THE ISOTOPIC SIGNATURE OF THE MINERALIZING FLUID OF THE LAVRION CARBONATE-REPLACEMENT PB-ZN-AG DISTRICT

The Pb-Zn-Ag carbonate-replacement deposits in the Lavrion district are genetically related to a 7- 10 Ma-old granodiorite, felsic dikes and sills. These deposits are hosted in the Upper and Lower marble and schists of the Cyclades Blueschist unit and occur along the major Legraina detachment fault. Carbonate-replacement orebodies occur as “mantos” and veins, dominated by base metal sulfides and Ag, Bi, Sn, Sb, As, and Pb sulfosalts. Calculated carbon and oxygen isotope compositions of the hydrothermal fluid range from δ13CCO2 of -13.7 to 0.8 per mil and δ18OH2O of 4.2 to 27.4 per mil, at 400º, 350º, 320º, 300º, 250º and 200ºC. These isotopic compositions reveal water-torock ratios ranging from 4.8 to 52.6%, which reflect intense interaction of the ore fluid with the host rock in a water-dominated, transitional closed to open hydrothermal system. The range of δ34SH2S for sulfides in the deposits were from -8.5 to 6.8 per mil, for similar temperatures, whereas for barite-fluorite veins from δ34SH2S of -43.6 to -16.4 per mil, at 200º, 150º and 100ºC. This range implies that there was contribution from a magmatic sulfur component exsolved from the Plaka pluton, as well as contribution from a metasedimentary component. Based on the isotopic signature of sulfur for barite, the ranges from -6.7 to -7.6, comprising an increase in the fluid influx. Isotopic temperatures based on pyrite-galena and sphalerite-pyrite pairs revealed at least three major events of carbonate-replacement ore deposition, (i) at ~ 360º, (ii) 320º-280ºand (iii) 260º-200ºC

Karakasi mines, Hermione, evolution of a Cyprus-type Cu-Zn deposit, Argolis, Greece

The Hermione Cyprus-type Cu-Zn deposits, Argolis, Greece, are hosted in Miocene ophiolites overlain by terrigenous turbidites with intercalations of limestones and manganiferous iron formations. The ore deposits form irregular lenticular or stratiform ore bodies, and veins. These ore bodies are associated with marginal volcanic activity in an arc-related Miocene palaeocontinent. Late N- to NNE-trending, sinistral, milky quartz-pyrite-calcite veins cut the host ophiolites. Alteration haloes of quartz-calcite, albite-sericite-chlorite, and chalcedony-epidote-clay minerals envelop the veins or develop in the lavas as concentric shells. The tellurium-bearing Cu-Zn mineralization is developed in two successive stages followed by a supergene stage. The Co-pyrite- chalcopyrite geothermometer defined two stages of sulphide equilibrium: 310° to 375°C (Stage I), and 220° to 260°C (Stage II). The calculated δ180 and \u3c5D compositions of the waters reflect the dominance of a magmatic component. The calculated δ3^Η^ fluid values also reveal a magmatic source for the sulphur, with minor contribution from submarine sediments, whereas tellurium is proposed to be derived from a mafic-ultramafic source. The physicochemical conditions of the hydrothermal fluids in the Hermione system were T=250°-300°C, P ~ 450 bars, pH =j61 to 530,fS2 HS aq) : = 10\u2711·6 to 10-12·4,fo2 = 10-35·5 to 10-38·3, logaH2S(aq) = 10\u273\u277 to 10\u2740, and loga = 10\u271 2·6 to 10-3·4

Cervelleite, Ag4TeS: solution and description of the crystal structure

Copyright: Springer-Verlag Wien 2015. This is the final, post refereeing version. You are advised to consult the publisher's version if you wish to cite from it, http://link.springer.com/article/10.1007%2Fs00710-015-0384-

Demonstration of 4H-SiC JFET Digital ICs Across 1000 C Temperature Range Without Change to Input Voltages

Operational testing of prototype 4H-SiC JFET ICs across an unrivaled ambient temperature span in excess of 1000 C, from -190 C to +812 C, has been demonstrated without any change/adjustment of input signal levels or power supply voltages. This unique ability is expected to simplify infusion of this IC technology into a broader range of beneficial applications

The evolution of a W, Au-Ag-Te and Au-Ag hydrothermal system, Tinos Island, Cyclades, Greece

