Estudio cinético de la deshidratación térmica del fosfoyeso

Phsophogypsum is a by-product from the processing phosphate rock. Before the use of it in cement industry such as setting regulator is necessary a study of dehydration reaction of phosphogypsum to avoid the false setting during the milling. The aim is to study the thermal behavior of two different phosphogypsum sources (Spain and Tunisia) under non-isothermal conditions in argon atmosphere by using Thermo-Gravimetriy, Differential Thermal Analysis (TG-DTA) and Differential Scanning Calorimetry (DSC). DSC experiments were carried out at temperatures ranging from ambient to 350 °C at different heating rates. The temperatures of conversion from gypsum to hemihydrate and anhydrite states and heat of dehydration were determined. Various methods were used to analyze the DSC data for reaction kinetics determination. The activation energy and frequency factor were calculated for dehydration of phosphogypsum. Activation energy values of the main dehydration reaction of phosphogypsum were calculated to be approximately 61–118 kJ/mol.El fosfoyeso es un subproducto procedente del procesado de la roca fosfato. Una de las posibles vías de reutilización y revalorización es su uso como regulador del fraguado en la industria cementera. Debido a los posibles problemas de falso fraguado asociado a los procesos de deshidratación que tienen lugar durante la molienda del cemento, esta investigación estudió el comportamiento térmico, bajo condiciones no-isotérmicas en atmósfera de argón, de dos fosfoyesos, mediante TG-DTA y DSC. Los ensayos de DSC se realizaron hasta los 350 °C a diferentes velocidades de calentamiento. La temperatura de conversión del yeso a las formas de hemihidrato y anhidrita y el calor de hidratación fueron determinados. Las cinéticas de reacción fueron obtenidas analizando los datos de DSC mediante varios métodos. Se calculó la energía de activación y el factor de frecuencia para las reacciones de deshidratación del subproducto. Los valores de energía de activación de las principales reacciones de deshidratación del fosfoyeso fueron obtenidos, aproximadamente 61-118 kJ/mol

Proof-of-principle of parametric stellarator neutronics modeling using Serpent2

This contribution presents neutron transport studies for the 5-period helical-axis advanced stellarator stellarator using the Serpent2 code. These studies utilize a parametric geometry model, enabling scans in neutronics modeling by varying the thickness of the reactor layers. For example, the tritium breeding ratio (TBR) can be determined by exploring various blanket material options and thicknesses to identify the threshold configuration that meets the TBR design criterion of 1.15. We found out that with the helium-cooled pebble ped candidate option, the TBR criterion is met with a breeding zone thickness of 26 cm, while with the dual-coolant lithium lead the threshold is exceeded at a thickness of 46 cm. Furthermore, the geometry includes non-planar field coils, allowing to study the fast neutron flux in these superconducting coils with a technological limit of 1 × 10 9 1 / cm 2 s . It is shown that the neutron fast flux is not constant at the coils, necessitating a neutron transport simulation to determine the distribution of the fast-flux at the coils. We show that the peak fast flux can be more than a factor of 2 higher than the average flux, and that the peak flux location rotates helically.</p