80 research outputs found
Greenhouse gases from membrane bioreactors: Mathematical modelling, sensitivity and uncertainty analysis
In this study a new mathematical model to quantify greenhouse gas emissions (namely, carbon dioxide and nitrous oxide) from membrane bioreactors (MBRs) is presented. The model has been adopted to predict the key processes of a pilot plant with pre-denitrification MBR scheme, filled with domestic and saline wastewater. The model was calibrated by adopting an advanced protocol based on an extensive dataset. In terms of nitrous oxide, the results show that an important role is played by the half saturation coefficients related to nitrogen removal processes and the model factors affecting the oxygen transfer rate in the aerobic and MBR tanks. Uncertainty analysis showed that for the gaseous model outputs 88\ue2\u80\u9393% of the measured data lays inside the confidence bands showing an accurate model prediction
Modelling organic material in activated sludge systems
A simple predictive model for the activated sludge reactor inorganic suspended solids (ISS) concentration is presented. It is based on the accumulation of influent ISS in the reactor and an ordinary heterotrophic organism (OHO) ISS content (fiOHO) of 0.15 mg ISS/mgOHOVSS and a variable phosphate accumulating organism (PAO) ISS content (fiPAO) proportional to their P content (fXBGP). The model is validated with data from 21 investigations conducted over the past 15 years on 30 aerobic and anoxic-aerobic nitrification denitrification (ND) systems and 18 anaerobic-anoxic-aerobic ND biological excess P removal (BEPR) systems variously fed artificial and real wastewater and operated from 3 to 20 d sludge age. The predicted reactor VSS/TSS ratio reflects the observed relative sensitivity to sludge age, which is low, and to BEPR, which is high. For effective use of the model for design, two significant issues require attention: measurement of the influent ISS concentration, which is not commonly done in wastewater characterisation analyses; and estimating a priori the P content of PAOs (fXBGP), which can vary considerably depending on the extent of anoxic P uptake BEPR that takes place in the system. Some guidance on selection of the mixed liquor VSS/TSS ratio for design is given
Biodegradability of wastewater and activated sludge organics in anaerobic digestion
The investigation provides experimental evidence that the unbiodegradable particulate organics fractions of primary sludge and waste activated sludge calculated from activated sludge models remain essentially unbiodegradable in anaerobic digestion. This was tested by feeding the waste activated sludge (WAS) from three different laboratory activated sludge (AS) systems to three separate anaerobic digesters (AD). Two of the AS systems were Modified Ludzack – Ettinger (MLE) nitrification-denitrification (ND) systems and the third was a membrane University of Cape Town (UCT) ND and enhanced biological P removal system. One of the MLE systems and the UCT system were fed the same real settled wastewater. The other MLE system was fed raw wastewater which was made by adding a measured constant flux (gCOD/d) of macerated primary sludge (PS) to the real settled wastewater. This PS was also fed to a fourth AD and a blend of PS and WAS from settled wastewater MLE system was fed to a fifth AD. The five ADs were each operated at five different sludge ages (10–60d). From the measured performance results of the AS systems, the unbiodegradable particulate organic (UPO) COD fractions of the raw and settled wastewaters, the PS and the WAS from the three AS systems were calculated with AS models. These AS model based UPO fractions of the PS and WAS were compared with the UPO fractions calculated from the performance results of the ADs fed these sludges. For the PS, the UPO fraction calculated from the AS and AD models matched closely, i.e. 0.30 and 0.31. Provided the UPO of heterotrophic (OHO, fE_OHO) and phosphorus accumulating (PAO, fE_PAO) biomass were accepted to be those associated with the death regeneration model of organism "decay", the UPO of the WAS calculated from the AS and AD models also matched well - if the steady state AS model fE_OHO = 0.20 and fE_PAO = 0.25 values were used, then the UPO fraction of the WAS calculated from the AS models deviated significantly from those calculated with the AD models. Therefore in plant wide wastewater treatment models the characterization of PS and WAS as defined by the AS models can be applied without modification in AD models. The observed rate limiting hydrolysis/acidogenesis rates of the sludges are listed
UCT-MBR vs IFAS-UCT-MBR for Wastewater Treatment: A Comprehensive Comparison Including N2O Emission
In this study the performance (in terms of carbon and nutrient removal) and N2O emission of two plant configurations adopting innovative technologies were investigated. With this regards, an University Cape Town (UCT) membrane bioreactor (MBR) plant and an Integrated Fixed Film Activated Sludge (IFAS) -UCT-MBR plant were monitored. Both plants treat real wastewater under two different values of the influent carbon nitrogen ratio (C/N = 5 mgCOD/mgN and C/N = 10 mgCOD/mgN). Results have shown the
