A multifunctional cotton fabric using TiO2 and PCMs: introducing thermal comfort and self-cleaning properties

The development of materials with multiple functionalities is a market imperative that places new challenges on textile processing. Whatever the application, the goal is always to achieve the best performance with the simplest and most economically attractive process, without forgetting the sustainability issues. The purpose of this study is to establish the conditions to obtain by a simple method a cotton material with comfort, self-cleaning properties and antimicrobial activity. For that, microcapsules of phase change materials (PCMs) and TiO2 nanoparticles (NP) were applied conjugated and resulting fabrics were characterized by infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), contact angle and scanning electron microscopy with X-ray microanalysis (SEM/EDS). The self-cleaning properties of treated fabrics were also analyzed based on the photocatalytic ability of coated fabrics capability to decomposition of methyl orange (MO) under solar simulator irradiation [1] [1]and assessment of degradation of coffee, red wine and curry stains [2]. The comfort properties were assessed according DSC and Alambeta analysis. Moreover, incorporating TiO2 NP in the finishing formulation also was assessment the bacterial inhibition on the treated fabrics.CNPq-Brazil (Conselho Nacional de Desenvolvimento Científico e Tecnológico – Brasil / National Council of Scientific and Technological Development – Brazil) for the doctoral scholarship (233550/2014-3). Programme - COMPETE and by national funds through FCT – Foundation for Science and Technology within the scope of the project POCI-01-0145-FEDER-007136 and Strategic Funding UID/Multi/04423/2013 by FCT and European Regional Development Fund (ERDF), in the framework of the programme PT2020.info:eu-repo/semantics/publishedVersio

Incorporation of lipid nanosystems containing omega‑3 fatty acids and resveratrol in textile substrates for wound healing and anti‑inflammatory applications

In the present work, lipid nanosystems containing omega-3 fatty acid (nanostructured lipid carriers, NLCs) or omega-3 fatty acid and resveratrol (liposomes) were developed to improve cotton textile substrates as dressings with anti-inflammatory properties for wound healing applications. Lipid nanosystems were incorporated into woven, non-woven and knitted cotton substrates by exhaustion and impregnation. Based on physical–chemical characterization of the textile substrates, the textile structure and type of lipid nanosystems dictated the adsorption efficiency. In the case of NLCs, the woven substrate functionalized by exhaustion had a higher omega-3 release being the most promising for wound dressing application. Whereas for liposomes, the most adequate textile was the cationized knitted fabric functionalized by impregnation, that showed a more prolonged release profile of resveratrol.This work is financed by Project UID/CTM/00264/2019 of 2C2T - Centro de Ciencia e Tecnologia Textil, funded by National Founds through FCT/MCTES. The authors also acknowledge the Portuguese Foundation for Science and Technology (FCT) for financial support in the framework of the Strategic Funding UID/Multi/04546/2013 and UID/FIS/04650/2019 in the ambit of the project POCI-01-0145-FEDER-032651, co-financed by the European Regional Development Fund (ERDF), through COMPETE 2020, under Portugal 2020

Manufacture Techniques of Chitosan-Based Microcapsules to Enhance Functional Properties of Textiles

In recent years, the textile industry has been moving to novel concepts of products, which could deliver to the user, improved performances. Such smart textiles have been proven to have the potential to integrate within a commodity garment advanced feature and functional properties of different kinds. Among those functionalities, considerable interest has been played in functionalizing commodity garments in order to make them positively interact with the human body and therefore being beneficial to the user health. This kind of functionalization generally exploits biopolymers, a class of materials that possess peculiar properties such as biocompatibility and biodegradability that make them suitable for bio-functional textile production. In the context of biopolymer chitosan has been proved to be an excellent potential candidate for this kind of application given its abundant availability and its chemical properties that it positively interacts with biological tissue. Notwithstanding the high potential of chitosan-based technologies in the textile sectors, several issues limit the large-scale production of such innovative garments. In facts the morphologies of chitosan structures should be optimized in order to make them better exploit the biological activity; moreover a suitable process for the application of chitosan structures to the textile must be designed. The application process should indeed not only allow an effective and durable fixation of chitosan to textile but also comply with environmental rules concerning pollution emission and utilization of harmful substances. This chapter reviews the use of microencapsulation technique as an approach to effectively apply chitosan to the textile material while overcoming the significant limitations of finishing processes. The assembly of chitosan macromolecules into microcapsules was proved to boost the biological properties of the polymer thanks to a considerable increase in the surface area available for interactions with the living tissues. Moreover, the incorporation of different active substances into chitosan shells allows the design of multifunctional materials that effectively combine core and shell properties. Based on the kind of substances to be incorporated, several encapsulation processes have been developed. The literature evidences how the proper choices concerning encapsulation technology, chemical formulations, and process parameter allow tuning the properties and the performances of the obtained microcapsules. Furthermore, the microcapsules based finishing process have been reviewed evidencing how the microcapsules morphology can positively interact with textile substrate allowing an improvement in the durability of the treatment. The application of the chitosan shelled microcapsules was proved to be capable of imparting different functionalities to textile substrates opening possibilities for a new generation of garments with improved performances and with the potential of protecting the user from multiple harms. Lastly, a continuous interest was observed in improving the process and formulation design in order to avoid the usage of toxic substances, therefore, complying with an environmentally friendly approach

