28,101 research outputs found
Synthesis and properties of Co-doped titanate nanotubes and their optical sensitization with methylene blue
Here we report on a novel chemical route to synthesize homogenous cobalt
doped titanate nanotubes (CoTNT), using an amorphous Co-doped precursor. The
influence of the synthesis temperature, autoclave dwell time and metal doping
on the structural and microstructural as well as on the optical properties of
the synthesized titanate nanotubes is studied and discussed. The optical band
gaps of the CoTNT samples are red shifted in comparison with the values
determined for the undoped samples, such red shifts bringing the absorption
edge of the CoTNT samples into the visible region. CoTNT materials also
demonstrate particular high adsorption ability for methylene blue, the amount
of the adsorbed dye being higher than the one predictable for a monolayer
formation. This suggests the possibility of intercalation of the dye molecule
between the TiO6 layers of the TNT structure. It is also shown that the
methylene blue sensitized Co-doped nanostructures are highly stable under UV
radiation and present a strong and broad absorption in the visible region.Comment: 31 pages, 3 tables, 7 figure
Lorentz-breaking effects in scalar-tensor theories of gravity
In this work, we study the effects of breaking Lorentz symmetry in
scalar-tensor theories of gravity taking torsion into account. We show that a
space-time with torsion interacting with a Maxwell field by means of a
Chern-Simons-like term is able to explain the optical activity in syncrotron
radiation emitted by cosmological distant radio sources. Without specifying the
source of the dilaton-gravity, we study the dilaton-solution. We analyse the
physical implications of this result in the Jordan-Fierz frame. We also analyse
the effects of the Lorentz breaking in the cosmic string formation process. We
obtain the solution corresponding to a cosmic string in the presence of torsion
by keeping track of the effects of the Chern-Simons coupling and calculate the
charge induced on this cosmic string in this framework. We also show that the
resulting charged cosmic string gives us important effects concerning the
background radiation.The optical activity in this case is also worked out and
discussed.Comment: 10 pages, no figures, ReVTex forma
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