CCS from industrial sources

The literature concerning the application of CCS to industry is reviewed. Costs are presented for different sectors including ``high purity'' (processes which inherently produce a high concentration of CO2), cement, iron and steel, refinery and biomass. The application of CCS to industry is a field which has had much less attention than its application to the electricity production sector. Costs range from less than $2011 10/tCO 2 up to above$ 2011 100/tCO 2 . In the words of a synthesis report from the United Nations Industrial Development Organisation (UNIDO) ``This area has so far not been the focus of discussions and therefore much attention needs to be paid to the application of CCS to industrial sources if the full potential of CCS is to be unlocked''

Mesoscale Compositionally Modulated Nanocrystalline Ni-Fe Electrodeposits for Nanopatterning Applications

A considerable range of surface nanostructures can be fabricated by the selective dissolution of elements or phases from metallic alloys. Selectively etched electrodeposited multilayers may find useful application in optoelectronic and MEMS devices. One issue with electrodeposited multilayers is that the fine-scale multilayer structure can often exhibit significant waviness if the band layer spacing is on the same order of magnitude as the grain size. In the present study, the mean grain size was reduced to below 10 nm in a compositionally modulated Ni-Fe alloy. Preferential etching on the electroform cross-section resulted in highly uniform and directional surface channels. The evolution of this nanopatterned surface morphology was characterized by atomic force microscopy and directional roughness parameters were obtained

Pleistocene landscape evolution in the Avon valley, southern Britain: optical dating of terrace formation and Palaeolithic archaeology

This paper presents the first comprehensive Optically Stimulated Luminescence dating programme from a sequence of Pleistocene river terraces in the Avon valley (Wiltshire-Hampshire-Dorset), southern Britain. These results offer the most complete chronometric framework for Pleistocene landscape evolution and Palaeolithic occupation in the Avon valley, allowing for the first time: (1) an assessment of the timing of terrace formation and landscape evolution, (2) the dating of hominin presence in the area, and (3) an investigation of the relationship between terrace formation and Quaternary climatic change. Analysis of 25 samples collected from terraces 10 and 7 to 4 show that the middle Avon terraces formed in response to the main Pleistocene climatic oscillations (Marine Isotope Stage (MIS) 10, 8, 6) and that fluvial mechanisms changed through time, resulting in three different types of terrace architecture. The highest and oldest deposits are compound terraces deposited during the Early Pleistocene before the Mid Pleistocene Transition. The middle reach of the valley is characterised by well-developed strath terraces overlain with thick fluvial deposits, reflecting the greater degree of incision in response to the increased amplitude of climate cycles in the Middle Pleistocene. The youngest deposits in the confined modern floodplain represent cut-and-fill terraces deposited after MIS5e. The results indicate that the two main Palaeolithic sites in the area, Milford Hill and Woodgreen, date to between at least MIS 10 and 8 with a pre-MIS 10 human occupation at a third main site at Bemerton. This is significant because the sites date to a period previously associated with a decline in hominin presence in Britain. The dating of the Avon valley terrace sequence highlights the complex nature of terrace formation during the Pleistocene and the need to critically reassess the chronological understanding of these fluvial archives in southern Britain. This research demonstrates that with a detailed and multidisciplinary approach shifts in hominin landscape use can be discovered, providing new information on hominin behavioural change during the Pleistocene

Ю.О. Митропольський — вчений та вихователь молоді

Висвітлено наукову діяльність та роботу з підготовки наукових кадрів академіка Ю.О. Митропольського. Змальовано його риси як вченого та вихователя молоді.Освещены научная деятельность и работа по подготовке научных кадров академика Ю.А.Митропольского. Обрисованы его черты как ученого и воспитателя молодежи.The paper highlights research and tutorial activities by Academician Yu.O. Mitropolsky. His qualities as a scientist and a tutor of youth are outlined

Molecular dynamics simulations of a fully hydrated dipalmitoyl phosphatidylcholine bilayer with different macroscopic boundary conditions and parameters

