118 research outputs found
The Butterfly Dimer [(tBu3SiO)Cr]2(m-OSitBu3)2 and Its Oxidative Cleavage to (tBu3SiO)2Cr(dN-NdCPh2)2 and (tBu3SiO)2CrdN(2, 6-Ph2-C6H3)
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Molybdenum and Tungsten Structural Differences are Dependent on ndz2/(n + 1)Ñ• Mixing: Comparisons of (silox)3MX/R (M = Mo, W; silox = tBu3SiO)
Get PDFArticle discussing molybdenum and tungsten structural differences being dependent on ndz2/(n + 1)s mixing and a comparison of (silox)3MX/R (M = Mo, W; silox - tBu3SiO)
Cyclopentadienyl Substituent Effects on Reductive Elimination Reactions in Group 4 Metallocenes:Â Kinetics, Mechanism, and Application to Dinitrogen Activation
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Interplay of Orbital Symmetry and Nonstatistical Dynamics in the Thermal Rearrangements of Bicyclo[n.1.0]polyenes
No full textAlkyl Substituent Effects on Reductive Elimination Reactions in Zirconocene Alkyl Hydride Complexes. Manipulation of the Alkyl Steric Environment Allows the Synthesis of a Zirconocene Dinitrogen Complex
No full textDihydrogen and Silane Addition to Base-Free, Monomeric Bis(cyclopentadienyl)titanium Oxides
No full textHexakis(acetonitrile-κN)ruthenium(II) bis(hexabromocarbadodecaborate) acetonitrile solvate
Get PDFThe title compound, [Ru(NCCH3)6](CH6B11Br6)2·CH3CN, consists of the 'naked' ruthenium(II) cation surrounded by six acetonitrile molecules, each coordinated via the nitrogen atoms in a linear or nearly-linear fashion in a typical octahedral over-all arrangement. The cation is balanced by the two hexa-bromocarborane cage anionic fragments [CB11H6Br6]. Weak C—H...Br and B—H...Br interactions link neighboring anions
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