86 research outputs found

    SYNTHESIS OF THE MACROCYCLIC THIOCROWN ETHERS 1,4,7,10,13,16,19-HEPTATHIAHENEICOSANE (21-S-7) AND 1,4,7,10,13,16,19,22-OCTATHIATETRAEICOSANE (24-S-8)

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    The synthesis and characterization of the two macrocyclic sulfides, 1,4,7,10,13,16,19-heptathiaheneicosane (21-S-7) and 1,4,7,10,13,16,19,22-octathiatetraeicosane (24-S-8), are described starting from different combinations of dithiols and dichlorides of differing chain lengths. Cs2CO3 is used for the cyclizations.</p

    SYNTHESIS OF THE MACROCYCLIC THIOCROWN ETHERS 1,4,7,10,13,16,19-HEPTATHIAHENEICOSANE (21-S-7) AND 1,4,7,10,13,16,19,22-OCTATHIATETRAEICOSANE (24-S-8)

    No full text
    The synthesis and characterization of the two macrocyclic sulfides, 1,4,7,10,13,16,19-heptathiaheneicosane (21-S-7) and 1,4,7,10,13,16,19,22-octathiatetraeicosane (24-S-8), are described starting from different combinations of dithiols and dichlorides of differing chain lengths. Cs2CO3 is used for the cyclizations
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