59 research outputs found
Derivation of the Curie-Weiss Law in Dynamical Mean-Field Theory
We present an analytic derivation of the linear temperature dependence of the
inverse static susceptibility near the
transition from a paramagnetic to a ferromagnetic correlated metal within the
dynamical mean-field theory (DMFT) for the Hubbard model. The equations for the
critical temperature and interaction strength of the transition are also
determined.Comment: 5 pages, no figure
Metallic ferromagnetism without exchange splitting
In the band theory of ferromagnetism there is a relative shift in the
position of majority and minority spin bands due to the self-consistent field
due to opposite spin electrons. In the simplest realization, the Stoner model,
the majority and minority spin bands are rigidly shifted with respect to each
other. Here we consider models at the opposite extreme, where there is no
overall shift of the energy bands. Instead, upon spin polarization one of the
bands broadens relative to the other. Ferromagnetism is driven by the resulting
gain in kinetic energy. A signature of this class of mechanisms is that a
transfer of spectral weight in optical absorption from high to low frequencies
occurs upon spin polarization. We show that such models arise from generalized
tight binding models that include off-diagonal matrix elements of the Coulomb
interaction. For certain parameter ranges it is also found that reentrant
ferromagnetism occurs. We examine properties of these models at zero and finite
temperatures, and discuss their possible relevance to real materials
Anisotropic Superparamagnetism of Monodispersive Cobalt-Platinum Nanocrystals
Based on the high-temperature organometallic route (Sun et al. Science 287,
1989 (2000)), we have synthesized powders containing CoPt_3 single crystals
with mean diameters of 3.3(2) nm and 6.0(2) nm and small log-normal widths
sigma=0.15(1). In the entire temperature range from 5 K to 400 K, the
zero-field cooled susceptibility chi(T) displays significant deviations from
ideal superparamagnetism. Approaching the Curie temperature of 450(10) K, the
deviations arise from the (mean-field) type reduction of the ferromagnetic
moments, while below the blocking temperature T_b, chi(T) is suppressed by the
presence of energy barriers, the distributions of which scale with the particle
volumes obtained from transmission electron microscopy (TEM). This indication
for volume anisotropy is supported by scaling analyses of the shape of the
magnetic absorption chi''(T,omega) which reveal distribution functions for the
barriers being also consistent with the volume distributions observed by TEM.
Above 200 K, the magnetization isotherms M(H,T) display Langevin behavior
providing 2.5(1) mu_B per CoPt_3 in agreement with reports on bulk and thin
film CoPt_3. The non-Langevin shape of the magnetization curves at lower
temperatures is for the first time interpreted as anisotropic
superparamagnetism by taking into account an anisotropy energy of the
nanoparticles E_A(T). Using the magnitude and temperature variation of E_A(T),
the mean energy barriers and 'unphysical' small switching times of the
particles obtained from the analyses of chi''(T,omega) are explained. Below T_b
hysteresis loops appear and are quantitatively described by a blocking model,
which also ignores particle interactions, but takes the size distributions from
TEM and the conventional field dependence of E_A into account.Comment: 12 pages with 10 figures and 1 table. Version accepted for
publication in Phys. Rev. B . Two-column layou
Quantum nucleation in ferromagnets with tetragonal and hexagonal symmetries
The phenomenon of quantum nucleation is studied in a ferromagnet in the
presence of a magnetic field at an arbitrary angle. We consider the
magnetocrystalline anisotropy with tetragonal symmetry and that with hexagonal
symmetry, respectively. By applying the instanton method in the
spin-coherent-state path-integral representation, we calculate the dependence
of the rate of quantum nucleation and the crossover temperature on the
orientation and strength of the field for a thin film and for a bulk solid. Our
results show that the rate of quantum nucleation and the crossover temperature
depend on the orientation of the external magnetic field distinctly, which
provides a possible experimental test for quantum nucleation in nanometer-scale
ferromagnets.Comment: 19 pages and 3 figures, Final version and accepted by Phys. Rev. B
(Feb. B1 2001
Gutzwiller-Correlated Wave Functions: Application to Ferromagnetic Nickel
Ferromagnetic Nickel is the most celebrated iron group metal with pronounced