At Tinos Island, Greece, the physicochemical evolution of the hydrothermal system and the associated stages of metallic mineralization that are developed in the vicinity of the Tinos granodiorite-leucogranite has been studied, based on fluid inclusion studies and chemical reactions modeling. Early tungsten mineraliozation was related to the metasomatic stage of contact metamorphism and precipitated at ~ 350oC, from moderate saline (10.4 to 14.8 wt% NaCl eq.), CO2- effervescing fluids, that contained variable amounts of CaCl2 and MgCl2. Panormos Bay Au-Ag-Te mineralization, located 16 km away from the intrusive site, was deposited from cooler 200° to 300oC, and low to moderate saline (0.2 to 13.2 wt% NaCl eq.) mineralizing fluids. Au-Ag mineralization at Apigania Bay, which represents a late evolutionary phase, was deposited from even cooler (125o to 235oC) and dilute (0.2 to 6.8 wt % NaCl eq.) fluids. In all, the mineralization stage precipitation was controlled by two principal factors: the exsolution of gaseous phase and an increase in pH from 3.3 to 7.6

Glaucoma detection: the content of optometric eye examinations for a presbyopic patient of African racial descent

Aims: Standardised patient (SP) methodology is the gold standard for evaluating clinical practice. We investigated the content of optometric eyecare for an early presbyopic SP of African racial descent, an “at-risk” patient group for primary open-angle glaucoma (POAG). Methods: A trained actor presented unannounced as a 44-year-old patient of African racial descent, complaining of recent near vision difficulties, to 100 community optometrists for an audio-recorded eye examination. The eye examinations were subsequently assessed via a checklist based on evidence-based POAG reviews, clinical guidelines and expert panel opinion. Results: Ninety-five per cent of optometrists carried out optic disc assessment and tonometry, which conforms to the UK College of Optometrists’ advice that those patients aged >40 years should receive at least two of the following tests: tonometry, optic disc assessment, visual field testing. Thirty-five per cent of optometrists carried out all of these tests and 6% advised the SP of increased POAG risk in those of African racial descent. Conclusion: SP encounters are an effective measure of optometric clinical practice. As in other healthcare disciplines, there are substantial differences between optometrists in the depth of their clinical investigations, challenging the concept of a “standard sight test”. There is a need for continuing professional development (CPD) in glaucoma screening, in which the increased risk of POAG in those of African racial descent should be emphasised

Yearlong 500 C Operational Demonstration of Up-Scaled 4H-SiC JFET Integrated Circuits

This work describes recent progress in the design, processing, and testing of significantly up-scaled 500 C durable 4H-SiC junction field effect transistor (JFET) integrated circuit (IC) technology with two-level interconnect undergoing development at NASA Glenn Research Center. For the first time, stable electrical operation of semiconductor ICs for over one year at 500 C in air atmosphere is reported. These groundbreaking durability results were attained on two-level interconnect JFET demonstration ICs with 175 or more transistors on each chip. This corresponds to a more than 7-fold increase in 500 C-durable circuit complexity from the 24 transistor ring oscillator ICs reported at HiTEC 2016. These results advance the technology foundation for realizing long-term durable 500 C ICs with increased functional capability for combustion engine sensing and control, planetary exploration, deep-well drilling monitoring, and other harsh-environment applications

Energy Trends: September 2020

Energy Trends and Energy Prices are produced by the Department for Business, Energy and Industrial Strategy (BEIS) on a quarterly basis. Both periodicals are published concurrently in June, September, December and March. The September editions cover the second quarter of the current year

6H-SiC Transistor Integrated Circuits Demonstrating Prolonged Operation at 500 C

The NASA Glenn Research Center is developing very high temperature semiconductor integrated circuits (ICs) for use in the hot sections of aircraft engines and for Venus exploration where ambient temperatures are well above the approximately 300 degrees Centigrade effective limit of silicon-on-insulator IC technology. In order for beneficial technology insertion to occur, such transistor ICs must be capable of prolonged operation in such harsh environments. This paper reports on the fabrication and long-term 500 degrees Centigrade operation of 6H-SiC integrated circuits based on epitaxial 6H-SiC junction field effect transistors (JFETs). Simple analog amplifier and digital logic gate ICs have now demonstrated thousands of hours of continuous 500 degrees Centigrade operation in oxidizing air atmosphere with minimal changes in relevant electrical parameters. Electrical characterization and modeling of transistors and circuits at temperatures from 24 degrees Centigrade to 500 degrees Centigrade is also described. Desired analog and digital IC functionality spanning this temperature range was demonstrated without changing the input signals or power supply voltages