Indagini chimiche su resti antropici dalla Necropoli di casinalbo (Modena): aspetti paleonutrizionali

Sono stati analizzati ossa incinerate dalla necropoli di Casinalbo. I microelementi presenti mostrano correlazioni con il sesso e la paleobotanica del territori

Indagini chimiche su resti antropici dalla necropoli di Casinalbo (Modena)

Il contributo presenta una serie di analisi chimiche effettuate sui resti cremati di alcune sepolture della necropoli di Casinalbo (Bronzo medio e recente). Sono evidenziate e discusse alcune differenze nella dieta di femmine e maschi adulti

Black Quartz from the Burano Formation (Val Secchia, Italy): An Unusual Gem

The Burano Formation in Val Secchia in the province of Reggio Emilia is rich in black or very dark quartz. The crystals are often pitted by scars, rarely shiny, often opaque, rarely translucent, and about 3 cm long. However, they have a beautiful color and are generally euhedral and bi-terminate with simple habitus and well developed faces-for these characteristics, they are very sought after by collectors. Micro-Raman analyses showed the quartz contains abundant inclusions of anhydrite and graphite. The inclusions of anhydrite are responsible for the chromatic inhomogeneity, while the black color is linked to the presence of disordered graphite inclusions. LA-ICP-MS analyses did not show a significant presence of chromophore elements. Black quartz formed in the original evaporite deposits of gypsum, which, due to diagenesis and the increase in temperature during deep tectonic burial conditions, lost water of crystallization and subsequently transformed into anhydrite. After the formation of quartz crystals, the Burano Formation was exhumated and rehydrated, resulting in gypsification at conditions close to the surface. The black quartzes of the Burano Formation represent an appreciable gemological material for the development of local craftsmanship, even if the difficulties in reaching the deposit limit their marketing

The Pb-rich sulfide veins in the Boccassuolo ophiolite: Implications for the geochemical evolution of hydrothermal activity across the ocean-continent transition in the Ligurian Tethys (Northern-Apennine, Italy)

Galena bearing sulfide veins have been discovered coexisting with Fe\u2013Cu\u2013Zn dominated veins in the hydrothermal stockwork of the Boccassuolo ophiolite (External Ligurides, Northern Apennine, Italy). The galena-rich veins cut across a volcanic pile composed of pillow lava flows, pillow breccia, and ophiolitic sandstone. Bulk-ore analyses indicate significant enrichment in Pb giving raise to mantle normalized Pb\u2013Ag\u2013Au\u2013Zn\u2013Cu patterns with unusual negative slope, in contrast with the average flat pattern of most sulfide deposits in the Internal Liguride ophiolites which reflect the Fe\u2013Cu\u2013Zn assemblage of ophiolite-hosted Volcanic-associated Massive Sulfide (VMS) deposits all over the world. A wide literature shows that, in contrast with the Internal Ligurides, plutonic and volcanic rocks of the External Ligurides display less depleted and even enriched geochemical characters, not consistent with common oceanic crust at mid oceanic ridges (MOR), but probably originated in the ocean\u2013continent transition of the Adria continental margin. In this geodynamic context, pillow basalts become locally enriched in Pb with high Pb/Cu ratios, and other crustal-compatible elements such as Mo and U. The Pb enrichment observed in the veins Boccassuolo is interpreted to be a result of leaching of such anomalous volcanics forming the ophiolitic substrate. The case of Boccassuolo supports the conclusion that the geochemical character of hydrothermal activity evolved from Cu\u2013Zn rich in MOR-type assemblages of the Internal Ligurides, towards composition enriched in Pb in the External Liguride domain, representing the transition from the Ligurian ocean to the Adria continental margin

Experiencing Visible and Invisible Metal Casting Techniques in Bronze Age Italy

What we know about Bronze Age metalworking in Italy basically relies on finished artefacts and on stone, clay or bronze implements involved in the process of manufacturing (tuyères, crucibles, moulds, hammers, chisels, et cetera; Bianchi, 2010; Bianchi, in press). Moreover, evidences of structures for casting are extremely poor, at least in Italy, likely because of a lack of extensive excavations and, in absence of metalworking residuals, the difficulty to clearly distinguish them from other kinds of firing structures (Cavazzuti et al. in press). The reconstruction of the whole technology of production therefore requires a strong effort of making and testing hypotheses, referring not only to autoptic observations on archaeological finds, but also to archaeometrical analysis and study of landscape, in order to identify possible sources of raw materials. In this work our aim is to deepen some aspects concerning archaeologically ‘visible’ (stone mould production and casting), and ‘invisible’ techniques (sword production) of metalworking in Bronze Age Italy, focussing on Terramare context