Hydrophobic interactions with coarse-grained model for water

Integral equation theory is applied to a coarse-grained model of water to study potential of mean force between hydrophobic solutes. Theory is shown to be in good agreement with the available simulation data for methane-methane and fullerene-fullerene potential of mean force in water; the potential of mean force is also decomposed into its entropic and enthalpic contributions. Mode coupling theory is employed to compute self-diffusion coefficient of water, as well as diffusion coefficient of a dilute hydrophobic solute; good agreement with molecular dynamics simulation results is found

Scalar multi-wormholes

In 1921 Bach and Weyl derived the method of superposition to construct new axially symmetric vacuum solutions of General Relativity. In this paper we extend the Bach-Weyl approach to non-vacuum configurations with massless scalar fields. Considering a phantom scalar field with the negative kinetic energy, we construct a multi-wormhole solution describing an axially symmetric superposition of $N$ wormholes. The solution found is static, everywhere regular and has no event horizons. These features drastically tell the multi-wormhole configuration from other axially symmetric vacuum solutions which inevitably contain gravitationally inert singular structures, such as `struts' and `membranes', that keep the two bodies apart making a stable configuration. However, the multi-wormholes are static without any singular struts. Instead, the stationarity of the multi-wormhole configuration is provided by the phantom scalar field with the negative kinetic energy. Anther unusual property is that the multi-wormhole spacetime has a complicated topological structure. Namely, in the spacetime there exist $2^N$ asymptotically flat regions connected by throats.Comment: 11 pages, 13 figure

The eddy heat-flux in rotating turbulent convection

The three components of the heat-flux vector $F =\rho C_p are numerically computed for a stratified rotating turbulent convection using the NIRVANA code in a flat box. The latitudinal component$F_\theta$proves to be negative (positive) in the northern (southern) hemisphere so that the heat always flows towards the poles. As a surprise, the radial heat-flux$F_r$peaks at the equator rather than at the poles (Taylor numbers O(10^6)). The same behavior is observed for the radial turbulence intensity$ which for \emph{free} turbulence is also believed to peak at the poles (see Eq. (19) below). As we can show, however, the consequences of this unexpected result (also obtained by Kaepylae, Korpi and Tuominen 2004) for the theory of differential rotation are small as mainly the F_\theta$is responsible to solve the `Taylor number puzzle'. In all our simulations the azimuthal component$F_\phi$proves to be negative so that the rotating turbulence produces an westwards directed azimuthal heat-flux which should be observable. Fluctuations with higher temperature are expected to be anticorrelated with their own angular velocity fluctuations. We find this rotation-induced result as understandable as the$F_\phi$ is closely related to the radial \Lambda-effect which is known to be also negative in stratified and rapidly rotating convection zones.Comment: 8 pages, 9 figures, Astron. Astrophys. (subm.

Structural and Dynamical Anomalies of a Gaussian Core Fluid: a Mode Coupling Theory Study

We present a theoretical study of transport properties of a liquid comprised of particles uist1:/home/sokrates/egorov/oldhome/Pap41/Submit > m abs.tex We present a theoretical study of transport properties of a liquid comprised of particles interacting via Gaussian Core pair potential. Shear viscosity and self-diffusion coefficient are computed on the basis of the mode-coupling theory, with required structural input obtained from integral equation theory. Both self-diffusion coefficient and viscosity display anomalous density dependence, with diffusivity increasing and viscosity decreasing with density within a particular density range along several isotherms below a certain temperature. Our theoretical results for both transport coefficients are in good agreement with the simulation data