234 research outputs found

    Voltammetry of quinones in anionic micelles

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    A voltammetric study of a series of differently substituted benzenediols was carried out in aq. anionic micellar solns. The partitioning of the probes between the bulk aq. and the micellar pseudophase affects both the obsd. currents and the half-wave potentials. The results are discussed in terms of probe-aggregate interactions and compared with kinetics of electron transfer reactions involving benzenediol/quinone couples
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