867 research outputs found
Synthesis and Properties of Dipyridylcyclopentenes
A short and general route to the substituted dipyridylcyclopentenes was explored and several new compounds belonging to this new group of diarylethenes were synthesized. The study of their photochromic and thermochromic properties shows that the rate of the thermal ring opening is strongly dependent on the polarity of the solvent.
Spin Relaxation in Graphene with self-assembled Cobalt Porphyrin Molecules
In graphene spintronics, interaction of localized magnetic moments with the
electron spins paves a new way to explore the underlying spin relaxation
mechanism. A self-assembled layer of organic cobalt-porphyrin (CoPP) molecules
on graphene provides a desired platform for such studies via the magnetic
moments of porphyrin-bound cobalt atoms. In this work a study of spin transport
properties of graphene spin-valve devices functionalized with such CoPP
molecules as a function of temperature via non-local spin-valve and Hanle spin
precession measurements is reported. For the functionalized (molecular)
devices, we observe a slight decrease in the spin relaxation time ({\tau}s),
which could be an indication of enhanced spin-flip scattering of the electron
spins in graphene in the presence of the molecular magnetic moments. The effect
of the molecular layer is masked for low quality samples (low mobility),
possibly due to dominance of Elliot-Yafet (EY) type spin relaxation mechanisms
Enantiomerically pure β-phenylalanine analogues from α–β-phenylalanine mixtures in a single reactive extraction step
An efficient and selective method for the extraction of α-amino acids in preference over their β-isomers using PdCl2(PPh3)2 was discovered, which enables the separation of product mixtures obtained in the enantioselective enzymatic formation of β-amino acids.
- …