Automated online preconcentration system for the determination of trace amounts of lead using Pb-selective resin and inductively coupled plasma-atomic emission spectrometry

An automated sequential-injection online preconcentration system was developed for the determination of lead by inductively coupled plasma - atomic emission spectrometry (ICP-AES). The preconcentration of lead was performed with a minicolumn containing a lead-selective resin, Analig Pb-01, which was installed between a selection and a switching valve. In an acidic condition ( pH 1), lead could be adsorbed on the resin. The concentrated lead was afterward eluted with 25 mu L of 0.06 M nitrilotriacetic acid (NTA) solution ( pH 9) and was subsequently transported into the nebulizer of ICP-AES for quantification. The selectivity of the resin toward lead was examined using a solution containing a mixture of 61 elements. When a sample volume of 5 mL was used, the quantitative collection of lead ( &#62;= 97%) was achieved, along with an enrichment factor of 19, a sampling frequency of 12 samples hr(-1), a detection limit of 70 pg mL(-1), and a lowest quantification limit of 100 pg mL(-1). The linear dynamic range was 0.1 to 5 ng mL(-1), and the relative standard deviation (n = 9) was 0.5% at a 5 ng mL(-1) Pb level. The detection limit of 30 pg mL(-1) and lowest quantification limit of 50 pg mL(-1) could be achieved when 10 mL of sample volume was used. The accuracy of the proposed method was validated by determining lead in the standard reference material of river water (SLRS-4), and its applicability to the determination of lead in environmental river water samples was demonstrated.</p

Effect of hydrogen adsorption on the quasiparticle spectra of graphene

We use the non-interacting tight-binding model to study the effect of isolated hydrogen adsorbates on the quasiparticle spectra of single-layer graphene. Using the Green's function approach, we obtain analytic expressions for the local density of states and the spectral function of hydrogen-doped graphene, which are also numerically evaluated and plotted. Our results are relevant for the interpretation of scanning tunneling microscopy and angle-resolved photoemission spectroscopy data of functionalized graphene.Comment: 4 pages, 3 figures, minor corrections to tex

Streaming clumps ejection model and the heterogeneous inner coma of Comet Wild 2

It is modeled that a significant component of the jets of some comets are released as aggregate clumps, which then fragment and shed particles after release, leading to a heterogeneous innermost coma

Preliminary results from the dust flux monitoring instrument during the encounter of Stardust spacecraft with Wild-2 comet

On January 2, 2004, the Stardust spacecraft successfully encountered the Wild-2 comet. The Dust Flux Monitoring Instrument (DFMI) provided quantitative measurements of dust particle fluxes and particle mass distributions throughout the entire flythrough

AI EDAM special issue: advances in implemented shape grammars: solutions and applications

This paper introduces the special issue “Advances in Implemented Shape Grammars: Solutions and Applications” and frames the topic of computer implementations of shape grammars, both with a theoretical and an applied focus. This special issue focuses on the current state of the art regarding computer implementations of shape grammars and brings a discussion about how those systems can evolve in the coming years so that they can be used in real life design scenarios. This paper presents a brief state of the art of shape grammars implementation and an overview of the papers included in the current special issue categorized under technical design, interpreters and interface design, and uses cases. The paper ends with a comprehensive outlook into the future of shape grammars implementations.info:eu-repo/semantics/acceptedVersio

Giant fluctuations of topological charge in a disordered wave guide

We study the fluctuations of the total topological charge of a scalar wave propagating in a hollow conducting wave guide filled with scatterers inside. We investigate the dependence of the screening on the scattering mean free path and on the presence of boundaries. Near the cut-off frequencies of the wave guide, screening is strongly suppressed near the boundaries. The resulting huge fluctuations of the total topological charge are very sensitive to the disorder.Comment: 8 pages 5 figures, submitted to Waves in Random and Complex Medi

Buffering plasmons in nanoparticle waveguides at the virtual-localized transition

We study the plasmonic energy transfer from a locally excited nanoparticle (LE-NP) to a linear array of small NPs and we obtain the parametric dependence of the response function. An analytical expression allows us to distinguish the extended resonant states and the localized ones, as well as an elusive regime of virtual states. This last appears when the resonance width collapses and before it becomes a localized state. Contrary to common wisdom, the highest excitation transfer does not occur when the system has a well defined extended resonant state but just at the virtual-localized transition, where the main plasmonic modes have eigenfrequencies at the passband edge. The slow group velocity at this critical frequency enables the excitation buffering and hence favors a strong signal inside the chain. A similar situation should appear in many other physical systems. The extreme sensitivity of this transition to the waveguide and LE-NP parameters provides new tools for plasmonics.Comment: Regular article: 7 pages and 5 figure

Generic susceptibilities of the half-filled Hubbard model in infinite dimensions

Around a metal-to-insulator transition driven by repulsive interaction (Mott transition) the single particle excitations and the collective excitations are equally important. Here we present results for the generic susceptibilities at zero temperature in the half-filled Hubbard model in infinite dimensions. Profiting from the high resolution of dynamic density-matrix renormalization at all energies, results for the charge, spin and Cooper-pair susceptibilities in the metallic and the insulating phase are computed. In the insulating phase, an almost saturated local magnetic moment appears. In the metallic phase a pronounced low-energy peak is found in the spin response.Comment: 12 pages, 12 figures; slight changes and one additional figure due to referees' suggestion