Pyroelectric response of ferroelectric nanoparticles: size effect and electric energy harvesting

The size effect on pyroelectric response of ferroelectric nanowires and nanotubes is analyzed. The pyroelectric coefficient strongly increases with the wire radius decrease and diverges at critical radius Rcr corresponding to the size-driven transition into paraelectric phase. Size-driven enhancement of pyroelectric coupling leads to the giant pyroelectric current and voltage generation by the polarized ferroelectric nanoparticles in response to the temperature fluctuation. The maximum efficiency of the pyroelectric energy harvesting and bolometric detection is derived, and is shown to approach the Carnot limit for low temperatures.Comment: 17 pages, 4 figures, 1 Appendi

Electromechanical Probing of Ionic Currents in Energy Storage Materials

The electrochemical processes in energy storage materials are generally linked with changes of molar volume of the host compound. Here, the frequency dependent strain response of 1D electrochemically active systems to periodic electric bias is analyzed. The sensitivity and resolution of these electrochemical strain measurements are compared to the current-based electrochemical impedance spectroscopy. The resolution and detection limits of interferometric and atomic force microscopy based systems for probing electrochemical reactions on the nanoscale are analyzed.Comment: 12 pages, 4 figures, 2 tables, 2 appendices, submitted to Appl. Phys. Let

Effect of the Intrinsic Width on the Piezoelectric Force Microscopy of a Single Ferroelectric Domain Wall

Intrinsic domain wall width is a fundamental parameter that reflects bulk ferroelectric properties and governs the performance of ferroelectric memory devices. We present closed-form analytical expressions for vertical and lateral piezoelectric force microscopy (PFM) profiles for the conical and disc models of the tip, beyond point charge and sphere approximations. The analysis takes into account the finite intrinsic width of the domain wall, and dielectric anisotropy of the material. These analytical expressions provide insight into the mechanisms of PFM image formation and can be used for quantitative analysis of the PFM domain wall profiles. PFM profile of a realistic domain wall is shown to be the convolution of its intrinsic profile and resolution function of PFM.Comment: 25 pages, 5 figures, 3 tables, 3 Appendices, To be submitted to J. Appl. Phy

DEVELOPMENT OF FORMS OF STRUCTURAL MATHEMATICAL MODELING IN DYNAMICS OF MECHANICAL OSCILLATION SYSTEMS: IMPEDANCE AND POSSIBLE VARIANTS OF APPROACH

Offering method of transformation of mathematical models of oscillation systems based on using of structural schemes. Structural analogs of mathematical models used for creature of variants of transfer functions of initial mechanical systems. Technology of transformation of structural schemes with object which has properties of integrated link of second order. Is shown that impedance is local characteristic of frequence dynamical properties of mechanical oscillation systems, in particular, vibration protection systems. Characteristics-analogs of impedance are given. They constructed on base using of movements and accelerations of allocated points. Conditions of ties of relative frequence characteristics are given. Conditions of compatibility of structural models of mechanical chains theory and automation control theory are identified