9 research outputs found

    JSCS–3961 Original scientific paper

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    An efficient one-pot synthesis of highly substituted furans catalyzed by N-bromosuccinimid

    Simple and improved regioselective brominations of aromatic compounds using N-benzyl-N,N-dimethylanilinium peroxodisulfate in the presence of potassium bromide under mild reactions conditions

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    A simple, efficient, and mild method for the selective bromination of some activated aromatic compounds using N-benzyl-N,N-dimethylanilinium peroxodisulfate in the presence of potassium bromide in non-aqueous solution is reported. The results obtained revealed good to excellent selectivity between the ortho and para positions of phenols and methoxyarenes

    An efficient one-pot synthesis of highly substituted furans catalyzed by N-bromosuccinimide

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    N-Bromosuccinimide was found to efficiently catalyze the synthesis of highly functionalized, tetra-substituted furan derivatives in the one-pot reactions of but-2-ene-1,4-diones and acetoacetate esters in the presence of i-PrOH as solvent under mild and neutral conditions at 80–90 °C for 3–7 h in high yields (87–94 %)
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