Impact of Electrostatic Forces in Contact Mode Scanning Force Microscopy

In this $\ll$ contribution we address the question to what extent surface charges affect contact-mode scanning force microscopy measurements. % We therefore designed samples where we could generate localized electric field distributions near the surface as and when required. % We performed a series of experiments where we varied the load of the tip, the stiffness of the cantilever and the hardness of the sample surface. % It turned out that only for soft cantilevers could an electrostatic interaction between tip and surface charges be detected, irrespective of the surface properties, i.\,e. basically regardless its hardness. % We explain these results through a model based on the alteration of the tip-sample potential by the additional electric field between charged tip and surface charges

Sol-Gel Derived Ferroelectric Nanoparticles Investigated by Piezoresponse Force Microscopy

Piezoresponse force microscopy (PFM) was used to investigate the ferroelectric properties of sol-gel derived LiNbO$_3$ nanoparticles. To determine the degree of ferroelectricity we took large-area images and performed statistical image-analysis. The ferroelectric behavior of single nanoparticles was verified by poling experiments using the PFM tip. Finally we carried out simultaneous measurements of the in-plane and the out-of-plane piezoresponse of the nanoparticles, followed by measurements of the same area after rotation of the sample by 90$^{\circ}$ and 180$^{\circ}$. Such measurements basically allow to determine the direction of polarization of every single particle

Ultra-smooth lithium niobate micro-resonators by surface tension reshaping

Thermal treatment of micro-structured lithium niobate substrates at temperatures close to, but below the melting point, allows surface tension to reshape a preferentially melted surface zone [1] of the crystal to form ultra-smooth single crystal toroidal or spherical structures. Such structures, an example of which is shown in figure 1, are suitable for the fabrication of photonic micro-resonators with low scattering loss. The thermally treated material maintains its single crystal nature after the thermal treatment because the bulk remains solid throughout the process acting as seed during the recrystallization process which takes place during the cooling stage. The single crystal nature of the reshaped material has been verified by piezoresponse force microscopy, Raman spectroscopy and chemical etching. The inherent properties of lithium niobate crystals (optically nonlinear, piezoelectric and electro-optic) makes the resultant micro-resonator extremely suitable for sensing applications, for the production of micro-lasers (if doped with Er or Nd), for nonlinear frequency generation and finally for switching/modulation and tunable spectral filtering in optical telecommunications. The transformation of the initial surface micro-structures to the resulting resonator structure is a temperature dependent process as the surface tension acts on the surface melted layer of the crystal, Experimental investigation and modelling of the thermal treatment as well as investigation of the performance of these microresonators is underway to establish full control of the fabrication process for practical applications

Anomalous temperature evolution of the internal magnetic field distribution in the charge-ordered triangular antiferromagnet AgNiO2

Zero-field muon-spin relaxation measurements of the frustrated triangular quantum magnet AgNiO2 are consistent with a model of charge disproportionation that has been advanced to explain the structural and magnetic properties of this compound. Below an ordering temperature of T_N=19.9(2) K we observe six distinct muon precession frequencies, due to the magnetic order, which can be accounted for with a model describing the probable muon sites. The precession frequencies show an unusual temperature evolution which is suggestive of the separate evolution of two opposing magnetic sublattices.Comment: 4 pages, 3 figure

Comparing and characterizing some constructions of canonical bases from Coxeter systems

The Iwahori-Hecke algebra $\mathcal{H}$ of a Coxeter system $(W,S)$ has a "standard basis" indexed by the elements of $W$ and a "bar involution" given by a certain antilinear map. Together, these form an example of what Webster calls a pre-canonical structure, relative to which the well-known Kazhdan-Lusztig basis of $\mathcal{H}$ is a canonical basis. Lusztig and Vogan have defined a representation of a modified Iwahori-Hecke algebra on the free $\mathbb{Z}[v,v^{-1}]$-module generated by the set of twisted involutions in $W$, and shown that this module has a unique pre-canonical structure satisfying a certain compatibility condition, which admits its own canonical basis which can be viewed as a generalization of the Kazhdan-Lusztig basis. One can modify the parameters defining Lusztig and Vogan's module to obtain other pre-canonical structures, each of which admits a unique canonical basis indexed by twisted involutions. We classify all of the pre-canonical structures which arise in this fashion, and explain the relationships between their resulting canonical bases. While some of these canonical bases are related in a trivial fashion to Lusztig and Vogan's construction, others appear to have no simple relation to what has been previously studied. Along the way, we also clarify the differences between Webster's notion of a canonical basis and the related concepts of an IC basis and a $P$-kernel.Comment: 32 pages; v2: additional discussion of relationship between canonical bases, IC bases, and P-kernels; v3: minor revisions; v4: a few corrections and updated references, final versio

