Iron(III) chelating resins-IV. Crosslinked copolymer beads of 1-(B-acrylamidoethyl)-3-hydroxy-2-methyl-4(1H)-pyridinone (AHMP) with 2-hydroxyethyl methacrylate (HEMA)

Iron(III) chelating beads have been synthesized by copolymerization of 1-(ß-acrylamidoethyl)-3-hydroxy-2-methyl-4(IH)-pyridinone (AHMP) with 2-hydroxyethyl methacrylate (HEMA), and ethyleneglycol dimethacrylate (EGDMA) as the crosslinking agent. The synthesis of the AHMP-HEMA beads was performed by suspension polymerization of AHMP, HEMA and EGDMA in benzyl alchol¿20% aqueous NaCl solution using 2,2¿-azobisisobutyronitrile (AIBN) as the initiator and polyvinylalcohol (40¿88) as a suspending agent.\ud \ud The crosslinked copolymer beads were characterized by IR, and the AHMP content was determined by elemental analysis. The AHMP-HEMA beads were not too hydrophilic, and the copolymers absorbed at equilibrium only 40¿50% water. It was found that the copolymer beads were very stable at 25°, but some degradation was observed at 121°.\ud \ud The AHMP-HEMA copolymers were able to chelate iron(III) and the chelation was dependent on the conditions such as pH and temperature. However, the capacities towards iron(III) chelation were always found to be much lower than the calculated values. The influence of the polymeric matrix on the iron(III) chelating ability was studied with iron(III) chelating resins containing various polymeric matrices. It was found that the iron(III) chelating efficiencies of the resins were strongly affected by their hydrophilicities. The low chelating efficiency of the AHMP-HEMA beads (0¿40%) is probably due to their poor swelling in water

Simplified TeV leptophilic dark matter in light of DAMPE data

Using a simplified framework, we attempt to explain the recent DAMPE cosmic $e^+ + e^-$ flux excess by leptophilic Dirac fermion dark matter (LDM). The scalar ($\Phi_0$) and vector ($\Phi_1$) mediator fields connecting LDM and Standard Model particles are discussed. Under constraints of DM relic density, gamma-rays, cosmic-rays and Cosmic Microwave Background (CMB), we find that the couplings $P \otimes S$, $P \otimes P$, $V \otimes A$ and $V \otimes V$ can produce the right bump in $e^+ + e^-$ flux for a DM mass around 1.5 TeV with a natural thermal annihilation cross-section $\sim 3 \times 10^{-26} cm^3/s$ today. Among them, $V \otimes V$ coupling is tightly constrained by PandaX-II data (although LDM-nucleus scattering appears at one-loop level) and the surviving samples appear in the resonant region, $m_{\Phi_1} \simeq 2m_{\chi}$. We also study the related collider signatures, such as dilepton production $pp \to \Phi_1 \to \ell^+\ell^-$, and muon $g-2$ anomaly. Finally, we present a possible $U(1)_X$ realization for such leptophilic dark matter.Comment: discussions added, version accepted by JHE

N-(1-Naphth­yl)acetoacetamide

The title compound, C14H13NO2, exists in the keto form. An N—H⋯O hydrogen bond helps to establish the packing

{2,2′-[4-Methyl-4-aza­heptane-1,7-diylbis(nitrilo­methyl­idyne)]diphenolato}zinc(II)

In the title compound, [Zn(C21H25N3O2)], the ZnII atom is five-coordinate from three N donor atoms and two O donor atoms of the dianion ligand in a distorted trigonal–bipyramidal arrangement. Three methyl­ene groups of the ligand are disordered over two orientations in a 0.555 (6):0.445 (6) ratio