We compared molecular dynamics simulations of a bilayer of 128 fully hydrated phospholipid (DPPC) molecules, using different parameters and macroscopic boundary conditions. The same system was studied under constant pressure, constant volume, and constant surface tension boundary conditions, with two different sets of charges, the single point charge (SPC) and extended single point charge (SPC/E) water model and two different sets of Lennard-Jones parameters for the interaction between water and methyl/methylene. Some selected properties of the resulting bilayer systems are compared to each other, previous simulations, and experimental data. It is concluded that in relatively high water concentration it is possible to use ab initio derived charges with constant pressure boundary conditions. The SPC water model gives a larger area per head group and a broader interface than the SPC/E model. Increasing the repulsion between water oxygens and CH2/CH3 groups has a large effect on the width of the interface and the area per head group. There is little difference between simulations with constant pressure and constant surface tension. The use of constant volume, using a reasonable estimate for the initial box dimensions, easily introduces artefacts. (C) 1996 American Institute of Physics

Angle-Resolved Environmental X-Ray Photoelectron Spectroscopy: A New Laboratory Setup for Photoemission Studies at Pressures up to 0.4 Torr

The paper presents the development and demonstrates the capabilities of a new laboratory-based environmental X-ray photoelectron spectroscopy system incorporating an electrostatic lens and able to acquire spectra up to 0.4 Torr. The incorporation of a two-dimensional detector provides imaging capabilities and allows the acquisition of angle-resolved data in parallel mode over an angular range of 14° without tilting the sample. The sensitivity and energy resolution of the spectrometer have been investigated by analyzing a standard Ag foil both under high vacuum (10−8 Torr) conditions and at elevated pressures of N2 (0.4 Torr). The possibility of acquiring angle-resolved data at different pressures has been demonstrated by analyzing a silicon/silicon dioxide (Si/SiO2) sample. The collected angle-resolved spectra could be effectively used for the determination of the thickness of the native silicon oxide layer

The Imperfective Past

The objective of our study was to investigate whether use of antipsychotics is associated with hip/femur fractures and whether pharmacological differences between antipsychotics are related to the occurrence of fractures.A case-control study was conducted, in which cases were defined as patients with a hip/femur fracture. Each patient was matched to one control patient. The association between use of antipsychotics and the occurrence of hip/femur fractures was evaluated using conditional logistic regression.The study included 44,500 patients from 683 general practices from different geographical areas in the UK, registered within the General Practice Research Database (GPRD). Exposure to antipsychotics was categorized as “no use”, “current use” and “prior use”.Both current and prior use of antipsychotics were associated with an approximately two-fold increased risk of fractures. After adjustment for possible confounders, a small significant effect remained (Odds Ratios (OR) of 1.3). We did not find an association between dose of antipsychotics, or between the degree of blockade of the alpha-1 adrenoceptor or histamine-1 receptor and risk of fractures. The total number of days of antipsychotic use was significantly associated with an increased risk of hip/femur fractures.We conclude that there is a small increased risk of hip/femur fractures associated with the use of antipsychotics. This risk increases with long-term use

Reduction of fossil fuel use and adoption of alternative energy sources

Reduction of carbon dioxide emissions means a much more radical change in the energy supply structure than any possibly successful strategy to replace scarce petroleum could ever be. Moreover, the vulnerability of oil supplies leads to problem solutions, which even aggravate the carbon dioxide problem. Therefore, any improvements must heavily rely on forced energy saving and enhanced use of renewable and nuclear energy. Although the theoretical potential to substitute carbon - and hydrocarbon - fuels has the rather high value of about 2/3 of final energy demand, the technical and economical feasibility of alternative fuels must be judged much more pessimistically. Some recent results of an analysis sponsored by the lEA show, that nuclear and renewable energy supplies may only be able to sustain about 50% of the growth or primary energy demand of the lEA-countries. Thus, if we want to be sure of having enough energy to sustain our lifestyle, we must not expect reductions of carbon dioxide emissions. This can only be achieved by huge efforts in energy saving, connected with a full utilization of the nuclear and renewable resources