Higher-order effects in the allowed beta decay of F20

It has been proposed by Gell-Mann(1) that the usual vector interaction in beta decay should be modified by addition of a small correction term due to the effect of virtual meson currents around the nucleons. This term in proportional to the difference of the anomalous magnetic moments of protons and neutrons and is of the order of 0.1% per Mev beta energy

An Evaluation Of Provision In A School Designated As Catering For Pupils Categorised As Having 'Emotional And Behavioural Difficulties' In The Light Of The Perspectives And Expectations Of Its Various Stakeholders

Line End is an 11-16 day school for pupils categorised as having emotional and behavioural difficulties (EBD). It is maintained by Farside Local Education Authority, and provides secondary education for pupils who are statemented as having emotional and behavioural difficulties. Some have additional learning difficulties, this assessment being based on reading ages that are considerably lower than their chronological ages, and scores in KS2 SATs that are below National averages. All referrals come through the local authority’s special educational needs department; invariably, the pupils who are placed at Line End either transfer from the EBD primary unit, or are those who have been excluded from mainstream secondary schools within the borough. The aim of the study is to establish the extent to which Line End is felt to be effective by its various stakeholders; and in establishing this position, it is first important to elicit the criteria by which the various stakeholders judge the school to be effective. The first phase of the study, therefore, is aimed at eliciting these stakeholder criteria, whilst the second phase focuses on the extent to which the school is perceived to be effective in its various areas of provision, based on these very criteria. A subsequent analysis of findings seeks to examine stakeholder perspectives, and the extent to which there is congruence and/or divergence of perspective amongst and between stakeholders might create conflict or tensions between and amongst stakeholders. Findings from the first phase of the study suggest that there is broad agreement amongst stakeholders about what should constitute effective provision for Line End pupils: addressing both academic and emotional/behavioural needs effectively, providing a safe and positive environment in which to make such provision, and providing opportunities for the reintegration of pupils to mainstream where appropriate and practicable. These three areas reflect the three major aims of the school as outlined in the staff handbook, and alongside these as key indicators of quality, stakeholders included relationships between home and school, and the management/organisation of the school -the extent to which it was strategically or ‘crisis’ managed. Findings from the second phase of the research suggested that the school was perceived to be effective by virtually all of its stakeholders - in some areas for some of the time. There were differences of perspective within stakeholder groups, and sometimes differences of emphasis between stakeholder groups. These differences did not necessarily lead to tension, as it was possible for differing perspectives to co-exist; the tensions became evident when perspectives conflicted rather than co-existed, as the group or individual who held the greatest power would invariably have its way in translating its perspective into policy and practic

Cyclosporine absorption profiles in pediatric kidney and liver transplant patients

Cyclosporine absorption profiling uses either the area under the concentration curve in the first 4 h post dose, AUC(0–4), or the concentration 2 h post dose (C2) to optimize immunosuppression in adult kidney and liver transplantation. We characterized C2 versus AUC(0–4) relationships over time after transplant and across transplant indications in 56 pediatric transplant patients. There were 36 kidney transplant patients aged 9.7±3.9 years. Nineteen of these patients were studied in the de novo period on day 7 post transplant and 17 in the maintenance phase more than 1 year post transplant. In addition, 20 liver transplant patients aged 8.9±4.2 years were studied in the maintenance phase. All patients had five blood samples collected over the 12-h dose interval that were analyzed by validated assay methods at a central laboratory. Pediatric C2 values were 1,463±658 ng/ml for de novo kidney, 954±322 ng/ml for maintenance kidney, and 619±339 ng/ml for maintenance liver transplant patients. C2 was a strong predictor of AUC(0–4) in all three pediatric groups, with coefficients of determination ( r 2 ) ranging from 0.861 to 0.936. Although data were limited from the de novo period, the C2 versus AUC(0–4) regression was consistent over time after transplant and between transplant indications, with a regression slope of 2.50 in de novo kidney, 2.54 in maintenance kidney, and 2.76 in maintenance liver transplant recipients. These slopes were also comparable to that in adult maintenance kidney transplant patients (2.60). In conclusion, C2 versus AUC(0–4) relationships demonstrated consistency over time (de novo vs. maintenance phase), between transplant indications (kidney vs. liver), and across age groups (pediatric vs. adult patients). Average C2 values achieved with current pediatric cyclosporine dosing practices cluster around the target C2 ranges recommended for adults.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/47821/1/467_2003_Article_1260.pd