36 research outputs found

    Structure of the elusive hydrido(methylcyclopentadienyl)dicarbonylmanganate(I) anion, [(η<sup>5</sup>-C<sub>5</sub>H<sub>4</sub>Me)Mn(CO)<sub>2</sub>H]-, as determined by single-crystal X-ray diffraction

    No full text
    The structure of [K(18-crown-6)][(η5-C5H4Me)Mn(CO)2H] has been determined by single-crystal X-ray diffraction, and the anion is found to adopt a three-legged piano-stool geometry. Its structure is compared with those of related bridging hydride and σ-bond complexes
    corecore