27 research outputs found

    CALCULS DES PROPRÉTÉS THERMODYNAMIQUES ET DE TRANSPORT DES PLASMAS Ar-N2 ET Ar-NH3 À LA PRESSION ATMOSPHÉRIQUE

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    Les propriétés thermodynamiques et de transport de mélanges Al-N2 et Al-NH3 pour la synthèse de nitrure d'aluminium par arc transféré plasma sont calculées. Dans le cas de vapeur d'aluminium métallique en présence de plasma d'azote ou d'ammoniac, une approche thermodynamique donne les conditions de composition initiale et de température qui conduisent à de bonnes conditions expérimentales pour la réaction en phase gazeuse. Les calculs des compositions des mélanges et des propriétés de transport (conductivité thermique, viscosité, coefficient de diffusion des différentes espèces...) permettent de prévoir le comportement des arcs transférés et le taux d'aluminium vaporisé.In this paper are calculated the thermodynamic and transport properties of Al-N2 and Al-NH3 mixtures to synthetize aluminium nitride under transferred arc plasma conditions. In the case of metallic aluminium vaporized in nitrogen or ammonia plasmas, a thermodynamic approach gives the conditions of composition, temperature and pressure which allow good operating conditions for reactions in the gaseous phase. The calculation of the mixtures composition and of the transport properties (thermal conductivity, viscosity, diffusion coefficient of the differents species...) allows to predict the behaviour of the transferred arcs and the rate of aluminium vaporisation

    Transport coefficients in thermal plasma : application to Mars and Titan atmospheres

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    this work is a contribution to the calculation of the transport coefficients for Nitrogen, hydrogen, mars and titan atmosphere plasma.ESA Technical Research Programme – TRP “Validation of Aerothermochemistry Models for Re-Entry Applications

    Kraft Pulp–Starch Covalent Linking: A Promising Route to a New Material

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    International audienceWe reported herein, the synthesis process of a direct cross-linking of modified polysaccharides. azidated starch, and alkyne Kraft pulp were cross-linked in the presence of Cu(I) catalyst, a type of Huisgen’s 1,3-dipolar azide–alkyne cycloaddition reaction, leading to the formation of starch cross-linked to kraft pulp fiber. The modified polysaccharides were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD) and scanning electron microscopy (SEM), and their physical properties were tested. The results show that the obtained novel material’s properties present an important enhancement compared to Kraft pulp fiber, about 71% and 44% for tear and break indexes respectively, up to 173% for elongation and of 136% for burst index
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