One pot preparation of CeO2@Alginate composite beads for the catalytic reduction of MB dye: Effect of cerium percentage

This study focuses on the preparation of composite beads CeO2@Alginate using a one-pot method. Ce(III) was used as a crosslinking agent and then was modified with a base to transform it into CeO2 encapsulated in the alginate matrix. To study the catalytic behavior of this material the reduction of MB dye in the presence of NaBH4 was selected as a model reaction. Several parameters affecting the reduction of the MB dye were studied such as the effect of cerium content in the composite beads, the concentration of NaBH4 and the concentration of the MB dye. The results showed that the dispersion of alginate in a solution containing Ce(III) leads to the formation of hydrogel beads. The treatment of the beads with a basic solution leads to the in-situ formation of CeO2 inside the beads with a porous structure. The catalytic activity of composite beads has shown interesting results via the reduction of MB dye. The reduction of MB dye catalyzed by CeO2@ALG(2%) was total in 2 min and the associated rate constant was 2.3 min–1. The reuse tests were studied during five successive cycles, in which it was shown that the CeO2@ALG(2%) catalyst was stable without losing its effectiveness

Synthesis and application of metal nanoparticles-loaded mesoporous silica toward the reduction of organic pollutants in a simple and binary system

In this work, mesoporous silica MCM-41 was prepared by hydrothermal route, and the obtained as-synthesized material (CTA-MCM-41) was modified by two different methods using silver and cerium assisted by thermal treatment. The modified materials were characterized by XRD, FTIR, XRF, XPS, nitrogen sorption measurements at −196 °C, SEM, and TEM analyses. The modified materials were tested as catalysts in a simple and binary system via the reduction reaction of Methylene Blue (MB), Congo Red (CR), 4-Nitrophenol (4-NP), Methyl Orange (MO), Orange G (OG) in the presence of NaBH4. The effect of the nanoparticles size, their dispersions, the nature of the organic pollutant, the initial concentration of the organic pollutant, and the concentration of the reducing agent NaBH4 have been studied and discussed. The obtained results confirmed that the preparation method plays an important role in the content and nature of nanoparticles, their sizes, their dispersions, and also on their catalytic performance. The Ag-Ce-MCM-2 material was selected as the best catalyst due to the synergistic effect between AgNPs and CeO2. The rate constant calculated in the simple system for the different pollutants was as follows: 0.1829 s−1, 0.1762 s−1, 0.0606 s−1, 0.0585 s−1, 0.0556 s−1 for MO, OG, MB, 4-NP, CR, respectively. The reduction in a binary system containing CR and MB or MO and MB was in competition, in which the CR or MO degrades together with the MB dye. Whereas for the other binary systems containing 4-NP/MB or OG/MB, the catalyst Ag-Ce-MCM-2 was more selective towards the MB dye. This catalyst demonstrated efficiency and reusability across different cycles, in which the conversion of the MB dye was complete in each reuse

Catalytic Reduction of Dyes and Antibacterial Activity of AgNPs@Zn@Alginate Composite Aerogel Beads

This work focuses on the preparation of aerogel composite beads based on Zn(II)-crosslinked alginate and loaded with different percentages of AgNPs using a simple approach. The obtained samples were evaluated in two different applications: the first application consists in their use as catalysts for the reduction of MB, MO, OG and CR dyes in a simple and binary system under the presence of NaBH4. For this, several parameters affecting the catalytic behavior of these catalysts have been investigated and discussed such as the catalyst mass, AgNPs content, dye nature, and the selectivity of the catalyst in a binary system. The second application concerns their antibacterial activities towards two Gram-negative bacteria Escherichia coli (ATCC 25922), and Pseudomonas aeruginosa (ATCC 27853), and a Gram-positive bacteria Staphylococcus aureus (ATCC 25923). The physico-chemical properties of different samples were characterized by XRD, FTIR, SEM/EDS, and TGA analysis. The obtained results confirmed the presence of AgNPs on a highly porous alginate structure. The dispersion of a high percentage of AgNPs leads to the formation of nanoparticles on the outer surface of the alginate which led to their leaching after the catalytic test, while the composite having a low percentage of AgNPs showed good results through all dyes without leaching of AgNPs. For the antibacterial application of the different samples, it was shown that a composite with a higher percentage of AgNPs was the most effective against all bacteria