highest carbon and nutrients removal efficiencies for the IFAS-UCT-MBR configuration during both the two investigated C/N values. Furthermore, the lowest N2O emission occurred for the IFAS-UCT-MBR
Greenhouse Gas Emissions from Membrane Bioreactors
Nowadays, it is widely accepted that wastewater treatment plants (WWTPs) are significant sources of greenhouse gas (GHG) emission, contributing to the anthropogenic sources. Among the GHG emitted from WWTPs, nitrous oxide (N2O) has been identified of having the major interest/concern, since its high global warming potential (GWP), is 298 times higher than that of CO2 and also to its capability to react with stratospheric ozone causing the layer depletion. Up to now, most of the experimental investigations have been carried out on conventional activated sludge (CAS) processes. The knowledge of N2O emission from advanced technologies such membrane bioreactors (MBRs) is still very limited. The present paper is aimed at providing a picture of the GHG emissions from MBR systems. In particular, data of N2O acquired from pilot plant systems monitoring are here presented. The key aim of the study was to highlight the effect of wastewater features and operational conditions on N2O production/emission from MBRs
A moving bed membrane bioreactor pilot plant for carbon and nutrient removal
The paper reports the main results of an experimental gathering campaign carried out on a moving bed membrane bioreactor pilot plant conceived for carbon and nutrients removal according to a University of Cape Town scheme. Organic carbon, nitrogen and phosphorus removal, biokinetic/stoichiometric constants, membrane fouling tendency and sludge dewaterability have been assessed during experiments. The achieved results showed that pilot plant was able to guarantee very high carbon removal, with average efficiency of 98%. In terms of nitrification, the system showed an excellent performance, with efficiencies higher than 98% for most of the experiments. This result might be related to the presence of biofilm in the aerobic compartment that contributed to sustain the complete nitrification of the influent ammonium. Conversely, the average P removal efficiency was quite moderate, likely due to the increase of the ammonium loading rate that could promote an increased NO3-N recycled from the anoxic to the anaerobic tank, interfering with PAOs activity inside the anaerobic tank. Referring to membrane fouling, the irreversible resistance due to superficial cake deposition was the mechanism that mostly affected the membrane filtration properties. Moreover, it was noticed the increase of the resistance due to pore blocking and a general worsening of the membrane filtration properties. This result could be due to the increase of the EPSBound fraction that could be promoted by biofilm detachment phenomena occurred during experiments
Bacterial community structure and removal performances in IFAS-MBRs: A pilot plant case study
The paper reports the results of an experimental campaign carried out on a University of Cape Town (UCT) integrated fixed-film activated sludge (IFAS) membrane bioreactor (MBR) pilot plant. The pilot plant was analysed in terms of chemical oxygen demand (COD) and nutrients removal, kinetic/stoichiometric parameters, membrane fouling and sludge dewaterability. Moreover, the cultivable bacterial community structure was also analysed. The pilot plant showed excellent COD removal efficiency throughout experiments, with average value higher than 98%, despite the slight variations of the influent wastewater. The achieved nitrification efficiency was close to 98% for most of the experiments, suggesting that the biofilm in the aerobic compartment might have sustained the complete nitrification of the influent ammonia, even for concentrations higher than 100\ua0mg\ua0L-1. The irreversible resistance due to superficial cake deposition was the mechanism that mostly affected the membrane fouling. Moreover, it was noticed an increase of the resistance due pore blocking likely due to the increase of the EPSBound fraction that could derive by biofilm detachment. The bacterial strains isolated from aerobic tank are wastewater bacteria known for exhibiting efficient heterotrophic nitrification\ue2\u80\u93aerobic denitrification and producing biofilm
Sulphate measurement in organic-rich solutions: Carbonate fusion pretreatment to remove organic interferences
Sulphate measurement using a barium sulphate turbidimetric method in solutions with high concentrations of organic material is shown to be problematic. The organics give background colour, which introduces a positive error to the measured absorption, and inhibit the barium sulphate precipitate, which results in a negative error. A carbonate fusion pretreatment of the sample results in the removal of the organic matter and associated interferences. With this pretreatment, excellent sulphate recoveries were obtained (100%). Rigorous testing of the method shows that reproducible and accurate results are obtainable
Proposta de um método racional para o dimensionamento de reatores de tratamento de esgotos por lodos ativados em bateladas para remoção de carga orgânica
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