discrepancies between the experimental electronic properties and predictions of
density functional theories. In this work, we show in detail that the recently
developed multi-band Gutzwiller theory provides a very good description of the
quasi-particle band structure of nickel. We obtain the correct exchange
splittings and we reproduce the experimental Fermi-surface topology. The
correct (111)-direction of the magnetic easy axis and the right order of
magnitude of the magnetic anisotropy are found. Our theory also reproduces the
experimentally observed change of the Fermi-surface topology when the magnetic
moment is oriented along the (001)-axis. In addition to the numerical study, we
give an analytical derivation for a much larger class of variational
wave-functions than in previous investigations. In particular, we cover cases
of superconductivity in multi-band lattice systems.Comment: 35 pages, 3 figure
Pressure-dependence of electron-phonon coupling and the superconducting phase in hcp Fe - a linear response study
A recent experiment by Shimizu et al. has provided evidence of a
superconducting phase in hcp Fe under pressure. To study the
pressure-dependence of this superconducting phase we have calculated the phonon
frequencies and the electron-phonon coupling in hcp Fe as a function of the
lattice parameter, using the linear response (LR) scheme and the full potential
linear muffin-tin orbital (FP-LMTO) method. Calculated phonon spectra and the
Eliashberg functions indicate that conventional s-wave
electron-phonon coupling can definitely account for the appearance of the
superconducting phase in hcp Fe. However, the observed change in the transition
temperature with increasing pressure is far too rapid compared with the
calculated results. For comparison with the linear response results, we have
computed the electron-phonon coupling also by using the rigid muffin-tin (RMT)
approximation. From both the LR and the RMT results it appears that
electron-phonon interaction alone cannot explain the small range of volume over
which superconductivity is observed. It is shown that
ferromagnetic/antiferromagnetic spin fluctuations as well as scattering from
magnetic impurities (spin-ordered clusters) can account for the observed values
of the transition temperatures but cannot substantially improve the agreeemnt
between the calculated and observed presure/volume range of the superconducting
phase. A simplified treatment of p-wave pairing leads to extremely small ( K) transition temperatures. Thus our calculations seem to rule out
both - and - wave superconductivity in hcp Fe.Comment: 12 pages, submitted to PR
Itinerant Ferromagnetism in the Periodic Anderson Model
We introduce a novel mechanism for itinerant ferromagnetism, based on a
simple two-band model. The model includes an uncorrelated and dispersive band
hybridized with a second band which is narrow and correlated. The simplest
Hamiltonian containing these ingredients is the Periodic Anderson Model (PAM).
Using quantum Monte Carlo and analytical methods, we show that the PAM and an
extension of it contain the new mechanism and exhibit a non-saturated
ferromagnetic ground state in the intermediate valence regime. We propose that
the mechanism, which does not assume an intra atomic Hund's coupling, is
present in both the iron group and in some f electron compounds like
Ce(Rh_{1-x} Ru_x)_3 B_2, La_x Ce_{1-x} Rh_3 B_2 and the uranium
monochalcogenides US, USe, and UTe
Remanent magnetization of fine particles
A brief review is given of some calculations of the remanent magnetization of fine particles. The remanence after previous saturation has been calculated for a number of different types of anisotropy. A discussion is also given of remanence curves attained after application of D. C. or A. C. fields, and relations between such curves are pointed out.On passe en revue quelques calculs de l'aimantation rémanente des grains fins. D'abord, on a calculé la rémanence après saturation en-posant en prémisse diverses anisotropies. Puis on discute les courbes de rémanence acquises après application des champs directs ou alternatifs et on met en valeur quelques relations entre ces courbes
Itinerant metamagnetism in TiBe2
The high field magnetization data of Monod, Felner, Chouteau and Shaltiel [1] on TiBe2 are discussed in terms of a metamagnetic transition in fields about 5 T.On discute les mesures de Monod, Felner, Chouteau et Shaltiel [1] de l'aimantation du composé défini TiBe2 sous champs intenses en termes d'une transition métamagnétique sous champs de 5 T environ
- …