Assessment of AgNPs@Cu@Alginate Composite for Efficient Water Treatment: Effect of the Content of Cu(II) Crosslinking Agent

This work concerns the preparation of multifunctional composite beads based on Cu-Alginate and AgNPs. First, the Cu-Alginate hydrogel was obtained by adding alginate at different concentrations of the crosslinking agent Cu2+ (2%, 4%, and 8%). The obtained hydrogels were modified by Ag+ species then by a chemical treatment (using NaBH4) followed by freeze-drying. The obtained aerogel beads were characterized by different methods and then were used as catalysts for the reduction of organic pollutants in a simple and binary system, and also as antibacterial and antifungal agents on different strains. The results showed the formation of a porous structure containing well-dispersed silver nanoparticles in the alginate matrix. The concentration of the Cu2+ crosslinking agent significantly influences the content of encapsulated AgNPs, the catalytic activity, and thus the antibacterial and antifungal properties of the resulting material. In the catalysis part, the Cu(2%)-ALG(AgNPs) material was selected as the most efficient catalyst due to the presence of high content of AgNPs and their good dispersion in the alginate biopolymer. High conversions of MO, 4-NP, MB, and CR were obtained in a reaction time of 2.5, 26, 23, and 29 min, respectively. Thus for binary systems, the Cu(2%)-ALG(AgNPs) catalyst was more selective with the MB dye. For antibacterial and antifungal activities all materials were effective through six strains, but it was shown that materials with unreduced Ag+ species were more effective

Zinc nanoparticles encapsulated in porous biopolymer beads for reduction of water pollutants and antimicrobial activity

This work focuses on the preparation of composite beads from alginate crosslinked with copper at several loading percent and also loaded with ZnNPs. Th obtained samples were applied as catalysts for the reduction of the organic polluants 4-NP, MB, OG, MO, and CR in simple and binary systems. XRD results and TEM images confirmed the presence of ZnNPs in the polymer matrix. XRF and TGA analysis showed that the percentage of the cross-linking agent significantly influences the content of ZnNPs as well as the thermal stability of the resulting material. The catalytic activity of the composite beads showed that the Cu(4 %)-ALG(ZnNPs) sample was the best catalyst for all pollutants. In the simple system, the recorded rate constants for MB, MO, 4-NP, OG, and CR were 0.0133 s−1, 0.0076 s−1, 0.005 s−1, 0.0042 s−1, 0.0036 s−1, respectively. The catalyst was more selective towards the cationic MB dye for binary systems. For antibacterial and antifungal applications, the different materials containing ZnNPs and their counterparts containing Zn2+ were found to be active across all bacterial strains (Gram positive and Gram negative) as well as fungi, and the Zn2+-containing composites in particular performed better across all bacteria and fungi

Primary urachal adenocarcinoma treated effectively with surgery and post operative chemoradiation therapy: Case Report with review of the literature

Urachal carcinomas is a rare and aggressive tumor, accounting for less than 1% of all bladder cancers. We report a case of a 32-year-old man, with no past medical history, complaining of a total hematuria. The abdominal computed tomography scan revealed an exophytic mass of 3 cm on the dome of the bladder, extending to the urachus. The computed tomography scan of chest, abdomen and pelvis did not show neither regional or distant metastasis. Partial Cystectomy with umbilectomy was performed. Histopathology was in favor of urachal adenocarcinoma, classed pT3a, based on Sheldon's staging system, pT2b based on Mayo system, and pT2 based on Ontario system