-order cone programming (SOCP)-based method is employed to solve the proposed maximum hosting capacity model. Through SOCP relaxation and linearization, the original nonconvex nonlinear programming model is converted into the mixed-integer second-order cone programming model. Meanwhile, to ensure the exactness of SOCP relaxation and improve the computation efficiency, increasingly tight linear cuts of distribution system and natural gas system are added to the SOCP relaxation. Finally, an example is given to verify the effectiveness of the proposed method. The analysis results show that the maximum hosting capacity of solar energy can be improved significantly by realizing the coordination of an integrated multi-energy system and the optimal utilization of electricity, heat, and gas energy. By applying SOCP relaxation, linearization, and adding increasingly tight linear cuts of distribution system and natural gas system to the SOCP relaxation, the proposed model can be solved accurately and efficiently