2 research outputs found
Comment on "Theory and computer simulation for the equation of state of additive hard-disk fluid mixtures"
A flaw in the comparison between two different theoretical equations of state
for a binary mixture of additive hard disks and Monte Carlo results, as
recently reported in C. Barrio and J. R. Solana, Phys. Rev. E 63, 011201
(2001), is pointed out. It is found that both proposals, which require the
equation of state of the single component system as input, lead to comparable
accuracy but the one advocated by us [A. Santos, S. B. Yuste, and M. L\'{o}pez
de Haro, Mol. Phys. 96, 1 (1999)] is simpler and complies with the exact limit
in which the small disks are point particles.Comment: 4 pages, including 1 figur
Alternative Approaches to the Equilibrium Properties of Hard-Sphere Liquids
An overview of some analytical approaches to the computation of the structural and thermodynamic properties of single component and multicomponent hard-sphere fluids is provided. For the structural properties, they yield a thermodynamically consistent formulation, thus improving and extending the known analytical results of the Percus鈥揧evick theory. Approximate expressions for the contact values of the radial distribution functions and the corresponding analytical equations of state are also discussed. Extensions of this methodology to related systems, such as sticky hard spheres and squarewell fluids, as well as its use in connection with the perturbation theory of fluids are briefly addressed.