49 research outputs found

    Dynamic nuclear polarization and spin-diffusion in non-conducting solids

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    There has been much renewed interest in dynamic nuclear polarization (DNP), particularly in the context of solid state biomolecular NMR and more recently dissolution DNP techniques for liquids. This paper reviews the role of spin diffusion in polarizing nuclear spins and discusses the role of the spin diffusion barrier, before going on to discuss some recent results.Comment: submitted to Applied Magnetic Resonance. The article should appear in a special issue that is being published in connection with the DNP Symposium help in Nottingham in August 200

    SAMPLING FOR RADIONUCLIDES AND OTHER TRACE SUBSTANCES.

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    Survey of statistical and sampling needs for environmental monitoring of commercial low-level radioactive waste disposal facilities

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    This project was designed to develop guidance for implementing 10 CFR Part 61 and to determine the overall needs for sampling and statistical work in characterizing, surveying, monitoring, and closing commercial low-level waste sites. When cost-effectiveness and statistical reliability are of prime importance, then double sampling, compositing, and stratification (with optimal allocation) are identified as key issues. If the principal concern is avoiding questionable statistical practice, then the applicability of kriging (for assessing spatial pattern), methods for routine monitoring, and use of standard textbook formulae in reporting monitoring results should be reevaluated. Other important issues identified include sampling for estimating model parameters and the use of data from left-censored (less than detectable limits) distributions
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