2 research outputs found
SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMICAL BEHAVIOR OF MONO- AND BIMETALLIC RUTHENIUM AND RHENIUM ALLENYLIDENES BEARING MULTICONJUGATED ORGANIC SPACERS
Novel monoallenylidenes of Ru and Re and homobimetallic Ru/Ru and heterobimetallic Ru/Re complexes bridged by multiconjugated aromatic organic spacers such as bianthracenylidene and biphenylene were obtained and characterized by conventional spectroscopic techniques and elemental analysis. Electrochemical measurements coupled to spectroelectrochemistry and EPR spectroscopy proved that in the bis(allenylidene) complexes an electronic communication is present between either the two allenylidene bridges or the two metal centers, enticing extended intramolecular electronic mobility
MONOREDUCED [M(R,R’timdt)2]- DITHIOLENES (M = Ni, Pd, Pt; R,R’timdt = DISUBSTITUTED IMIDAZOLINE-2,4,5-TRITHIONE): SOLID STATE PHOTOCONDUCTING PROPERTIES IN THE THIRD OPTICAL FIBER WINDOW
Electrochemically monoreduced [M(R,R’timdt)2] dithiolenes, showing unprecedented wavelength
selective photoconducting properties in the third optical fiber window (1500–1800 nm), finetunable through modifications in the chemical structure, allowed for the fabrication of a test photodetector with a bit rate of about 85 kbit s-1