41 research outputs found
Shorter Exciton Lifetimes via an External Heavy-Atom Effect: Alleviating the Effects of Bimolecular Processes in Organic Light-Emitting Diodes
Multiexcitedâstate phenomena are believed to be the root cause of two exigent challenges in organic lightâemitting diodes; namely, efficiency rollâoff and degradation. The development of novel strategies to reduce exciton densities under heavy load is therefore highly desirable. Here, it is shown that triplet exciton lifetimes of thermally activated delayedâfluorescenceâemitter molecules can be manipulated in the solid state by exploiting intermolecular interactions. The external heavyâatom effect of brominated host molecules leads to increased spinâorbit coupling, which in turn enhances intersystem crossing rates in the guest molecule. Wave function overlap between the host and the guest is confirmed by combined molecular dynamics and density functional theory calculations. Shorter triplet exciton lifetimes are observed, while high photoluminescence quantum yields and essentially unaltered emission spectra are maintained. A change in the intersystem crossing rate ratio due to increased dielectric constants leads to almost 50% lower triplet exciton densities in the emissive layer in the steady state and results in an improved onset of the photoluminescence quantum yield rollâoff at high excitation densities. Efficient organic lightâemitting diodes with better rollâoff behavior based on these novel hosts are fabricated, demonstrating the suitability of this concept for realâworld applications.United States. Department of Energy (Grant DEâFG02â07ER46474
PRM109 Visualizing Methods For Discrete-Event-Simulations Using The Example Of A Breast Cancer Decision-Analytic Model
Correlation between electrical properties and crystalline phases for ZnO-Bi2O3 based varistor ceramics with rare earth additives
PIN78 ECONOMIC IMPACT OF INFLUENZA EPIDEMICS: MODELLING INTERACTIONS OF INFECTIONS, TREATMENT PATHWAYS AND REIMBURSEMENT
Donor-Acceptor Iptycenes with Thermally Activated Delayed Fluorescence
A new donorâacceptor iptycene containing carbazole donors and a thiadiazoloquinoxaline acceptor was synthesized and its photoâ and electrochemical properties evaluated. The key intermediate 1 allows a lateral modification through crossâcoupling, and the (triisopropylsilyl)acetylene product 2 exhibits bright yellow fluorescence with emission lifetimes of 2.42 ”s in deoxygenated hexane. The long lifetime and high quantum efficiency (73â%) is quenched by Oâ and therefore attributed to thermally activated delayed fluorescence (TADF). This approach allows functionalization through crossâcoupling reactions and depicts a promising scaffold for the synthesis of TADFâactive molecules.Keywords: Functional organic materials; Fluorescence; Donorâacceptor systems; Iptycenes; Cross-couplin